Topic summary

Piperidine

Piperidine
Names IUPAC name
Piperidine
Preferred IUPAC name
Piperidine
Other names
Hexahydropyridine
Azacyclohexane
Pentamethyleneamine
Azinane
Identifiers
3D model (JSmol)
ChEBIChEMBLChemSpiderECHA InfoCard100.003.467EC Number
  • 203-813-0
KEGGRTECS number
  • TM3500000
UNIIUN number2401
  • InChI=1S/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2
    Key: NQRYJNQNLNOLGT-UHFFFAOYSA-N
  • InChI=1/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2
  • InChI=1/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2
    Key: NQRYJNQNLNOLGT-UHFFFAOYAY
  • C1CCNCC1
Properties C5H11NMolar mass85.150 g·mol Appearance Colorless liquid OdorSemen-like, fishy-ammoniacal, pungent Density0.862 g/mL Melting point−7 °C (19 °F; 266 K) Boiling point106 °C (223 °F; 379 K) Miscible Acidity (pKa) 11.22 (protonated) −64.2·10 cm/mol Viscosity1.573 cP at 25 °C Hazards GHS labelling: DangerH225, H311, H314, H331P210, P233, P240, P241, P242, P243, P260, P264, P271, P280, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P311, P312, P321, P322, P361, P363, P370+P378, P403+P233, P403+P235, P405, P501NFPA 704 (fire diamond) Safety data sheet (SDS) MSDS1Legal status
Related compounds
Related compounds
Pyridine
Pyrrolidine
Piperazine

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Piperidine is an organic compound with the molecular formula (CH2)5NH. This heterocyclicamine consists of a six-membered ring containing five methylene bridges (–CH2–) and one amine bridge (–NH–). It is a colorless liquid with an odor described as objectionable, humansperm-like, typical of amines. The name comes from the genus name Piper, which is the Latin word for pepper. Although piperidine is a common organic compound, it is best known as a representative structure element within many pharmaceuticals and alkaloids, such as naturally-occurring solenopsins.