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Explosive material An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An exp ...
s are produced in numerous physical forms for their use in mining, engineering, or military applications. The different physical forms and fabrication methods are grouped together in several use forms of explosives. Explosives are sometimes used in their pure forms, but most common applications transform or modify them. These use forms are commonly categorized as:


Castings

Castings, or castable explosives, are explosive materials or mixtures in which at least one component can be safely melted at a temperature which is safe to handle the other components, and which are normally produced by casting or pouring the molten mixture or material into a form or use container. In modern usage,
Trinitrotoluene Troponin T (shortened TnT or TropT) is a part of the troponin complex, which are proteins integral to the contraction of skeletal and heart muscles. They are expressed in skeletal and cardiac myocytes. Troponin T binds to tropomyosin and help ...
or TNT is the basic meltable explosive used in essentially all castable explosives. Other ingredients found in modern castable explosives include: * Active, energetic or explosive ingredients: ** Aluminum powder **
Ammonium nitrate Ammonium nitrate is a chemical compound with the formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, but does not form hydrates. It is predominantly us ...
**
Ammonium picrate Dunnite, also known as Explosive D or systematically as ammonium picrate, is an explosive developed in 1906 by US Army Major Beverly W. Dunn, who later served as chief inspector of the Bureau of Transportation Explosives. Ammonium picrate is a sa ...
** Barium nitrate ** EDNA ** HMX ** Lead nitrate **
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (''ПЕНТА'', primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as ''nitropenta''), is an explosive material. ...
** Sodium picrate **
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...
** Tetryl * Inert ingredients **
Boric acid Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula . It may also be called hydrogen orthoborate, trihydroxidoboron or boracic acid. It is usually encountered as colorless crystals or a white ...
**
Calcium chloride Calcium chloride is an inorganic compound, a Salt (chemistry), salt with the chemical formula . It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with cal ...
** Wax **
Silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
, often in the form of
silica fume Silica fume, also known as microsilica, (CAS number 69012-64-2, EINECS number 273-761-1) is an amorphous (non-crystalline) polymorph of silicon dioxide, silica. It is an ultrafine powder collected as a by-product of the silicon and ferrosilicon a ...
( Cab-o-sil for example) Common castable explosives include: *
Amatol Amatol is a highly explosive material made from a mixture of TNT and ammonium nitrate. The British name originates from the words ammonium and toluene (the precursor of TNT). Similar mixtures (one part dinitronaphthalene and seven parts a ...
* Baratol * Boracitol *
Composition B Composition B (Comp B), also known as Hexotol and Hexolite (among others), is a high explosive consisting of castable mixtures of RDX and TNT. It is used as the main explosive filling in artillery projectiles, rockets, land mines, hand grenade ...
*
Cyclotol Cyclotol is an explosive consisting of castable mixtures of RDX and TNT. It is related to the more common Composition B, which is roughly 60% RDX and 40% TNT; various compositions of Cyclotol contain from 65% to 80% RDX. Typical ranges are fr ...
* Octol *
Pentolite Pentolite is a composite high explosive used for military and civilian purposes, e.g., warheads and explosive booster, booster charges. It is made of pentaerythritol tetranitrate (PETN) phlegmatized with TNT, trinitrotoluene (TNT) by melt casting.B ...
* Plumbatol * Tritonal *
Torpex Torpex ("Torpedo explosive") is a secondary explosive, 50% more powerful than TNT by mass. Torpex comprises 42% RDX, 40% TNT and 18% powdered aluminium. It was used in the Second World War from late 1942, at which time some used the names Torp ...
* IMX-101


Polymer bonded

Polymer-bonded explosives, also known as Plastic-bonded explosives or simply PBX, are a relatively solid and inflexible explosive form containing a powdered explosive material and a polymer (plastic) binder. These are usually carefully mixed, often with a very thin coating of the polymer onto the powder grains of the explosive material, and then hot pressed to form dense solid blocks of PBX material. There are numerous PBX explosives, mostly based on
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...
, HMX, or TATB explosive materials. An extensive but by no means complete list of PBX materials is in the main
Polymer-bonded explosive Polymer-bonded explosives, also called PBX or plastic-bonded explosives, are explosive materials in which explosive powder is bound together in a matrix using small quantities (typically 5–10% by weight) of a synthetic polymer. PBXs are normally ...
article. The major naming systems for PBX use: * LX-# (
Lawrence Livermore National Laboratory Lawrence Livermore National Laboratory (LLNL) is a Federally funded research and development centers, federally funded research and development center in Livermore, California, United States. Originally established in 1952, the laboratory now i ...
developed PBXes) * PBX #### (
Los Alamos National Laboratory Los Alamos National Laboratory (often shortened as Los Alamos and LANL) is one of the sixteen research and development Laboratory, laboratories of the United States Department of Energy National Laboratories, United States Department of Energy ...
developed PBXes) * PBXN-# (
United States Navy The United States Navy (USN) is the naval warfare, maritime military branch, service branch of the United States Department of Defense. It is the world's most powerful navy with the largest Displacement (ship), displacement, at 4.5 millio ...
developed PBXes) LX numbers range from 1 to 17. PBX system numbers start around 9000 and use numerous scattered numbers between there and 9700. Some commonly known PBXes are: * LX-17 * PBX 9502 * PBX 9404 * LX-11 * LX-14 PBXes are notable for their use in modern
Nuclear weapons A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either nuclear fission, fission (fission or atomic bomb) or a combination of fission and nuclear fusion, fusion reactions (thermonuclear weap ...
. Modern US and British nuclear warheads nearly all use insensitive PBX types using only TATB explosive, to increase safety in case of accidents.


Putties, aka Plastic explosives

Technically known as putties, but more commonly Plastic explosives, these mixtures are a thick, flexible, moldable solid material that can be shaped and will retain that shape after forming, much like
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
. Putties normally contain mostly
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...
explosive, but may include some
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (''ПЕНТА'', primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as ''nitropenta''), is an explosive material. ...
(Semtex, for example). Some common putties are: * C4 * (Now-obsolete) Composition C *
Semtex Semtex is a general-purpose plastic explosive containing RDX and PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, originally under the name B 1 a ...
* PE-4


Rubberized

Rubberized explosives are flat sheets of solid but flexible material, a mixture of a powdered explosive (commonly
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...
or
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (''ПЕНТА'', primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as ''nitropenta''), is an explosive material. ...
) and a synthetic or natural rubber compound. Rubberized sheet explosives are commonly used for explosive welding and for various other industrial and military applications. Rubberized explosives can be cut to specific shape, bent around solid surfaces, glued or taped in place, or simply laid on relatively flat surfaces. Some common rubberized explosives include: * Detasheet - a discontinued
DuPont Dupont, DuPont, Du Pont, duPont, or du Pont may refer to: People * Dupont (surname) Dupont, also spelled as DuPont, duPont, Du Pont, or du Pont is a French surname meaning "of the bridge", historically indicating that the holder of the surname re ...
product now manufactured by The Ensign-Bickford Aerospace & Defense Company ** Deta Flex - a DuPont military version of Detasheet ** LX-02-1 - a DuPont Deta Flex variant used by the
US Department of Energy US or Us most often refers to: * Us (pronoun), ''Us'' (pronoun), the objective case of the English first-person plural pronoun ''we'' * US, an abbreviation for the United States US, U.S., Us, us, or u.s. may also refer to: Arts and entertainme ...
nuclear weapons programs * Primasheet - current Ensign-Bickford product line ** Primasheet 1000 - Primasheet 1000 using
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (''ПЕНТА'', primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as ''nitropenta''), is an explosive material. ...
** Primasheet 2000 - Primasheet 2000 using
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...


Extrudable

Extrudable explosives are an extremely viscous liquid, similar in properties to
silicone In Organosilicon chemistry, organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (, where R = Organyl group, organic group). They are typically colorless oils or elastomer, rubber ...
based
caulk Caulk (also known as caulking and calking) is a material used to Seal (mechanical), seal Joint (building), joints or seams against leakage in various structures and piping. The oldest form of caulk consisted of fibrous materials driven into ...
ing materials used in construction. It is used in similar ways - stored in a container, then extruded out a nozzle into thin cracks, holes, or along surfaces. Some extrudable explosives can then be hardened using a heat curing process. Others will remain a viscous fluid permanently. Common extrudable explosives include: * Setting extrudables ** LX-13 ** XTX-8003 ** XTX-8004 * Non-setting extrudables ** Demex-400


Binary

Binary explosives are cap-sensitive (detonatable with a standard #8
blasting cap A detonator is a device used to make an explosive or explosive device explode. Detonators come in a variety of types, depending on how they are initiated (chemically, mechanically, or electrically) and details of their inner working, which of ...
) two-part explosives mixtures, shipped separately and combined at the use site. Many of these mixtures are based on
Ammonium nitrate Ammonium nitrate is a chemical compound with the formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, but does not form hydrates. It is predominantly us ...
as an oxidizer plus a volatile fuel, but unlike
ANFO ANFO ( ) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial high explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number ...
(ammonium nitrate fuel oil explosive) these binaries can be detonated by blasting caps. ANFO requires high explosive boosters to detonate it. Most binary explosives are a slurry after mixing, but some form a fluid with solid components dissolved into liquid ones. Some common binary explosives include: * Kinestik (ammonium nitrate/
nitromethane Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in ...
) * Tannerite (ammonium nitrate/aluminum) * Kinepouch * Kinepak * Boulder-Busters * Marine Pac * ASTRO-PAK The historical but now uncommon Astrolite explosive is also a binary explosive. This category is somewhat unusual in that a single explosives researcher, Gerald Hurst, was responsible for inventing and developing most of the explosive mixtures now in use.Astrolite usenet posts archived at Yarchive
accessed 2008-12-28


Blasting agents

Blasting agents are explosive materials or mixtures which are not detonatable by standard #8
blasting cap A detonator is a device used to make an explosive or explosive device explode. Detonators come in a variety of types, depending on how they are initiated (chemically, mechanically, or electrically) and details of their inner working, which of ...
s. The best known blasting agent is
ANFO ANFO ( ) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial high explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number ...
explosive, a mixture containing primarily
ammonium nitrate Ammonium nitrate is a chemical compound with the formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, but does not form hydrates. It is predominantly us ...
with a small quantity (typically around 6%) of fuel oil, most commonly
diesel fuel Diesel fuel, also called diesel oil, heavy oil (historically) or simply diesel, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a re ...
. Other fuels and additives are used as well. While ANFO is often made on-site using fertilizer grade ammonium nitrate, blasting agents can also be purchased in prepackaged form, usually in metal or cardboard cylinders. Some brand names of packaged blasting agents include: * Nitramon * Nitramite * Pellite * Carbomite * Vibronite * Dynatex * Hydratol * Anoil


Dynamites

It is usually sold in the form of a stick roughly long and in diameter but other sizes also exist. Dynamite is considered a "high explosive", which means it detonates rather than deflagrates. The chief uses of dynamite used to be in construction, mining and demolition. However, newer explosives and techniques have replaced dynamite in many applications. Dynamite is still used, mainly as bottom charge or in underwater blasting.


References

{{Reflist Explosives engineering