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In
mathematical physics Mathematical physics refers to the development of mathematics, mathematical methods for application to problems in physics. The ''Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and t ...
, scalar potential, simply stated, describes the situation where the difference in the potential energies of an object in two different positions depends only on the positions, not upon the path taken by the object in traveling from one position to the other. It is a
scalar field In mathematics and physics, a scalar field is a function associating a single number to every point in a space – possibly physical space. The scalar may either be a pure mathematical number ( dimensionless) or a scalar physical quantit ...
in
three-space Three-dimensional space (also: 3D space, 3-space or, rarely, tri-dimensional space) is a geometric setting in which three values (called ''parameters'') are required to determine the position (geometry), position of an element (i.e., Point (m ...
: a directionless value ( scalar) that depends only on its location. A familiar example is potential energy due to gravity. A ''scalar
potential Potential generally refers to a currently unrealized ability. The term is used in a wide variety of fields, from physics to the social sciences to indicate things that are in a state where they are able to change in ways ranging from the simple r ...
'' is a fundamental concept in
vector analysis Vector calculus, or vector analysis, is concerned with differentiation and integration of vector fields, primarily in 3-dimensional Euclidean space \mathbb^3. The term "vector calculus" is sometimes used as a synonym for the broader subjec ...
and
physics Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which rel ...
(the adjective ''scalar'' is frequently omitted if there is no danger of confusion with ''
vector potential In vector calculus, a vector potential is a vector field whose curl is a given vector field. This is analogous to a '' scalar potential'', which is a scalar field whose gradient is a given vector field. Formally, given a vector field v, a ''ve ...
''). The scalar potential is an example of a
scalar field In mathematics and physics, a scalar field is a function associating a single number to every point in a space – possibly physical space. The scalar may either be a pure mathematical number ( dimensionless) or a scalar physical quantit ...
. Given a vector field , the scalar potential is defined such that: : \mathbf = -\nabla P = - \left( \frac, \frac, \frac \right), where is the
gradient In vector calculus, the gradient of a scalar-valued differentiable function of several variables is the vector field (or vector-valued function) \nabla f whose value at a point p is the "direction and rate of fastest increase". If the gr ...
of and the second part of the equation is minus the gradient for a function of the
Cartesian coordinates A Cartesian coordinate system (, ) in a plane is a coordinate system that specifies each point uniquely by a pair of numerical coordinates, which are the signed distances to the point from two fixed perpendicular oriented lines, measured i ...
. In some cases, mathematicians may use a positive sign in front of the gradient to define the potential.Se

for an example where the potential is defined without a negative. Other references such as avoid using the term ''potential'' when solving for a function from its gradient.
Because of this definition of in terms of the gradient, the direction of at any point is the direction of the steepest decrease of at that point, its magnitude is the rate of that decrease per unit length. In order for to be described in terms of a scalar potential only, any of the following equivalent statements have to be true: #-\int_a^b \mathbf\cdot d\mathbf = P(\mathbf)-P(\mathbf), where the integration is over a
Jordan arc In topology, the Jordan curve theorem asserts that every ''Jordan curve'' (a plane simple closed curve) divides the plane into an "interior" region bounded by the curve and an "exterior" region containing all of the nearby and far away exterior p ...
passing from location to location and is evaluated at location . #\oint \mathbf\cdot d\mathbf=0, where the integral is over any simple closed path, otherwise known as a
Jordan curve In mathematics, a curve (also called a curved line in older texts) is an object similar to a line, but that does not have to be straight. Intuitively, a curve may be thought of as the trace left by a moving point. This is the definition tha ...
. #\times =0. The first of these conditions represents the fundamental theorem of the gradient and is true for any vector field that is a gradient of a differentiable single valued scalar field . The second condition is a requirement of so that it can be expressed as the gradient of a scalar function. The third condition re-expresses the second condition in terms of the curl of using the fundamental theorem of the curl. A vector field that satisfies these conditions is said to be
irrotational In vector calculus, a conservative vector field is a vector field that is the gradient of some function (mathematics), function. A conservative vector field has the property that its line integral is path independent; the choice of any path betwee ...
(conservative). Scalar potentials play a prominent role in many areas of physics and engineering. The gravity potential is the scalar potential associated with the gravity per unit mass, i.e., the
acceleration In mechanics, acceleration is the rate of change of the velocity of an object with respect to time. Accelerations are vector quantities (in that they have magnitude and direction). The orientation of an object's acceleration is given by ...
due to the field, as a function of position. The gravity potential is the
gravitational potential energy Gravitational energy or gravitational potential energy is the potential energy a massive object has in relation to another massive object due to gravity. It is the potential energy associated with the gravitational field, which is released (conv ...
per unit mass. In
electrostatics Electrostatics is a branch of physics that studies electric charges at rest (static electricity). Since classical times, it has been known that some materials, such as amber, attract lightweight particles after rubbing. The Greek word for am ...
the
electric potential The electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as the amount of work energy needed to move a unit of electric charge from a reference point to the specific point in ...
is the scalar potential associated with the electric field, i.e., with the
electrostatic force Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventio ...
per unit charge. The electric potential is in this case the electrostatic potential energy per unit charge. In
fluid dynamics In physics and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids—liquids and gases. It has several subdisciplines, including '' aerodynamics'' (the study of air and other gases in motion) ...
, irrotational lamellar fields have a scalar potential only in the special case when it is a Laplacian field. Certain aspects of the nuclear force can be described by a
Yukawa potential In particle, atomic and condensed matter physics, a Yukawa potential (also called a screened Coulomb potential) is a potential named after the Japanese physicist Hideki Yukawa. The potential is of the form: :V_\text(r)= -g^2\frac, where is a ...
. The potential play a prominent role in the
Lagrangian Lagrangian may refer to: Mathematics * Lagrangian function, used to solve constrained minimization problems in optimization theory; see Lagrange multiplier ** Lagrangian relaxation, the method of approximating a difficult constrained problem with ...
and Hamiltonian formulations of
classical mechanics Classical mechanics is a physical theory describing the motion of macroscopic objects, from projectiles to parts of machinery, and astronomical objects, such as spacecraft, planets, stars, and galaxies. For objects governed by classical ...
. Further, the scalar potential is the fundamental quantity in
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
. Not every vector field has a scalar potential. Those that do are called ''
conservative Conservatism is a cultural, social, and political philosophy that seeks to promote and to preserve traditional institutions, practices, and values. The central tenets of conservatism may vary in relation to the culture and civilization in ...
'', corresponding to the notion of
conservative force In physics, a conservative force is a force with the property that the total work done in moving a particle between two points is independent of the path taken. Equivalently, if a particle travels in a closed loop, the total work done (the sum ...
in physics. Examples of non-conservative forces include frictional forces, magnetic forces, and in fluid mechanics a solenoidal field velocity field. By the Helmholtz decomposition theorem however, all vector fields can be describable in terms of a scalar potential and corresponding
vector potential In vector calculus, a vector potential is a vector field whose curl is a given vector field. This is analogous to a '' scalar potential'', which is a scalar field whose gradient is a given vector field. Formally, given a vector field v, a ''ve ...
. In electrodynamics, the electromagnetic scalar and vector potentials are known together as the
electromagnetic four-potential An electromagnetic four-potential is a relativistic vector function from which the electromagnetic field can be derived. It combines both an electric scalar potential and a magnetic vector potential into a single four-vector.Gravitation, J.A. Wh ...
.


Integrability conditions

If is a conservative vector field (also called ''irrotational'', '' curl-free'', or ''potential''), and its components have continuous
partial derivative In mathematics, a partial derivative of a function of several variables is its derivative with respect to one of those variables, with the others held constant (as opposed to the total derivative, in which all variables are allowed to vary). Pa ...
s, the potential of with respect to a reference point is defined in terms of the
line integral In mathematics, a line integral is an integral where the function to be integrated is evaluated along a curve. The terms ''path integral'', ''curve integral'', and ''curvilinear integral'' are also used; '' contour integral'' is used as well, ...
: :V(\mathbf r) = -\int_C \mathbf(\mathbf)\cdot\,d\mathbf = -\int_a^b \mathbf(\mathbf(t))\cdot\mathbf'(t)\,dt, where is a parametrized path from to , : \mathbf(t), a\leq t\leq b, \mathbf(a)=\mathbf, \mathbf(b)=\mathbf. The fact that the line integral depends on the path only through its terminal points and is, in essence, the path independence property of a conservative vector field. The
fundamental theorem of line integrals The gradient theorem, also known as the fundamental theorem of calculus for line integrals, says that a line integral through a gradient field can be evaluated by evaluating the original scalar field at the endpoints of the curve. The theorem is ...
implies that if is defined in this way, then , so that is a scalar potential of the conservative vector field . Scalar potential is not determined by the vector field alone: indeed, the gradient of a function is unaffected if a constant is added to it. If is defined in terms of the line integral, the ambiguity of reflects the freedom in the choice of the reference point .


Altitude as gravitational potential energy

An example is the (nearly) uniform gravitational field near the Earth's surface. It has a potential energy : U = m g h where is the gravitational potential energy and is the height above the surface. This means that gravitational potential energy on a contour map is proportional to altitude. On a contour map, the two-dimensional negative gradient of the altitude is a two-dimensional vector field, whose vectors are always perpendicular to the contours and also perpendicular to the direction of gravity. But on the hilly region represented by the contour map, the three-dimensional negative gradient of always points straight downwards in the direction of gravity; . However, a ball rolling down a hill cannot move directly downwards due to the
normal force In mechanics, the normal force F_n is the component of a contact force that is perpendicular to the surface that an object contacts, as in Figure 1. In this instance '' normal'' is used in the geometric sense and means perpendicular, as oppose ...
of the hill's surface, which cancels out the component of gravity perpendicular to the hill's surface. The component of gravity that remains to move the ball is parallel to the surface: : \mathbf F_\mathrm = - m g \ \sin \theta where is the angle of inclination, and the component of perpendicular to gravity is : \mathbf F_\mathrm = - m g \ \sin \theta \ \cos \theta = - m g \sin 2 \theta. This force , parallel to the ground, is greatest when is 45 degrees. Let be the uniform interval of altitude between contours on the contour map, and let be the distance between two contours. Then \theta = \tan^\frac so that F_P = - m g . However, on a contour map, the gradient is inversely proportional to , which is not similar to force : altitude on a contour map is not exactly a two-dimensional potential field. The magnitudes of forces are different, but the directions of the forces are the same on a contour map as well as on the hilly region of the Earth's surface represented by the contour map.


Pressure as buoyant potential

In
fluid mechanics Fluid mechanics is the branch of physics concerned with the mechanics of fluids (liquids, gases, and plasmas) and the forces on them. It has applications in a wide range of disciplines, including mechanical, aerospace, civil, chemical and ...
, a fluid in equilibrium, but in the presence of a uniform gravitational field is permeated by a uniform buoyant force that cancels out the gravitational force: that is how the fluid maintains its equilibrium. This
buoyant force Buoyancy (), or upthrust, is an upward force exerted by a fluid that opposes the weight of a partially or fully immersed object. In a column of fluid, pressure increases with depth as a result of the weight of the overlying fluid. Thus the pr ...
is the negative gradient of
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
: : \mathbf = - \nabla p. \, Since buoyant force points upwards, in the direction opposite to gravity, then pressure in the fluid increases downwards. Pressure in a static body of water increases proportionally to the depth below the surface of the water. The surfaces of constant pressure are planes parallel to the surface, which can be characterized as the plane of zero pressure. If the liquid has a vertical
vortex In fluid dynamics, a vortex ( : vortices or vortexes) is a region in a fluid in which the flow revolves around an axis line, which may be straight or curved. Vortices form in stirred fluids, and may be observed in smoke rings, whirlpools in t ...
(whose axis of rotation is perpendicular to the surface), then the vortex causes a depression in the pressure field. The surface of the liquid inside the vortex is pulled downwards as are any surfaces of equal pressure, which still remain parallel to the liquids surface. The effect is strongest inside the vortex and decreases rapidly with the distance from the vortex axis. The buoyant force due to a fluid on a solid object immersed and surrounded by that fluid can be obtained by integrating the negative pressure gradient along the surface of the object: : F_B = - \oint_S \nabla p \cdot \, d\mathbf.


Scalar potential in Euclidean space

In 3-dimensional Euclidean space , the scalar potential of an irrotational vector field is given by \Phi(\mathbf) = \int_ \frac \, dV(\mathbf r') where is an infinitesimal volume element with respect to . Then \mathbf = -\mathbf \Phi = - \mathbf \int_ \frac \, dV(\mathbf r') This holds provided is continuous and vanishes asymptotically to zero towards infinity, decaying faster than and if the
divergence In vector calculus, divergence is a vector operator that operates on a vector field, producing a scalar field giving the quantity of the vector field's source at each point. More technically, the divergence represents the volume density of t ...
of likewise vanishes towards infinity, decaying faster than . Written another way, let \Gamma(\mathbf) = \frac\frac be the Newtonian potential. This is the fundamental solution of the
Laplace equation In mathematics and physics, Laplace's equation is a second-order partial differential equation named after Pierre-Simon Laplace, who first studied its properties. This is often written as \nabla^2\! f = 0 or \Delta f = 0, where \Delta = \na ...
, meaning that the Laplacian of is equal to the negative of the
Dirac delta function In mathematics, the Dirac delta distribution ( distribution), also known as the unit impulse, is a generalized function or distribution over the real numbers, whose value is zero everywhere except at zero, and whose integral over the entire ...
: :\nabla^2\Gamma(\mathbf r) + \delta(\mathbf r)=0. Then the scalar potential is the divergence of the
convolution In mathematics (in particular, functional analysis), convolution is a mathematical operation on two functions ( and ) that produces a third function (f*g) that expresses how the shape of one is modified by the other. The term ''convolution' ...
of with : :\Phi = \operatorname(\mathbf E * \Gamma). Indeed, convolution of an irrotational vector field with a rotationally invariant potential is also irrotational. For an irrotational vector field , it can be shown that \nabla^2\mathbf = \mathbf(\mathbf \cdot \mathbf). Hence \nabla\operatorname(\mathbf E * \Gamma) = \nabla^2(\mathbf E * \Gamma) = \mathbf E * \nabla^2\Gamma = -\mathbf E * \delta = -\mathbf E as required. More generally, the formula \Phi = \operatorname(\mathbf E * \Gamma) holds in -dimensional Euclidean space () with the Newtonian potential given then by \Gamma(\mathbf r) = \frac where is the volume of the unit -ball. The proof is identical. Alternatively, integration by parts (or, more rigorously, the properties of convolution) gives \Phi(\mathbf r) = -\frac \int_ \frac \,dV(\mathbf r').


See also

*
Gradient theorem The gradient theorem, also known as the fundamental theorem of calculus for line integrals, says that a line integral through a gradient field can be evaluated by evaluating the original scalar field at the endpoints of the curve. The theorem is ...
* Fundamental theorem of vector analysis * Equipotential (isopotential) lines and surfaces


Notes


References

{{DEFAULTSORT:Scalar Potential Potentials Vector calculus Scalar physical quantities fr:Champ de vecteurs#Champ de gradient