In
thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws o ...
, an isochoric process, also called a constant-volume process, an isovolumetric process, or an isometric process, is a
thermodynamic process during which the
volume
Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). Th ...
of the
closed system undergoing such a process remains constant. An isochoric process is exemplified by the heating or the cooling of the contents of a sealed,
inelastic container: The thermodynamic process is the addition or removal of heat; the isolation of the contents of the container establishes the closed system; and the inability of the container to
deform imposes the constant-volume condition. The isochoric process here should be a
quasi-static process.
Formalism
An isochoric thermodynamic
quasi-static process is characterized by constant
volume
Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). Th ...
, i.e., .
The process does no
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
-volume
work, since such work is defined by
where is pressure. The sign convention is such that positive work is performed by the system on the environment.
If the process is not quasi-static, the work can perhaps be done in a volume constant thermodynamic process.
For a
reversible process, the
first law of th