α-Olefin Sulfonate
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α-Olefin Sulfonate
General chemical structure of α-olefin sulfonatesR= Alkyl, M= Na+, n = 1 or 2 α-Olefin sulfonates (also: alpha-olefin sulfonates or AOS) are a group of anionic surfactants, which are used as detergents. The compounds contain a - mostly linear, primary - alkyl R and a monovalent cation M, preferably sodium. The most frequently used example of this group of substances is sodium α-olefin sulfonate (INCI: Sodium C14-16 Olefin Sulfonate).External identifiers of or database links to ''Sodium C14-16 olefin sulfonate'': CAS-Number68439-57-6 EC Number270-407-8 ECHA-InfoCard100.063.987 Wikidata: Q72507735. Production and composition α-Olefin sulfonates are produced by sulfonation of alpha-olefins, typically using sulfur trioxide. Subsequent alkaline hydrolysis gives a mixture of alkene sulfonates (60-65%) and hydroxyalkane sulfonates (35-40%). The commercially available olefin sulfonates are mostly solutions with about 40% active ingredient content. Description In addition to ...
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Sulfur Trioxide
Sulfur trioxide (alternative spelling sulphur trioxide) is the chemical compound with the formula SO3. It has been described as "unquestionably the most conomicallyimportant sulfur oxide". It is prepared on an industrial scale as a precursor to sulfuric acid. Sulfur trioxide exists in several forms: gaseous monomer, crystalline trimer, and solid polymer. Sulfur trioxide is a solid at just below room temperature with a relatively narrow liquid range. Gaseous SO3 is the primary precursor to acid rain. Molecular structure and bonding Monomer The molecule SO3 is trigonal planar. As predicted by VSEPR theory, its structure belongs to the D3h point group. The sulfur atom has an oxidation state of +6 and may be assigned a formal charge value as low as 0 (if all three sulfur-oxygen bonds are assumed to be double bonds) or as high as +2 (if the Octet Rule is assumed). When the formal charge is non-zero, the S-O bonding is assumed to be delocalized. In any case the three S-O bond leng ...
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Alkene Derivatives
In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon–carbon double bond. The double bond may be internal or at the terminal position. Terminal alkenes are also known as α-olefins. The International Union of Pure and Applied Chemistry (IUPAC) recommends using the name "alkene" only for acyclic hydrocarbons with just one double bond; alkadiene, alkatriene, etc., or polyene for acyclic hydrocarbons with two or more double bonds; cycloalkene, cycloalkadiene, etc. for cyclic ones; and "olefin" for the general class – cyclic or acyclic, with one or more double bonds. Acyclic alkenes, with only one double bond and no other functional groups (also known as mono-enes) form a homologous series of hydrocarbons with the general formula with ''n'' being a >1 natural number (which is two hydrogens less than the corresponding alkane). When ''n'' is four or more, isomers are possible, distinguished by the position and conformation of the double bond. A ...
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Sodium Laureth Sulfate
Sodium laureth sulfate (SLES), an accepted contraction of sodium lauryl ether sulfate, also called sodium alkylethersulfate, is an anionic detergent and surfactant found in many personal care products (soaps, shampoos, toothpaste, etc.) and for industrial uses. SLES is an inexpensive and very effective foaming agent.Kurt Kosswig,"Surfactants" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, 2005, Weinheim. SLES, sodium lauryl sulfate (SLS), ammonium lauryl sulfate (ALS), and sodium pareth sulfate are surfactants that are used in many cosmetic products for their cleaning and emulsifying properties. It is derived from palm kernel oil or coconut oil. In herbicides, it is used as a surfactant to improve absorption of the herbicidal chemicals and reduces time the product takes to be rainfast, when enough of the herbicidal agent will be absorbed. Its chemical formula is . Sometimes the number represented by ''n'' is specified in the name, for example laureth-2 sulfa ...
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Pesticides
Pesticides are substances that are used to pest control, control pest (organism), pests. They include herbicides, insecticides, nematicides, fungicides, and many others (see table). The most common of these are herbicides, which account for approximately 50% of all pesticide use globally. Most pesticides are used as plant protection products (also known as crop protection products), which in general protect plants from weeds, fungi, or insects. In general, a pesticide is a Chemical substance, chemical or biological agent (such as a virus, bacterium, or entomopathogenic fungus, fungus) that deters, incapacitates, kills, or otherwise discourages pests. Target pests can include insects, plant pathogens, weeds, mollusca, molluscs, birds, mammals, fish, nematodes (roundworms), and microbes that destroy property, cause nuisance, spread disease, or are disease Vector (epidemiology), vectors. Along with these benefits, pesticides also have drawbacks, such as Pesticide poisoning, potent ...
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Mortar (masonry)
Mortar is a workable paste which hardens to bind building blocks such as stones, bricks, and concrete masonry units, to fill and seal the irregular gaps between them, spread the weight of them evenly, and sometimes to add decorative colours or patterns to masonry walls. In its broadest sense, mortar includes pitch, asphalt, and soft clay, as those used between bricks, as well as cement mortar. The word "mortar" comes from the Old French word ''mortier'', "builder's mortar, plaster; bowl for mixing." (13c.). Cement mortar becomes hard when it cures, resulting in a rigid aggregate (composite) , aggregate structure; however, the mortar functions as a weaker component than the building blocks and serves as the sacrificial element in the masonry, because mortar is easier and less expensive to repair than the building blocks. Bricklayers typically make mortars using a mixture of sand, a binder, and water. The most common binder since the early 20th century is Portland cement, but ...
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Concrete
Concrete is a composite material composed of aggregate bound together with a fluid cement that cures to a solid over time. It is the second-most-used substance (after water), the most–widely used building material, and the most-manufactured material in the world. When aggregate is mixed with dry Portland cement and water, the mixture forms a fluid slurry that can be poured and molded into shape. The cement reacts with the water through a process called hydration, which hardens it after several hours to form a solid matrix that binds the materials together into a durable stone-like material with various uses. This time allows concrete to not only be cast in forms, but also to have a variety of tooled processes performed. The hydration process is exothermic, which means that ambient temperature plays a significant role in how long it takes concrete to set. Often, additives (such as pozzolans or superplasticizers) are included in the mixture to improve the physical prop ...
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Emulsion Polymerization
In polymer chemistry, emulsion polymerization is a type of radical polymerization that usually starts with an emulsion incorporating water, monomers, and surfactants. The most common type of emulsion polymerization is an oil-in-water emulsion, in which droplets of monomer (the oil) are emulsified (with surfactants) in a continuous phase of water. Water-soluble polymers, such as certain polyvinyl alcohols or hydroxyethyl celluloses, can also be used to act as emulsifiers/stabilizers. The name "emulsion polymerization" is a misnomer that arises from a historical misconception. Rather than occurring in emulsion droplets, polymerization takes place in the latex/colloid particles that form spontaneously in the first few minutes of the process. These latex particles are typically 100 nm in size, and are made of many individual polymer chains. The particles are prevented from coagulating with each other because each particle is surrounded by the surfactant ('soap'); the charge on the ...
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Toxicity
Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacteria, bacterium, or plant, as well as the effect on a substructure of the organism, such as a cell (biology), cell (cytotoxicity) or an organ such as the liver (hepatotoxicity). Sometimes the word is more or less synonymous with poison#Poisoning, poisoning in everyday usage. A central concept of toxicology is that the effects of a toxicant are Dose (biochemistry), dose-dependent; even water can lead to water intoxication when taken in too high a dose, whereas for even a very toxic substance such as snake venom there is a dose below which there is no detectable toxic effect. Toxicity is species-specific, making cross-species analysis problematic. Newer paradigms and metrics are evolving to bypass animal testing, while maintaining the concept of toxicity endpoints. Etymology In Ancient G ...
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Water Hardness
Hard water is water that has a high mineral content (in contrast with "soft water"). Hard water is formed when water percolates through deposits of limestone, chalk or gypsum, which are largely made up of calcium and magnesium carbonates, bicarbonates and sulfates. Drinking hard water may have moderate health benefits. It can pose critical problems in industrial settings, where water hardness is monitored to avoid costly breakdowns in boilers, cooling towers, and other equipment that handles water. In domestic settings, hard water is often indicated by a lack of foam formation when soap is agitated in water, and by the formation of limescale in kettles and water heaters. Wherever water hardness is a concern, water softening is commonly used to reduce hard water's adverse effects. Origins Natural rainwater, snow and other forms of precipitation typically have low concentrations of divalent cations such as calcium and magnesium. They may have small concentrations of ions such as ...
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Double Bond
In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist between two different elements: for example, in a carbonyl group between a carbon atom and an oxygen atom. Other common double bonds are found in azo compounds (N=N), imines (C=N), and sulfoxides (S=O). In a skeletal formula, a double bond is drawn as two parallel lines (=) between the two connected atoms; typographically, the equals sign is used for this. Double bonds were introduced in chemical notation by Russian chemist Alexander Butlerov. Double bonds involving carbon are stronger and shorter than single bonds. The bond order is two. Double bonds are also electron-rich, which makes them potentially more reactive in the presence of a strong electron acceptor (as in addition reactions of the halogens). File:Ethene structural.svg, ...
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Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually faint, and may be similar to that of gasoline or Naphtha, lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to naturally occurring petroleum, natural gas and coal, or their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are eithe ...
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