Topic summary

Organoborane

Organoborane

Extracted from the Wikipedia article Organoboron chemistry.

Halogenation

Organoborane activation with hydroxide or alkoxide and treatment with X2 yields haloalkanes. With excess base, two of the three alkyl groups attached to the boron atom may convert to halide, but disiamylborane permits only halogenation of the hydroborated olefin: