Topic summary

RDX

RDX
RDX crystal
Names Preferred IUPAC name
1,3,5-Trinitro-1,3,5-triazinane
Other names
1,3,5-Trinitroperhydro-1,3,5-triazine
RDX
cyclonite, hexogen
1,3,5-Trinitro-1,3,5-triazacyclohexane
1,3,5-Trinitrohexahydro-s-triazine
Cyclotrimethylenetrinitramine
Hexahydro-1,3,5-trinitro-s-triazine
Trimethylenetrinitramine
hexolite
Identifiers
3D model (JSmol)
ChEBIChemSpiderECHA InfoCard100.004.092UNIIUN number0072, 0391, 0483
  • InChI=1S/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2
    Key: XTFIVUDBNACUBN-UHFFFAOYSA-N
  • InChI=1/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2
    Key: XTFIVUDBNACUBN-UHFFFAOYAY
  • C1N(CN(CN1[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-]
Properties C3H6N6O6Molar mass222.117 g·mol Appearance Colorless or yellowish crystals Density1.806 g/cm Melting point205.5 °C (401.9 °F; 478.6 K) Boiling point234 °C (453 °F; 507 K) insoluble Explosive data Shock sensitivityLow Friction sensitivityLow Detonation velocity8750 m/s RE factor1.60 Hazards Occupational safety and health (OHS/OSH):
Main hazards
Explosive, detonates on contact with mercury fulminate, highly toxic GHS labelling: DangerH201, H301, H370, H373P210, P250, P280, P370, P372, P373, P501NFPA 704 (fire diamond) Flash pointExplosive Lethal dose or concentration (LD, LC): 100 mg/kg NIOSH (US health exposure limits):
PEL (Permissible)
none
REL (Recommended)
TWA 1.5 mg/m ST 3 mg/m [skin]
IDLH (Immediate danger)
N.D.
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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RDX (Research Department Explosive or Royal Demolition Explosive), or hexogen, also known by other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, tasteless, and widely used as an explosive. Chemically, it is classified as a nitroamine alongside HMX. It was used widely in World War II and remains common in military applications. It is lower performing and more toxic than modern replacements like TKX-50.

RDX is often used in mixtures with other explosives and plasticizers or phlegmatizers (desensitizers); it is the explosive agent in C-4 plastic explosive and a key ingredient in Semtex. It is stable in storage and is considered one of the most energetic and brisant of the military high explosives, with a relative effectiveness factor of 1.60.