Johannes Nicolaus Brønsted
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Johannes Nicolaus Brønsted (; 22 February 1879 – 17 December 1947) was a Danish physical chemist who is best known for developing the
Brønsted–Lowry acid–base theory The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was developed independently in 1923 by physical chemists Johannes Nicolaus Brønsted (in Denmark) and Thomas Martin Lowry (in ...
; he developed the theory at the same time as (but independently of) Martin Lowry.


Biography

Brønsted was born in Varde,
Denmark Denmark is a Nordic countries, Nordic country in Northern Europe. It is the metropole and most populous constituent of the Kingdom of Denmark,, . also known as the Danish Realm, a constitutionally unitary state that includes the Autonomous a ...
on 22 February 1879. His mother died shortly after his birth, and his father died when Brønsted was 14 years old; he then moved to Copenhagen with his older sister and his stepmother. In 1897, Brønsted began his studies as a chemical engineer at the Polytechnic Institute in
Copenhagen Copenhagen ( ) is the capital and most populous city of Denmark, with a population of 1.4 million in the Urban area of Copenhagen, urban area. The city is situated on the islands of Zealand and Amager, separated from Malmö, Sweden, by the ...
. After his first degree, Brønsted changed fields and received his
magister degree A magister degree (also magistar, female form: magistra; from , "teacher") is an academic degree used in various systems of higher education. The magister degree arose in medieval universities in Europe and was originally equal to the doctorate; ...
in
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
in 1902 from the
University of Copenhagen The University of Copenhagen (, KU) is a public university, public research university in Copenhagen, Copenhagen, Denmark. Founded in 1479, the University of Copenhagen is the second-oldest university in Scandinavia, after Uppsala University. ...
. In 1905, he became an assistant at the Chemical Institute and obtained his doctoral degree in 1908. In the same year, Brønsted became a professor of physical and
inorganic chemistry Inorganic chemistry deals with chemical synthesis, synthesis and behavior of inorganic compound, inorganic and organometallic chemistry, organometallic compounds. This field covers chemical compounds that are not carbon-based, which are the subj ...
at the
University of Copenhagen The University of Copenhagen (, KU) is a public university, public research university in Copenhagen, Copenhagen, Denmark. Founded in 1479, the University of Copenhagen is the second-oldest university in Scandinavia, after Uppsala University. ...
. In 1929, Brønsted was a visiting professor at
Yale University Yale University is a Private university, private Ivy League research university in New Haven, Connecticut, United States. Founded in 1701, Yale is the List of Colonial Colleges, third-oldest institution of higher education in the United Stat ...
. His research gained worldwide recognition, resulting in four
Nobel Prize The Nobel Prizes ( ; ; ) are awards administered by the Nobel Foundation and granted in accordance with the principle of "for the greatest benefit to humankind". The prizes were first awarded in 1901, marking the fifth anniversary of Alfred N ...
nominations, a gold H. C. Ørsted Medal and being appointed as a fellow of the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
and a member of the
National Academy of Sciences The National Academy of Sciences (NAS) is a United States nonprofit, NGO, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the ...
. Brønsted married Charlotte Warberg, whom he met during his first degree. The couple had four children. In
World War II World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
, Brønsted's opposition to the
Nazis Nazism (), formally named National Socialism (NS; , ), is the far-right politics, far-right Totalitarianism, totalitarian socio-political ideology and practices associated with Adolf Hitler and the Nazi Party (NSDAP) in Germany. During H ...
led to his election to the Danish parliament in 1947, but he was too ill to take his seat and died shortly after the election.


Research

Early in his career, Brønsted studied
chemical thermodynamics Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measure ...
and later studied
electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...
solutions and carried out an extensive series of solubility measurements. These measurements led him to establish general laws which were later confirmed when the Debye–Hückel theory was proposed. Brønsted is best known for his work on reaction kinetics, in particular
acid–base reaction In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms an ...
s. In 1923, he recognized that acid–base reactions involved the transfer of a proton, from the
acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
(proton donor) to the base (proton acceptor). Almost simultaneously and independently, the British chemist Martin Lowry arrived at the same conclusion, thus the name
Brønsted–Lowry acid–base theory The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was developed independently in 1923 by physical chemists Johannes Nicolaus Brønsted (in Denmark) and Thomas Martin Lowry (in ...
. Also in 1923, Gilbert N. Lewis proposed an
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
ic theory of acid–base reactions, but both theories remain commonly used. Later in his career, Brønsted kept studying reaction kinetics, with a special focus on reactions taking place in non-aqueous solutions. He also developed some work about the effect of molecular size on the thermodynamical properties of hydrocarbons, polymers and colloids. He also worked with the Nobel prize winner George de Hevesy on isotope separation by fractional distillation.


References

{{DEFAULTSORT:Bronsted, Johannes Nicolaus 1879 births 1947 deaths People from Varde Municipality Danish physical chemists University of Copenhagen alumni Academic staff of the University of Copenhagen Foreign associates of the National Academy of Sciences Danish chemists