Hauyne or haüyne, also called hauynite or haüynite ( ), is a

tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consi ...

sulfate The sulfate or sulphate ion is a polyatomic ion, polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salt (chemistry), ...

mineral with

endmember An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of ...

formula . As much as 5 wt % may be present, and also and Cl. It is a

feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing pri ...

and a member of the

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of th ...

group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy,Farndon and Parker (2009). Minerals, Rocks and Fossils of the World. Lorenz Books and was named in 1807 by Brunn-Neergard for the French crystallographer

René Just Haüy René Just Haüy () FRS MWS FRSE (28 February 1743 – 1 June 1822) was a French priest and mineralogist, commonly styled the Abbé Haüy after he was made an honorary canon of Notre Dame. Due to his innovative work on crystal structure and hi ...

(1743–1822). It is sometimes used as a gemstone.

Sodalite group

Formulae: *haüyne *

nosean Nosean, also known as noselite, is a mineral of the feldspathoid group with formula: Na8 Al6 Si6 O24( SO4). H2O. It forms isometric crystals of variable color: white, grey, blue, green, to brown. It has a Mohs hardness of 5.5 to 6 and a specific ...

lazurite Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula . It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usually ...

* tsaregorodtsevite *

tugtupite Tugtupite is a beryllium aluminium tectosilicate. It also contains sodium and chlorine and has the formula Na4 Al Be Si4 O12 Cl. Tugtupite is a member of the silica-deficient feldspathoid mineral group. It occurs in high alkali intrusive igneous ...

* vladimirivanovite All these minerals are

s. Haüyne forms a

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...

with nosean and with sodalite. Complete solid solution exists between synthetic nosean and haüyne at 600 °C, but only limited solid solution occurs in the sodalite-nosean and sodalite-haüyne systems.Bellatreccia, Della Ventura, Piccinini, Cavallo and Brilli (2009): H₂O and CO₂ in minerals of the haüyne-sodalite group: an FTIR spectroscopy study. Mineralogical Magazine 73:399-413 The characteristic blue color of sodalite-group minerals arises mainly from caged and clusters.

Unit cell

Haüyne belongs to the hexatetrahedral class of the isometric system, 3m,

space group In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it ...

P3n. It has one formula unit per

unit cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector, for example) does not necessari ...

(Z = 1), which is a

cube In geometry, a cube is a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex. Viewed from a corner it is a hexagon and its net is usually depicted as a cross. The cube is the on ...

with side length of 9 Å. More accurate measurements are as follows: *a = 8.9 Å *a = 9.08 to 9.13 Å *a = 9.10 to 9.13 Å *a = 9.11(2) Å *a = 9.116 Å *a = 9.13 ÅDeer Howie and Zussman (1963) Rock-forming minerals, Volume 4, Framework Silicates, pages 289 to 302

Structure

All

silicates In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name i ...

have a basic structural unit that is a

tetrahedron In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the ...

with an

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...

O at each apex, and a

silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...

ion Si in the middle, forming (SiO₄)⁴⁻. In

tectosilicates Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consi ...

(framework silicates) each oxygen ion is shared between two tetrahedra, linking all the tetrahedra together to form a framework. Since each O is shared between two tetrahedra only half of it "belongs" to the Si ion in either tetrahedron, and if no other components are present then the formula is SiO₂, as in

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

Aluminium Aluminium (aluminum in AmE, American and CanE, Canadian English) is a chemical element with the Symbol (chemistry), symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately o ...

ions Al, can substitute for some of the silicon ions, forming (AlO₄)⁵⁻ tetrahedra. If the substitution is random the ions are said to be disordered, but in haüyne the Al and Si in the tetrahedral framework are fully ordered. Si has a charge 4+, but the charge on Al is only 3+. If all the

cations An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

(positive ions) are Si then the positive charges on the Si's exactly balance the negative charges on the O's. When Al replaces Si there is a deficiency of positive charge, and this is made up by extra positively charged ions (cations) entering the structure, somewhere in between the tetrahedra. In haüyne these extra cations are

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...

Na⁺ and

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

Ca²⁺, and in addition the negatively charged

group (SO₄)²⁻ is also present. In the haüyne structure the tetrahedra are linked to form six-membered rings that are stacked up in an ..ABCABC.. sequence along one direction, and rings of four tetrahedra are stacked up parallel to another direction. The resulting arrangement forms continuous channels that can accommodate a large variety of

and

anions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

Appearance

Haüyne crystallizes in the isometric system forming rare

dodecahedral In geometry, a dodecahedron (Greek , from ''dōdeka'' "twelve" + ''hédra'' "base", "seat" or "face") or duodecahedron is any polyhedron with twelve flat faces. The most familiar dodecahedron is the regular dodecahedron with regular pentag ...

or pseudo-

octahedral In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at ea ...

crystals that may reach 3 cm across; it also occurs as rounded grains. The crystals are transparent to translucent, with a vitreous to greasy luster. The color is usually bright blue, but it can also be white, grey, yellow, green and pink. In

thin section In optical mineralogy and petrography, a thin section (or petrographic thin section) is a thin slice of a rock or mineral sample, prepared in a laboratory, for use with a polarizing petrographic microscope, electron microscope and electron m ...

the crystals are colorless or pale blue, and the streak is very pale blue to white.

Optical properties

Haüyne is isotropic. Truly isotropic minerals have no

birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefrin ...

, but haüyne is weakly birefringent when it contains inclusions. The

refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, o ...

is 1.50; although this is quite low, similar to that of ordinary window glass, it is the largest value for minerals of the sodalite group. It may show reddish orange to purplish pink

fluorescence Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, ...

under longwave

ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiati ...

light.

Physical properties

Cleavage is distinct to perfect, and twinning is common, as contact, penetration and polysynthetic twins. The fracture is uneven to

conchoidal Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically slig ...

, the mineral is

brittle A material is brittle if, when subjected to stress, it fractures with little elastic deformation and without significant plastic deformation. Brittle materials absorb relatively little energy prior to fracture, even those of high strength. ...

, and it has

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion (mechanical), abrasion. In general, different materials differ in their hardn ...

to 6, almost as hard as

feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feld ...

. All the members of the sodalite group have quite low densities, less than that of

; haüyne is the densest of them all, but still its

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

is only 2.44 to 2.50. If haüyne is placed on a glass slide and treated with

nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available ni ...

HNO₃, and then the solution is allowed to evaporate slowly,

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...

needles of

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and dr ...

form. This distinguishes haüyne from

, which forms cubic crystals of

chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chl ...

under the same conditions. The mineral is not

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...

Geological setting and associations

Haüyne occurs in

phonolite Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneou ...

s and related

leucite Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster ...

- or

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatit ...

-rich,

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is o ...

-poor,

igneous rocks Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or l ...

; less commonly in nepheline-free

extrusive Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In contras ...

s and

metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, cau ...

(

marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorpho ...

). Associated minerals include

, titanian

andradite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".melilite,

augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group ...

sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal syste ...

biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more alum ...

phlogopite Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O ...

and

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common ...

Localities

The

type locality Type locality may refer to: * Type locality (biology) * Type locality (geology) See also * Local (disambiguation) * Locality (disambiguation) {{disambiguation ...

Lake Nemi Lake Nemi ( it, Lago di Nemi, la, Nemorensis Lacus, also called Diana's Mirror, la, Speculum Dianae) is a small circular volcanic lake in the Lazio region of Italy south of Rome, taking its name from Nemi, the largest town in the area, that ...

, Alban Hills, Rome Province, Latium, Italy. Occurrences include: *Canary Islands: A pale blue mineral intermediate between haüyne and

has been found in

spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties ...

dunite Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with ...

xenoliths A xenolith ("foreign rock") is a rock fragment (country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ign ...

from

La Palma La Palma (, ), also known as ''La isla bonita'' () and officially San Miguel de La Palma, is the most north-westerly island of the Canary Islands, Spain. La Palma has an area of making it the fifth largest of the eight main Canary Islands. The ...

, Canary Islands.Wulff-Pedersen et al (2000) American Mineralogist 85:1397-1405 *Ecuador: Phenocrysts found in alkaline extrusive rocks (

tephrite Tephrite is an igneous, volcanic ( extrusive) rock, with aphanitic to porphyritic texture. Mineral content is usually abundant feldspathoids (leucite or nepheline), plagioclase, and lesser alkali feldspar. Pyroxenes (clinopyroxenes) are comm ...

), product of effusive volcanism of the Sumaco volcano, of northeast

Ecuador Ecuador ( ; ; Quechuan languages, Quechua: ''Ikwayur''; Shuar language, Shuar: ''Ecuador'' or ''Ekuatur''), officially the Republic of Ecuador ( es, República del Ecuador, which literally translates as "Republic of the Equator"; Quechuan ...

. *Germany: In ejected rocks of

hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic ro ...

-haüyne-

scapolite The scapolites (Gr. σκάπος, rod, and λίθος, stone) are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite () and marial ...

rock from the Laach lake volcanic complex, Eifel, Rhineland-Palatinate *Italy: Anhedral blue to dark grey

phenocrysts 300px, Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter 2.3 cm) for scale. A phenocryst is an early forming, relativ ...

- melilite-bearing

lava Lava is molten or partially molten rock ( magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or ...

at Monte Vulture, Melfi, Basilicata, Potenza *Italy: Millimetric transparent blue crystals in ejecta consisting mainly of K-feldspar and plagioclase from Albano Laziale, Roma *Italy: Ejected blocks in the

peperino Peperino is an Italian word describing a brown or grey volcanic tuff, containing fragments of basalt and limestone, with disseminated crystals of augite, mica, magnetite, leucite, and other similar minerals. The name originally referred to the d ...

of the Alban Hills, Rome Province, Latium, contain white

haüyne associated with

garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...

, melilite and latiumite. *US: Haüyne of metamorphic origin occurs at the Edwards Mine, St. Lawrence County, New York. *US: Haüyne occurs in nepheline alnoite with melilite,

and

Winnett Winnett is a town in and the county seat of Petroleum County, Montana, United States. The population was 188 at the 2020 census. History Winnett was named for Walter John Winnett, who was born at the Queen's Hotel in Toronto, Ontario, Cana ...

Petroleum County, Montana Petroleum County is a county in the U.S. state of Montana. As of the 2020 census, the population was 496, making it the least populous county in Montana and the eighth-least populous in the United States. Its county seat is Winnett. The county ...

, US. *US: Haüyne is common in small quantities as

and

lamprophyre Lamprophyres () are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica- undersaturated mafic or ultramafic rocks with high magne ...

at the

Cripple Creek, Colorado Cripple Creek is a statutory city that is the county seat of Teller County, Colorado, United States. The city population was 1,155 at the 2020 United States Census. Cripple Creek is a former gold mining camp located southwest of Colorado Spri ...

Mining District, Colorado, US.Carnein and Bartos (2005) Mineralogical Record 36-2:173

References

{{reflist

External links

JMol: http://rruff.geo.arizona.edu/AMS/viewJmol.php?id=05334 V. Nasti, "L’olotipo dell'haüyna" (2009), Il Cercapietre, Notiziario del Gruppo Mineralogico Romano, n. 1-2/2009, pagg.16-43. Feldspathoid Sodalite group Sodium minerals Calcium minerals Aluminium minerals Cubic minerals Minerals in space group 218 Luminescent minerals Gemstones