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The art of kalai (kalhai or qalai) is the process of coating an
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
surface such as
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
or
brass Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
by deposition of metal tin on it. The word "kalai" is derived from
Sanskrit Sanskrit (; stem form ; nominal singular , ,) is a classical language belonging to the Indo-Aryan languages, Indo-Aryan branch of the Indo-European languages. It arose in northwest South Asia after its predecessor languages had Trans-cultural ...
word ''kalya lepa'', which means "white wash or tin". A cultural Sanskrit work by Keladi Basava called "Sivatattva Ratnakara" (1699) mentions "kalaya-lepa" in the chapter of cookery or "''supashashtra''" which means applying kalai on utensils. People practicing the art of kalai are called Kalaiwala or Kalaigar. Basically, Kalaigars or Kalaiwalas are community craftsmen.


History

Vessels with kalai, both on its interior and exterior have been found in the excavations of Bramhapuri at
Kolhapur Kolhapur () is a city on the banks of the Panchganga River in the southern part of the Indian state of Maharashtra. Kolhapur is one of the most significant cities in South Maharashtra and has been a hub of historical, religious, and cultural a ...
,
Maharashtra Maharashtra () is a state in the western peninsular region of India occupying a substantial portion of the Deccan Plateau. It is bordered by the Arabian Sea to the west, the Indian states of Karnataka and Goa to the south, Telangana to th ...
which adds to the archeological evidence of kalai art. From this evidence, P K. Gode, who studied tin coating on metallic vessels in
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
, stated that the history of tin coating dates back to 1300 C.E. The history of kalai is also recorded in “Parsibhashanushasana” of Vikaramasimha (before Samvat 1600 i.e. C.E. 1544) and also in the famous Ain- I -Akbari (C.E. 1590) by Abul Fazal.


Spiritual approach

The copper vessels with kalai were used to store water and cook food earlier because of a spiritual belief that copper attracts and transmits a divine consciousness also called “Chaitanya”. The spiritual approach to the use of copper vessels to store water is that copper and tin have Sattva-Raja (the basic component of creation/universe) component that is transferred to water.


Scientific approach

Earlier, copper and brass vessels were used because of their high conductivity. High conductivity of copper vessels reduces the fuel cost. However, a chemical reaction between copper and oxygen called oxidization turns the copper vessels black. Copper also reacts with the moisture in air and creates copper carbonate, which can be noticed as light green rust on the surface. Copper carbonate is poisonous and can make a person severely ill if it gets mixed with food. The copper can get dissolved in water in trace amounts when the water is stored in copper vessels for a long period of time. The process is known as the “ oligodynamic effect”. Kalai protects from food poisoning and blackening of copper vessels by preventing direct contact of air with the copper or brass surface. Tin is also a good conductor of heat like copper, hence applying kalai does not result in loss of heat conductivity for the utensil. The kalai is required to be done on the vessels approximately every two months. Tin will melt if the temperature is above 425 degrees Fahrenheit (218.333 degrees Celsius). Also, the tin coating wears away with time. In order to protect the coating, one should use wooden or
silicone In Organosilicon chemistry, organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (, where R = Organyl group, organic group). They are typically colorless oils or elastomer, rubber ...
spatulas and avoid cooking acidic foods.


Process

Kalai
can be done in various ways. Virgin grade tin (called ‘ranga’ in
Hindi Modern Standard Hindi (, ), commonly referred to as Hindi, is the Standard language, standardised variety of the Hindustani language written in the Devanagari script. It is an official language of India, official language of the Government ...
), caustic soda, sal ammoniac (
ammonium chloride Ammonium chloride is an inorganic chemical compound with the chemical formula , also written as . It is an ammonium salt of hydrogen chloride. It consists of ammonium cations and chloride anions . It is a white crystalline salt (chemistry), sal ...
, called ‘nausadar’ powder in Hindi), and water are used in the process. The first step of kalai is to clean the utensil with water. There are two ways of cleaning the utensil further to remove any impurities such as dust. The first is to clean it with caustic soda. The other is to wash it with dilute acid solution which contains a gold purifying compound known as ‘sufa’. If the latter is used, the utensil should be cleaned immediately after applying the dilute acidic solution as it may bear a mark if not done immediately. After the cleaning, the vessel is heated on burning coal for about 2 to 3 minutes. The Kalaiwala, Kalaigar or Kalaikar then digs a small pit in the ground to burn the coal. He/she prepares a temporary
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being supplied above atmospheric pressure. In a ...
to do kalai and blows air through bellows. After the vessel turns pinkish hot, virgin grade tin (in the form of strips) is applied on the hot vessel. This step is called ‘casting’ by the Kalaigars. The ‘nausadar’ powder is sprinkled on the vessel. The tin melts rapidly which is then rubbed evenly on the utensil with the help of a cotton cloth or a swab of cotton. The rubbing process is known as ‘majaay’ in Hindi. A whitish smoke with the peculiar smell of
ammonia Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...
is released when the ‘nausadar’ powder is rubbed on the utensil. A silvery lining appears on the vessel with a shine. The final step of kalai is to dip the utensil in cold water.


Present scenario

Kalai was earlier done with
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
instead of tin but now it would be too expensive. As
stainless steel Stainless steel, also known as inox, corrosion-resistant steel (CRES), or rustless steel, is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Stainless steel's resistance to corrosion comes from its chromi ...
and
aluminum Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
ware came into being, the usage of copper and brass utensils decreased, which led the Kalaigars to suffer losses. Nowadays only some hotels and a very few people use vessels with kalai. As a result, there are a very few Kalaigars left and the art of kalai is vanishing.


References

{{reflist Alloys Copper Brass Tin