Strontium sulfide is the
inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''.
Inorgan ...
with the formula
Sr S. It is a white solid. The compound is an intermediate in the conversion of strontium sulfate, the main strontium
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
called
celestite
Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate ( Sr S O). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources o ...
(or, more correctly, celestine), to other more useful compounds.
[J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht “Strontium and Strontium Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. .]
Production and reactions
Strontium sulfide is produced by
roasting
Roasting is a cooking method that uses dry heat where hot air covers the food, cooking it evenly on all sides with temperatures of at least from an open flame, oven, or other heat source. Roasting can enhance the flavor through caramelizat ...
celestine with
coke at 1100–1300 °C.
The sulfate is
reduced, leaving the sulfide:
:SrSO
4 + 2 C → SrS + 2 CO
2
About 300,000 tons are processed in this way annually.
[ Both luminous and nonluminous sulfide phases are known, impurities, defects, and dopants being important.][R. Ward, R. K. Osterheld, R. D. Rosenstein "Strontium Sulfide and Selenide Phosphors" Inorganic Syntheses, 1950, vol. III, pp. 11–24. ]
As expected for a sulfide salt of alkaline earth, the sulfide hydrolyzes readily:
:SrS + 2 H2O → Sr(OH)2 + H2S
For this reason, samples of SrS have an odor of rotten eggs.
Similar reactions are used in the production of commercially useful compounds, including the most useful strontium compound, strontium carbonate
Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite.
Chemical properties
Strontium carbonate is a white, odorless, tasteless powder ...
: a mixture of strontium sulfide with either carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
gas or sodium carbonate
Sodium carbonate (also known as washing soda, soda ash, sal soda, and soda crystals) is the inorganic compound with the formula and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water ...
leads to formation of a precipitate
In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemic ...
of strontium carbonate.[
:SrS + H2O + CO2 → SrCO3 + H2S
:SrS + Na2CO3 → SrCO3 + Na2S
]Strontium nitrate
Strontium nitrate is an inorganic compound composed of the elements strontium, nitrogen and oxygen with the formula Sr( NO3)2. This colorless solid is used as a red colorant and oxidizer in pyrotechnics.
Preparation
Strontium nitrate is typica ...
can also be prepared in this way.
References
External links
Strontium Sulfide Info
American Elements
American Elements is a global manufacturer and distributor of advanced materials with an over 35,000-page online product catalog and compendium of information on the chemical elements, advanced materials, and high technology applications. The co ...
{{Authority control
Strontium compounds
Monosulfides
Rock salt crystal structure