Alkylated

C-alkylation

C-alkylation is a process for the formation of carbon-carbon bonds. The largest example of this takes place in the alkylation units of petrochemical plants, which convert low-molecular-weight alkenes into high octane gasoline components. Electron-rich species such as phenols are also commonly alkylated to produce a variety of products; examples include linear alkylbenzenes used in the production of surfactants like LAS, or butylated phenols like BHT, which are used as antioxidants. This can be achieved using either acid catalysts like Amberlyst, or Lewis acids like aluminium. On a laboratory scale the Friedel–Crafts reaction uses alkyl halides, as these are often easier to handle than their corresponding alkenes, which tend to be gasses. The reaction is catalysed by aluminium trichloride. This approach is rarely used industrially as alkyl halides are more expensive than alkenes.