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Excimer

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An excimer (originally short for excited dimer) is a short-lived polyatomic molecule formed from two species that do not form a stable molecule in the ground state. In this case, formation of molecules is possible only if such atom is in an electronicexcited state. Heteronuclear molecules and molecules that have more than two species are also called exciplex molecules (originally short for excited complex).

Excimer lampExcimer lampAn excimer lamp (or excilamp) is a source of ultraviolet light based on spontaneous emission of excimer (exciplex) molecules. IntroductionExcimer lamps are quasimonochromatic light sources operating over a wide range of wavelengths in the ultraviolet (UV) and vacuum ultraviolet (VUV) spectral regions.Excited stateExcited stateIn quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state.Molecular orbitalMolecular orbitalIn chemistry, a molecular orbital is a mathematical function describing the location and wave-like behavior of an electron in a molecule. This function can be used to calculate chemical and physical properties such as the probability of finding an electron in any specific region. The terms atomic orbital and molecular orbital were introduced by Robert S. Mulliken in 1932 to mean one-electron orbital wave functions.Ground stateGround stateThe ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum. If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states.ElectronElectronThe electron (e, or β in nuclear reactions) is a subatomic particle whose electric charge is negative one elementary charge. It is an elementary particle contained in the matter that makes up the universe. All atoms are composed of electrons, as well as varying numbers protons and neutrons, but the electrons have almost 2,000 times less mass than the other two constituents.Spin (physics)Spin (physics)Spin is an intrinsic form of angular momentum carried by elementary particles, and thus by composite particles such as hadrons, atomic nuclei, and atoms. Spin is quantized, and accurate models for the interaction with spin require relativistic quantum mechanics or quantum field theory.MoleculeMoleculeA molecule is a group of two or more atoms that are held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.Heteronuclear moleculeHeteronuclear moleculeA heteronuclear molecule is a molecule composed of atoms of more than one chemical element. For example, a molecule of water (H2O) is heteronuclear because it has atoms of two different elements, hydrogen (H) and oxygen (O). Similarly, a heteronuclear ion is an ion that contains atoms of more than one chemical element. For example, the carbonate ion (CO3) is heteronuclear because it has atoms of carbon (C) and oxygen (O).NanosecondNanosecondLook up in Wiktionary, the free dictionary.Pauli exclusion principlePauli exclusion principleIn quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e., fermions) cannot simultaneously occupy the same quantum state within a system that obeys the laws of quantum mechanics. This principle was formulated by Austrian physicist Wolfgang Pauli in 1925 for electrons, and later extended to all fermions with his spin–statistics theorem of 1940.HOMO and LUMOHOMO and LUMOIn chemistry, HOMO and LUMO are types of molecular orbitals described at absolute zero. The acronyms stand for highest occupied molecular orbital and lowest unoccupied molecular orbital, respectively. HOMO and LUMO are sometimes collectively called the frontier orbitals, such as in the frontier molecular orbital theory. GapThe energy difference between the HOMO and LUMO is the HOMO–LUMO gap.Arene substitution patternArene substitution patternArene substitution patterns are part of organic chemistryIUPAC nomenclature and pinpoint the position of substituents other than hydrogen in relation to each other on an aromatic hydrocarbon. Ortho, meta, and para substitutionIn ortho-substitution, two substituents occupy positions next to each other, which may be numbered 1 and 2.

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