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Topic summary

Hydroxide

Hydroxide
Names IUPAC name
Hydroxide
Systematic IUPAC name
Oxidanide (not recommended)
Identifiers
3D model (JSmol)
ChEBIChemSpiderUNII
  • InChI=1S/H2O/h1H2/p-1
  • [OH-]
Properties OH
Molar mass17.007 g·mol Basicity (pKb) 0.0 Conjugate acidWaterConjugate baseOxide anionRelated compounds
Related compounds
O2H
OH
O2
H2O
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Hydroxide (occasionally hydroxyl ion) is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogenatom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, ligand, nucleophile, and catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solutions, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group−OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

Many inorganic substances which bear the word hydroxide in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.