Lithium oxide ( O) or lithia is an

inorganic chemical compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...

. It is a white or pale yellow solid. Although not specifically important, many materials are assessed on the basis of their Li₂O content. For example, the Li₂O content of the principal lithium mineral

spodumene Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a commercially important source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), or alternatively yellow ...

(LiAlSi₂O₆) is 8.03%.

Production

Lithium oxide forms along with small amounts of lithium peroxide when lithium metal is burned in the air and combines with oxygen at temperatures above 100 °C: :4Li + → 2. Pure can be produced by the

thermal decomposition Thermal decomposition, or thermolysis, is a chemical decomposition of a substance caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic ...

of lithium peroxide, , at 450 °CWietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim. . :2 → 2 +

Structure

Solid lithium oxide adopts an antifluorite structure with four-coordinated Li+ centers and eight-coordinated oxides. The ground state gas phase molecule is linear with a bond length consistent with strong ionic bonding.Wells A. F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications A spectroscopic determination of the bond length of the LiOLi molecule: Strong ionic bonding, D. Bellert, W. H. Breckenridge, J. Chem. Phys. 114, 2871 (2001);

VSEPR theory Valence shell electron pair repulsion (VSEPR) theory ( , ) is a conceptual model, model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. It is also named the Gill ...

would predict a bent shape similar to .

Uses

Lithium oxide is used as a

flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phe ...

in ceramic glazes; and creates blues with

copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...

and pinks with

cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...

. Lithium oxide reacts with

water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...

and

steam Steam is water vapor, often mixed with air or an aerosol of liquid water droplets. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization. Saturated or superheated steam is inv ...

, forming

lithium hydroxide Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...

and should be isolated from them. Its usage is also being investigated for non-destructive emission spectroscopy evaluation and degradation monitoring within

thermal barrier coating Thermal barrier coatings (TBCs) are advanced materials systems usually applied to metallic surfaces on parts operating at elevated temperatures, such as gas turbine combustors and turbines, and in automotive exhaust heat management. These 100 ...

systems. It can be added as a co-dopant with yttria in the zirconia ceramic top coat, without a large decrease in expected service life of the coating. At high heat, lithium oxide emits a very detectable spectral pattern, which increases in intensity along with degradation of the coating. Implementation would allow in situ monitoring of such systems, enabling an efficient means to predict lifetime until failure or necessary maintenance. Lithium metal might be obtained from lithium oxide by electrolysis, releasing oxygen as by-product.

Reactions

Lithium oxide absorbs

carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...

forming

lithium carbonate Lithium carbonate is an inorganic compound, the lithium salt of carbonic acid with the chemical formula, formula . This white Salt (chemistry), salt is widely used in processing metal oxides. It is on the WHO Model List of Essential Medicines, Wor ...

: : + → The oxide reacts slowly with water, forming

: : + → 2

References

External links