Daubréeite is a rare

bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs ...

oxohalide In chemistry, molecular oxohalides (oxyhalides) are a group of chemical compounds in which both oxygen and halogen atoms are attached to another chemical element A in a single molecule. They have the general formula , where X = fluorine (F), chlor ...

mineral with formula . It is a creamy-white to yellow-brown, soft, earthy clay–like mineral which crystallizes in the

tetragonal crystal system In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a squ ...

. It is a member of the matlockite group. It was first described for an occurrence in the Constanicia mine, Tazna,

Bolivia , image_flag = Bandera de Bolivia (Estado).svg , flag_alt = Horizontal tricolor (red, yellow, and green from top to bottom) with the coat of arms of Bolivia in the center , flag_alt2 = 7 × 7 square p ...

, in 1876. It was named for French mineralogist

Gabriel Auguste Daubrée Gabriel Auguste Daubrée MIF FRS FRSE (25 June 181429 May 1896) was a French geologist, best known for applying experimental methods to structural geology. He served as the director of the École des Mines as well as the president of the French ...

(1814–1896). At the Tanza location it occurs as a secondary mineral formed by the

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

of native bismuth or

bismuthinite Bismuthinite is a mineral consisting of bismuth sulfide ( Bi2 S3). It is an important ore for bismuth. The crystals are steel-grey to off-white with a metallic luster. It is soft enough to be scratched with a fingernail and rather dense. Bism ...

. It occurs with

clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...

s. In addition to its discovery location it has also been reported from the Tintic District in the

East Tintic Mountains The East Tintic Mountains are a mountain range in central Juab, Utah, and Tooele counties in Utah, United States on the east margin of the Great Basin just west of the Wasatch Front about south-southeast of Salt Lake City. The community of Eur ...

Juab County Juab County ( ) is a county in western Utah, United States. As of the 2010 United States Census, the population was 10,246. Its county seat and largest city is Nephi. Juab County is part of the Provo–Orem, Utah Metropolitan Statistica ...

Utah Utah ( , ) is a state in the Mountain West subregion of the Western United States. Utah is a landlocked U.S. state bordered to its east by Colorado, to its northeast by Wyoming, to its north by Idaho, to its south by Arizona, and to its ...

; in the Josephine Creek District of

Josephine County, Oregon Josephine County is one of the 36 counties in the U.S. state of Oregon. As of the 2020 census, the population was 88,090. The county seat is Grants Pass. The county is probably named after a stream in the area called Josephine Creek, which ...

; in the Manhattan District of

Nye County, Nevada Nye County is a county in the U.S. state of Nevada. As of the 2020 census, the population was 51,591. Its county seat is Tonopah. At , Nye is Nevada's largest county by area and the third-largest county in the contiguous United States, be ...

; and the Rio Marina Mine on

Elba Elba ( it, isola d'Elba, ; la, Ilva) is a Mediterranean island in Tuscany, Italy, from the coastal town of Piombino on the Italian mainland, and the largest island of the Tuscan Archipelago. It is also part of the Arcipelago Toscano Nation ...

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...

References

Oxide minerals Halide minerals Bismuth minerals Tetragonal minerals Minerals in space group 129 {{oxide-mineral-stub