Daubréelite is a rare

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide () as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenide mineral, selenides, the tell ...

. It crystallizes with cubic symmetry and has chemical composition of Fe²⁺Cr³⁺₂S₄. It usually occurs as black platy aggregates.

Naming and history

Daubréelite was named after the French

mineralogist Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...

petrologist Petrology () is the branch of geology that studies rocks, their mineralogy, composition, texture, structure and the conditions under which they form. Petrology has three subdivisions: igneous, metamorphic, and sedimentary petrology. Igneous an ...

and meteoriticist

Gabriel Auguste Daubrée Gabriel Auguste Daubrée MIF FRS FRSE (25 June 181429 May 1896) was a French geologist, best known for applying experimental methods to structural geology. He served as the director of the École des Mines as well as the president of the Frenc ...

. The mineral was first described in 1876 in the ''American Journal of Science''. Its type locality is the

Coahuila meteorite Coahuila, formally Coahuila de Zaragoza, officially the Free and Sovereign State of Coahuila de Zaragoza, is one of the 31 states of Mexico. The largest city and State Capital is the city of Saltillo; the second largest is Torreón and the thir ...

, Bolsom de Mapimí,

Coahuila Coahuila, formally Coahuila de Zaragoza, officially the Free and Sovereign State of Coahuila de Zaragoza, is one of the 31 states of Mexico. The largest city and State Capital is the city of Saltillo; the second largest is Torreón and the thi ...

Mexico Mexico, officially the United Mexican States, is a country in North America. It is the northernmost country in Latin America, and borders the United States to the north, and Guatemala and Belize to the southeast; while having maritime boundar ...

Classification

In the Nickel-Strunz classification daubréelite is part of the "Sulfides and Sulfosalts" and further a "metal sulfide with a metal-sulfide ratio of 3:4 and 2:3".

Occurrences

Daubréelite is found in

iron meteorite Iron meteorites, also called siderites or ferrous meteorites, are a type of meteorite that consist overwhelmingly of an iron–nickel alloy known as meteoric iron that usually consists of two mineral phases: kamacite and taenite. Most iron me ...

s as an inclusion in

meteoric iron Meteoric iron, sometimes meteoritic iron, is a native metal and early-universe protoplanetary-disk remnant found in meteorites and made from the elements iron and nickel, mainly in the form of the mineral phases kamacite and taenite. Meteoric ...

(

kamacite Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:ni ...

and

taenite Taenite is a mineral found naturally on Earth mostly in iron meteorites. It is an alloy of iron and nickel, with a chemical formula of and nickel proportions of 20% up to 65%. The name is derived from the Greek ταινία for "band, ribbo ...

). Further paragenetic minerals are alabandine, enstatite,

graphite Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...

plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

and

schreibersite Schreibersite is generally a rare iron nickel phosphide mineral, , though common in iron-nickel meteorites. It has been found on Disko Island in Greenland and Illinois. Another name used for the mineral is rhabdite. It forms tetragonal crystals ...

. According to one source daubréelite has been described from 34 localities. Some notable examples being the Hoba meteorite and the Canyon Diablo meteorite. The mineral was also found in the

Hadley Rille meteorite The Hadley Rille meteorite was a meteorite discovered on the Moon at coordinates 26° 26' 0" N, 3° 39' 20" E, or Station 9A, during the Apollo 15 mission in 1971. It was the second meteorite to be discovered on a Solar System body other than the ...

which was retrieved by the

Apollo 15 Apollo 15 (July 26August 7, 1971) was the ninth crewed mission in the Apollo program and the fourth Moon landing. It was the first List of Apollo missions#Alphabetical mission types, J mission, with a longer stay on the Moon and a greate ...

mission in the Rima Hadley (

Mare Imbrium Mare Imbrium (Latin ''imbrium'', the "Sea of Showers" or "Sea of Rains") is a vast lunar mare, lava plain within the Imbrium Basin on the Moon and is one of the larger craters in the Solar System. The Imbrium Basin formed from the collision ...

Crystallography

Daubréelite crystallizes with cubic symmetry with the space group ''F''d''m'' (4/''m'' 2/''m''). There are 8

formula unit In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. It can also refer to the chemical formula for that unit. Those structures do not consist of discrete mol ...

s in one

primitive cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector, for example) does not necessaril ...

References

{{DEFAULTSORT:Daubreelite Meteorite minerals Cubic minerals Minerals in space group 227

Naming and history

Classification

Occurrences

Crystallography

See also

References