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HMX
HMX, also called octogen, is a powerful and relatively insensitive nitroamine high explosive chemically related to RDX. The compound's name is the subject of much speculation, having been variously listed as High Melting Explosive, High-velocity Military Explosive, or High-Molecular-weight RDX. The molecular structure of HMX consists of an eight-membered ring of alternating carbon and nitrogen atoms, with a nitro group attached to each nitrogen atom. Because of its high mass-specific enthalpy of formation, it is one of the most potent chemical explosives manufactured, although a number of newer ones, including HNIW and ONC, are more powerful. Synthesis HMX is more complicated to manufacture than most explosives, and this confines it to specialist applications. It and RDX are both produced by the Bachmann process—nitration of hexamine using a mixture of ammonium nitrate and nitric acid in a mixture of acetic acid and acetic anhydride as solvent—with the major product det ...
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Polymer-bonded Explosive
Polymer-bonded explosives, also called PBX or plastic-bonded explosives, are explosive materials in which explosive powder is bound together in a matrix using small quantities (typically 5–10% by weight) of a synthetic polymer. PBXs are normally used for explosive materials that are not easily melted into a casting, or are otherwise difficult to form. PBX was first developed in 1952 at Los Alamos National Laboratory, as RDX embedded in polystyrene with diisooctyl phthalate (DEHP) plasticizer. HMX compositions with teflon-based binders were developed in 1960s and 1970s for gun shells and for Apollo Lunar Surface Experiments Package (ALSEP) seismic experiments, although the latter experiments are usually cited as using hexanitrostilbene (HNS). Potential advantages Polymer-bonded explosives have several potential advantages: * If the polymer matrix is an elastomer (rubbery material), it tends to absorb shocks, making the PBX very insensitive to accidental detonation, and th ...
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Octol
Octol is a melt- castable, high explosive mixture consisting of HMX and TNT in different weight proportions. Composition Two formulations are commonly used: * 70% HMX & 30% TNT * 75% HMX & 25% TNT Given that HMX has a much higher detonation velocity than TNT (over 2,000 metres per second faster) and forms the main part of this explosive blend, the brisance characteristics of Octol can be inferred. Applications The applications of Octol are generally military; e.g., shaped charges and warheads that are used in guided missiles and submunitions. Octol is somewhat more expensive than RDX-based explosives, such as Composition B and Cyclotol. The advantage of Octol is that it significantly reduces the size and weight of the explosive charge required. These are important considerations where smart weapons such as guided missiles are concerned. A light (but effective) warhead means a superior power to weight ratio. This in turn results in a higher velocity missile with a longer rang ...
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Hexanitrohexaazaisowurtzitane
Hexanitrohexaazaisowurtzitane, also called HNIW and CL-20, is a polycyclic compound, polycyclic nitroamine explosive with the formula . It has a better Redox, oxidizer-to-fuel ratio than conventional HMX or RDX. It releases 20% more energy than traditional HMX-based propellants. History and use In the 1980s, CL-20 was developed by the Naval Air Weapons Station China Lake, China Lake facility, primarily to be used in propellants. While most development of CL-20 has been fielded by the Thiokol, Thiokol Corporation, the US Navy (through Office of Naval Research, ONR) has also been interested in CL-20 for use in rocket propellants, such as for missiles, as it has lower observability characteristics such as less visible smoke. Thus far, CL-20 has only been used in the AeroVironment Switchblade 300 “kamikaze” drone, but is undergoing testing for use in the Lockheed Martin [LMT] AGM-158C Long Range Anti-Ship Missile (LRASM) and AGM-158B Joint Air-to-Surface Standoff Missile-Exten ...
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High Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or Dust explosion, grain dust * pressure, pressurized gas compressor, gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear weapon, nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high ...
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RE Factor
TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. A ton of TNT equivalent is a unit of energy defined by convention to be (). It is the approximate energy released in the detonation of a metric ton (1,000 kilograms) of trinitrotoluene (TNT). In other words, for each gram of TNT exploded, (or 4184 joules) of energy are released. This convention intends to compare the destructiveness of an event with that of conventional explosive materials, of which TNT is a typical example, although other conventional explosives such as dynamite contain more energy. A related concept is the physical quantity TNT-equivalent mass (or mass of TNT equivalent), expressed in the ordinary units of mass and its multiples: kilogram (kg), megagram (Mg) or tonne (t), etc. Kiloton and megaton The "kiloton (of TNT equivalent)" is a unit of energy equal to 4.184 terajoules (). A kiloton of TNT can be visualized as a cube of TNT on a si ...
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Octanitrocubane
Octanitrocubane (molecular formula: C8(NO2)8) is a proposed high explosive that, like TNT, is shock-insensitive (not readily detonated by shock). The octanitrocubane molecule has the same chemical structure as cubane (C8H8) except that each of the eight hydrogen atoms is replaced by a nitro group (NO2). As of 1998, octanitrocubane had not been produced in quantities large enough to test its performance as an explosive. It is, however, not as powerful an explosive as once thought, as the high-density theoretical crystal structure has not been achieved. For this reason, heptanitrocubane, the slightly less nitrated form, is believed to have marginally better performance, despite having a worse oxygen balance. Octanitrocubane is thought to have 20–25% greater performance than HMX (octogen). This increase in power is due to its highly expansive breakdown into CO2 and N2, as well as to the presence of strained chemical bonds in the molecule which have stored potential energy. In a ...
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Hexamine
Hexamethylenetetramine (HMTA), also known as 1,3,5,7-tetraazaadamantane, is a heterocyclic organic compound with diverse applications. It has the chemical formula (CH2)6N4 and is a white crystalline compound that is highly soluble in water and polar organic solvents. It is useful in the synthesis of other organic compounds, including plastics, pharmaceuticals, and rubber additives. The compound is also used medically for certain conditions. It sublimes in vacuum at 280°C. It has a tetrahedral cage-like structure similar to adamantane. The four vertices are occupied by nitrogen atoms, which are linked by methylene groups. Although the molecular shape defines a cage, no void space is available at the interior. Synthesis, structure, reactivity Hexamethylenetetramine was discovered by Aleksandr Butlerov in 1859. In this article, Butlerov discovered formaldehyde, which he called "dioxymethylen" (methylene dioxide) age 247because his empirical formula for it was incorrect (C4H4O4) ...
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Heptanitrocubane
Heptanitrocubane is an experimental high explosive based on the cubic eight-carbon cubane molecule and closely related to octanitrocubane. Seven of the eight hydrogen atoms at the corners of the cubane molecule are replaced by nitro groups, giving the final molecular formula . As with octanitrocubane, not enough heptanitrocubane has been synthesized to perform detailed tests on its stability and energy. It is hypothesized to have slightly better performance than explosives such as HMX, the current high-energy standard explosive, based on chemical energy analysis. While in theory not as energetic as octanitrocubane's theoretical maximum density, the heptanitrocubane that has been synthesized so far is a more effective explosive than any octanitrocubane that has been produced, due to more efficient crystal packing and hence higher density. Heptanitrocubane was first synthesized by the same team who synthesized octanitrocubane, Philip Eaton and Mao-Xi Zhang at the University o ...
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Shaped Charge
A shaped charge, commonly also hollow charge if shaped with a cavity, is an explosive charge shaped to focus the effect of the explosive's energy. Different types of shaped charges are used for various purposes such as cutting and forming metal, initiating nuclear weapons, penetrating armor, or perforating wells in the oil and gas industry. A typical modern shaped charge, with a metal liner on the charge cavity, can penetrate armor steel to a depth of seven or more times the diameter of the charge (charge diameters, CD), though depths of 10 CD and above have been achieved. Contrary to a misconception, possibly resulting from the acronym ''HEAT'' (high-explosive anti-tank), the shaped charge does not depend in any way on heating or melting for its effectiveness; that is, the jet from a shaped charge does not melt its way through armor, as its effect is purely kinetic in nature—however the process creates significant heat and often has a significant secondary incendiary ef ...
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Hayabusa2
is an asteroid sample-return mission operated by the Japanese state space agency JAXA. It is a successor to the ''Hayabusa'' mission, which returned asteroid samples for the first time in June 2010. ''Hayabusa2'' was launched on 3 December 2014 and rendezvoused in space with near-Earth asteroid 162173 Ryugu on 27 June 2018. It surveyed the asteroid for a year and a half and took samples. It left the asteroid in November 2019 and returned the samples to Earth on 5 December 2020 UTC. Its mission has now been extended through at least 2031, when it will rendezvous with the small, rapidly-rotating asteroid . ''Hayabusa2'' carries multiple science payloads for remote sensing and sampling, and four small rovers to investigate the asteroid surface and analyze the environmental and geological context of the samples collected. Mission overview Asteroid 162173 Ryugu (formerly designated ) is a primitive carbonaceous near-Earth asteroid. Carbonaceous asteroids are thought to p ...
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Asteroid
An asteroid is a minor planet—an object larger than a meteoroid that is neither a planet nor an identified comet—that orbits within the Solar System#Inner Solar System, inner Solar System or is co-orbital with Jupiter (Trojan asteroids). Asteroids are rocky, metallic, or icy bodies with no atmosphere, and are broadly classified into C-type asteroid, C-type (carbonaceous), M-type asteroid, M-type (metallic), or S-type asteroid, S-type (silicaceous). The size and shape of asteroids vary significantly, ranging from small rubble piles under a kilometer across to Ceres (dwarf planet), Ceres, a dwarf planet almost 1000 km in diameter. A body is classified as a comet, not an asteroid, if it shows a coma (tail) when warmed by solar radiation, although recent observations suggest a continuum between these types of bodies. Of the roughly one million known asteroids, the greatest number are located between the orbits of Mars and Jupiter, approximately 2 to 4 astronomical unit, AU ...
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