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Yttria
Yttrium oxide, also known as yttria, is Y2 O3. It is an air-stable, white solid substance. The thermal conductivity of yttrium oxide is 27 W/(m·K). Applications Phosphors Yttrium oxide is widely used to make Eu:YVO4 and Eu:Y2O3 phosphors that give the red color in color TV picture tubes. Yttria lasers Y2O3 is a prospective solid-state laser material. In particular, lasers with ytterbium as dopant allow the efficient operation both in continuous operation and in pulsed regimes. At high concentration of excitations (of order of 1%) and poor cooling, the quenching of emission at laser frequency and avalanche broadband emission takes place. (Yttria-based lasers are not to be confused with YAG lasers using yttrium aluminium garnet, a widely used crystal host for rare earth laser dopants). Gas lighting The original use of the mineral yttria and the purpose of its extraction from mineral sources was as part of the process of making gas mantles and other products for turning the fla ...
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Yttria-stabilized Zirconia
Yttria-stabilized zirconia (YSZ) is a ceramic in which the cubic crystal structure of zirconium dioxide is made stable at room temperature by an addition of yttrium oxide. These oxides are commonly called "zirconia" ( Zr O2) and "yttria" ( Y2 O3), hence the name. Stabilization Pure zirconium dioxide undergoes a phase transformation from monoclinic (stable at room temperature) to tetragonal (at about 1173 °C) and then to cubic (at about 2370 °C), according to the scheme : monoclinic (1173 °C) ↔ tetragonal (2370 °C) ↔ cubic (2690 °C) ↔ melt. During these transformations, zirconia can experience volume expansion of up to 5-6%. This change can induce internal stresses, leading to cracking or fracture in ceramic materials. Obtaining stable sintered zirconia ceramic products is difficult because of the large volume change, about 5%, accompanying the transition from tetragonal to monoclinic. Stabilization of the cubic polymorph of zirconia over ...
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Yttriaite-(Y)
Yttriaite-(Y) is an exceedingly rare mineral, a natural form of yttrium oxide, Y2O3.Mills, S.J., Kartashov, P.M., Ma, C., Rossman, G.R., Novgorodova, M.I., Kampf, A.R., and Raudsepp, M., 2011: Yttriaite-(Y): The natural occurrence of Y2O3 from the Bol’shaya Pol’ya River, Subpolar Urals, Russia. American Mineralogist 96(7), 1166–1170 In terms of chemistry it is yttrium-analogue of kangite, arsenolite, avicennite and senarmontite (isometric minerals). Other minerals with the general formula A2O3 include corundum, bismite, bixbyite, eskolaite, hematite, karelianite, sphaerobismoite, tistarite, and valentinite Valentinite is an Antimony trioxide, antimony oxide mineral with formula antimony, Sb2oxygen, O3. Valentinite crystallizes in the orthorhombic system and typically forms as radiating clusters of euhedral crystals or as fibrous masses. It is colorl ....Mindat, Tistarite, http://www.mindat.org/min-38695.html Yttriaite-(Y) forms tiny inclusions in native tungsten. Refer ...
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Yttrium
Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Crust (geology), Earth's crust. The most important present-day use of yttrium is as a component of phosphors, especially those used in LEDs. Historically, it was once widely used in the red phosphors in television set cathode ray tube displays. Yttrium is also used in the production of electrodes, electrolytes, electronic filters, lasers, superconductors, various medical applications, and Trace element, tracing various materials to enhance their properties. Yttrium has no known Biology, biological role. Exposure to yttrium compounds can cause Respiratory ...
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Zirconium Oxide
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zirconium silicate or zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mi ...
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CRC Press
The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information technology. CRC Press is now a division of Taylor & Francis, itself a subsidiary of Informa. History The CRC Press was founded as the Chemical Rubber Company (CRC) in 1903 by brothers Arthur, Leo and Emanuel Friedman in Cleveland, Ohio, based on an earlier enterprise by Arthur, who had begun selling rubber laboratory aprons in 1900. The company gradually expanded to include sales of laboratory equipment to chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...s. In 1913 the CRC offered a short (116-page) manual called the ''Rubber Handboo ...
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Yttrium Aluminium Garnet
Yttrium aluminium garnet (YAG, Yttrium, Y3Aluminium, Al5Oxygen, O12) is a synthetic crystalline material of the garnet group. It is a Crystal system, cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a Crystal system, hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM). Due to its broad optical transparency, low internal stress, high hardness, chemical and heat resistance, YAG is used for a variety of optics. Its lack of birefringence (unlike sapphire) makes it an interesting material for high-energy/high-power laser systems. Laser damage threshold, Laser damage levels of YAG ranged from 1.1 to 2.2 kJ/cm2 (1064 nm, 10 ns). YAG, like garnet and sapphire, has no uses as a laser medium when pure. However, after being doped with an appropriate ion, YAG is commonly used as a host material in various solid-state lasers. Rare earth elements such as neodymium and erbium can be doping (semiconductors), doped into ...
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Tungsten
Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first isolated as a metal in 1783. Its important ores include scheelite and wolframite, the latter lending the element its alternative name. The free element is remarkable for its robustness, especially the fact that it has the highest melting point of all known elements, melting at . It also has the highest boiling point, at . Its density is 19.254 g/cm3, comparable with that of uranium and gold, and much higher (about 1.7 times) than that of lead. Polycrystalline tungsten is an intrinsically brittle and hard material (under standard conditions, when uncombined), making it difficult to work into metal. However, pure single-crystalline tungsten is more ductile and can be cut with a hard-steel hacksaw. Tungsten occurs in many alloys ...
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Astronomical Unit
The astronomical unit (symbol: au or AU) is a unit of length defined to be exactly equal to . Historically, the astronomical unit was conceived as the average Earth-Sun distance (the average of Earth's aphelion and perihelion), before its modern redefinition in 2012. The astronomical unit is used primarily for measuring distances within the Solar System or around other stars. It is also a fundamental component in the definition of another unit of astronomical length, the parsec. One au is approximately equivalent to 499 light-seconds. History of symbol usage A variety of unit symbols and abbreviations have been in use for the astronomical unit. In a 1976 resolution, the International Astronomical Union (IAU) had used the symbol ''A'' to denote a length equal to the astronomical unit. In the astronomical literature, the symbol AU is common. In 2006, the International Bureau of Weights and Measures (BIPM) had recommended ua as the symbol for the unit, from the French ...
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Ammonium Chloride
Ammonium chloride is an inorganic chemical compound with the chemical formula , also written as . It is an ammonium salt of hydrogen chloride. It consists of ammonium cations and chloride anions . It is a white crystalline salt (chemistry), salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. In its naturally occurring mineralogic form, it is known as salammoniac. The mineral is commonly formed on burning coal dumps from condensation of coal-derived gases. It is also found around some types of volcanic vents. It is mainly used as fertilizer and a flavouring agent in Salty liquorice, some types of liquorice. It is a product of the reaction of hydrochloric acid and ammonia. Production It is a product of the Solvay process used to produce sodium carbonate: :CO2 + 2 NH3 + 2 NaCl + H2O → 2 NH4Cl + Na2CO3 Not only is that method the principal one for the manufacture of ammonium chloride, but also it is used to minimize ammonia release in some ind ...
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Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. Etymology Because it was produced from halite, rock salt according to the methods of Johann Rudolph Glauber, hydrochloric acid was historically called by European alchemists ''spirits of salt'' or ''acidum salis'' (salt acid). Both names are still used, especially in other languages, such as , , , , , , , , , , (''ensan''), zh, 盐酸 (''yánsuān''), and (''yeomsan''). Gaseous HCl was called ''marine acid air''. The name ''muriatic acid'' has the same origin (''muriatic'' means "pertaining to brine or salt", hence ''muriate'' means hydrochloride), and this ...
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Yttrium(III) Chloride
Yttrium(III) chloride is an inorganic compound of yttrium and chloride. It exists in two forms, the hydrate (YCl3(H2O)6) and an anhydrous form (YCl3). Both are colourless salts that are highly soluble in water and deliquescent. Structure Solid YCl3 adopts a cubic structure with close-packed chloride ions and yttrium ions filling one third of the octahedral holes and the resulting YCl6 octahedra sharing three edges with adjacent octahedra, giving it a layered structure. This structure is shared by a range of compounds, notably AlCl3. Preparation and reactions YCl3 is often prepared by the "ammonium chloride Ammonium chloride is an inorganic chemical compound with the chemical formula , also written as . It is an ammonium salt of hydrogen chloride. It consists of ammonium cations and chloride anions . It is a white crystalline salt (chemistry), sal ... route," starting from either Y2O3 or hydrated chloride or oxychloride. or YCl3·6H2O. These methods produce (NH4)2 Cl5 :10 N ...
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