
In the study of past climates ("
paleoclimatology
Paleoclimatology ( British spelling, palaeoclimatology) is the scientific study of climates predating the invention of meteorological instruments, when no direct measurement data were available. As instrumental records only span a tiny part of ...
"), climate proxies are preserved physical characteristics of the past that stand in for direct meteorological measurements and enable scientists to reconstruct the
climatic conditions over a longer fraction of the Earth's history. Reliable
global records of climate only began in the 1880s, and proxies provide the only means for scientists to determine climatic patterns before record-keeping began.
A large number of climate proxies have been studied from a variety of geologic contexts. Examples of proxies include stable isotope measurements from
ice core
An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier
A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier ...
s, growth rates in
tree rings,
species composition
Relative species abundance is a component of biodiversity and is a measure of how common or rare a species is relative to other species in a defined location or community.Hubbell, S. P. 2001. ''The unified neutral theory of biodiversity and biogeog ...
of
sub-fossil pollen in lake sediment or
foraminifera
Foraminifera ( ; Latin for "hole bearers"; informally called "forams") are unicellular organism, single-celled organisms, members of a phylum or class (biology), class of Rhizarian protists characterized by streaming granular Ectoplasm (cell bio ...
in ocean sediments, temperature profiles of
borehole
A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as petr ...
s, and stable isotopes and mineralogy of
coral
Corals are colonial marine invertebrates within the subphylum Anthozoa of the phylum Cnidaria. They typically form compact Colony (biology), colonies of many identical individual polyp (zoology), polyps. Coral species include the important Coral ...
s and carbonate
speleothems
A speleothem (; ) is a geological formation made by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depend ...
. In each case, the proxy indicator has been influenced by a particular seasonal climate parameter (e.g., summer temperature or monsoon intensity) at the time in which they were laid down or grew. Interpretation of climate proxies requires a range of ancillary studies, including calibration of the sensitivity of the proxy to climate and cross-verification among proxy indicators.
Proxies can be combined to produce temperature reconstructions longer than the
instrumental temperature record
Global surface temperature (GST) is the average temperature of Earth's surface. More precisely, it is the weighted average of the temperatures over the ocean and land. The former is also called sea surface temperature and the latter is calle ...
and can inform discussions of
global warming
Present-day climate change includes both global warming—the ongoing increase in global average temperature—and its wider effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes ...
and climate history. The geographic distribution of proxy records, just like the instrumental record, is not at all uniform, with more records in the northern hemisphere.
["Borehole Temperatures Confirm Global Warming Pattern."](_blank)
/ref>
Proxies
In science, it is sometimes necessary to study a variable which cannot be measured directly. This can be done by "proxy methods," in which a variable which correlates with the variable of interest is measured, and then used to infer the value of the variable of interest. Proxy methods are of particular use in the study of the past climate, beyond times when direct measurements of temperatures are available.
Most proxy records have to be calibrated against independent temperature measurements, or against a more directly calibrated proxy, during their period of overlap to estimate the relationship between temperature and the proxy. The longer history of the proxy is then used to reconstruct temperature from earlier periods.
Ice cores
Drilling
Ice cores
An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains i ...
are cylindrical samples from within ice sheets
In glaciology, an ice sheet, also known as a continental glacier, is a mass of glacial ice that covers surrounding terrain and is greater than . The only current ice sheets are the Antarctic ice sheet and the Greenland ice sheet. Ice sheets ...
in the Greenland
Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...
, Antarctic
The Antarctic (, ; commonly ) is the polar regions of Earth, polar region of Earth that surrounds the South Pole, lying within the Antarctic Circle. It is antipodes, diametrically opposite of the Arctic region around the North Pole.
The Antar ...
, and North American
North America is a continent in the Northern and Western hemispheres. North America is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the Caribbean Sea, and to the sou ...
regions.[Strom, Robert. ''Hot House.'' p. 255]["Core Location Maps."](_blank)
First attempts of extraction occurred in 1956 as part of the International Geophysical Year
The International Geophysical Year (IGY; ), also referred to as the third International Polar Year, was an international scientific project that lasted from 1 July 1957 to 31 December 1958. It marked the end of a long period during the Cold War w ...
. As original means of extraction, the U.S. Army's Cold Regions Research and Engineering Laboratory used an -long modified electrodrill in 1968 at Camp Century, Greenland
Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...
, and Byrd Station
The Byrd Station is a former research station established by the United States during the International Geophysical Year by U.S. Navy Seabees during Operation Deep Freeze II in West Antarctica. It was a year-round base until 1972, and then se ...
, Antarctica
Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean (also known as the Antarctic Ocean), it contains the geographic South Pole. ...
. Their machinery could drill through of ice
Ice is water that is frozen into a solid state, typically forming at or below temperatures of 0 ° C, 32 ° F, or 273.15 K. It occurs naturally on Earth, on other planets, in Oort cloud objects, and as interstellar ice. As a naturally oc ...
in 40–50 minutes. From 1300 to in depth, core sample
A core sample is a cylindrical section of (usually) a naturally-occurring substance. Most core samples are obtained by drilling with special drills into the substance, such as sediment or rock, with a hollow steel tube, called a core drill. The ...
s were in diameter
In geometry, a diameter of a circle is any straight line segment that passes through the centre of the circle and whose endpoints lie on the circle. It can also be defined as the longest Chord (geometry), chord of the circle. Both definitions a ...
and 10 to long. Deeper samples of 15 to long were not uncommon. Every subsequent drilling
Drilling is a cutting process where a drill bit is spun to cut a hole of circular cross section (geometry), cross-section in solid materials. The drill bit is usually a rotary Cutting tool (machining), cutting tool, often multi-point. The bit i ...
team improves their method with each new effort.
Proxy
The ratio between the 16O and 18O water molecule isotopologues in an ice core
An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier
A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier ...
helps determine past temperatures and snow accumulations. The heavier isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
(18O) condenses more readily as temperatures
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making up a subst ...
decrease and falls more easily as precipitation
In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls from clouds due to gravitational pull. The main forms of precipitation include drizzle, rain, rain and snow mixed ("sleet" in Commonwe ...
, while the lighter isotope (16O) needs colder conditions to precipitate. The farther north
North is one of the four compass points or cardinal directions. It is the opposite of south and is perpendicular to east and west. ''North'' is a noun, adjective, or adverb indicating Direction (geometry), direction or geography.
Etymology
T ...
one needs to go to find elevated levels of the 18O isotopologue, the warmer the period.
In addition to oxygen isotopes, water contains hydrogen isotopes – 1H and 2H, usually referred to as H and D (for deuterium
Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more c ...
) – that are also used for temperature proxies. Normally, ice cores from Greenland are analyzed for δ18O and those from Antarctica for δ-deuterium. Those cores that analyze for both show a lack of agreement. (In the figure, δ18O is for the trapped air, not the ice. δD is for the ice.)
Air bubbles in the ice, which contain trapped greenhouse gases
Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
such as carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
and methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
, are also helpful in determining past climate changes.
From 1989 to 1992, the European Greenland Ice Core Drilling Project drilled in central Greenland
Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...
at coordinates 72° 35' N, 37° 38' W. The ices in that core were 3840 years old at a depth of 770 m, 40,000 years old at 2521 m, and 200,000 years old or more at 3029 m bedrock
In geology, bedrock is solid rock that lies under loose material ( regolith) within the crust of Earth or another terrestrial planet.
Definition
Bedrock is the solid rock that underlies looser surface material. An exposed portion of bed ...
. Ice cores
An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains i ...
in Antarctica can reveal the climate records for the past 650,000 years.
Location map
A map is a symbolic depiction of interrelationships, commonly spatial, between things within a space. A map may be annotated with text and graphics. Like any graphic, a map may be fixed to paper or other durable media, or may be displayed on ...
s and a complete list of U.S. ice core
An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier
A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier ...
drilling sites can be found on the website for the National Ice Core Laboratory.
Tree rings
Dendroclimatology is the science of determining past climates from trees, primarily from properties of the annual tree rings. Tree rings are wider when conditions favor growth, narrower when times are difficult. Two primary factors are temperature and humidity / water availability. Other properties of the annual rings, such as maximum latewood density (MXD) have been shown to be better proxies than simple ring width. Using tree rings, scientists have estimated many local climates for hundreds to thousands of years previous. By combining multiple tree-ring studies (sometimes with other climate proxy records), scientists have estimated past regional and global climates (see Temperature record of the past 1000 years).
Fossil leaves
Paleoclimatologists often use leaf teeth to reconstruct mean annual temperature in past climates, and they use leaf size as a proxy for mean annual precipitation. In the case of mean annual precipitation reconstructions, some researchers believe taphonomic processes cause smaller leaves to be overrepresented in the fossil record, which can bias reconstructions. However, recent research suggests that the leaf fossil record may not be significantly biased toward small leaves. New approaches retrieve data such as content of past atmospheres from fossil leaf stoma
In botany, a stoma (: stomata, from Greek language, Greek ''στόμα'', "mouth"), also called a stomate (: stomates), is a pore found in the Epidermis (botany), epidermis of leaves, stems, and other organs, that controls the rate of gas exc ...
ta and isotope composition, measuring cellular CO2 concentrations. A 2014 study was able to use the carbon-13
Carbon-13 (13C) is a natural, stable isotope of carbon with a nucleus containing six protons and seven neutrons. As one of the environmental isotopes, it makes up about 1.1% of all natural carbon on Earth.
Detection by mass spectrometry
A m ...
isotope ratio
The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundan ...
s to estimate the CO2 amounts of the past 400 million years, the findings hint at a higher climate sensitivity to CO2 concentrations.
Boreholes
Borehole
A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as petr ...
temperatures are used as temperature proxies. Since heat transfer through the ground is slow, temperature measurements at a series of different depths down the borehole, adjusted for the effect of rising heat from inside the Earth, can be " inverted" (a mathematical formula to solve matrix equations) to produce a non-unique series of surface temperature values. The solution is "non-unique" because there are multiple possible surface temperature reconstructions that can produce the same borehole temperature profile. In addition, due to physical limitations, the reconstructions are inevitably "smeared", and become more smeared further back in time. When reconstructing temperatures around 1500 AD, boreholes have a temporal resolution of a few centuries. At the start of the 20th century, their resolution is a few decades; hence they do not provide a useful check on the instrumental temperature record
Global surface temperature (GST) is the average temperature of Earth's surface. More precisely, it is the weighted average of the temperatures over the ocean and land. The former is also called sea surface temperature and the latter is calle ...
. However, they are broadly comparable. These confirmations have given paleoclimatologists the confidence that they can measure the temperature of 500 years ago. This is concluded by a depth scale of about to measure the temperatures from 100 years ago and to measure the temperatures from 1,000 years ago.[Environmental News Network staff. "Borehole temperatures confirm global warming."](_blank)
Boreholes have a great advantage over many other proxies in that no calibration is required: they are actual temperatures. However, they record surface temperature not the near-surface temperature (1.5 meter) used for most "surface" weather observations. These can differ substantially under extreme conditions or when there is surface snow. In practice the effect on borehole temperature is believed to be generally small. A second source of error is contamination of the well by groundwater may affect the temperatures, since the water "carries" more modern temperatures with it. This effect is believed to be generally small, and more applicable at very humid sites. It does not apply in ice cores where the site remains frozen all year.
More than 600 boreholes, on all continents, have been used as proxies for reconstructing surface temperatures. The highest concentration of boreholes exist in North America
North America is a continent in the Northern Hemisphere, Northern and Western Hemisphere, Western hemispheres. North America is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South Ameri ...
and Europe
Europe is a continent located entirely in the Northern Hemisphere and mostly in the Eastern Hemisphere. It is bordered by the Arctic Ocean to the north, the Atlantic Ocean to the west, the Mediterranean Sea to the south, and Asia to the east ...
. Their depths of drilling typically range from 200 to greater than 1,000 meters into the crust of the Earth or ice sheet.
A small number of boreholes have been drilled in the ice sheets; the purity of the ice there permits longer reconstructions. Central Greenland borehole temperatures show "a warming over the last 150 years of approximately 1°C ± 0.2°C preceded by a few centuries of cool conditions. Preceding this was a warm period centered around A.D. 1000, which was warmer than the late 20th century by approximately 1°C." A borehole in the Antarctica icecap shows that the "temperature at A.D. 1 asapproximately 1°C warmer than the late 20th century".[BOREHOLES IN GLACIAL ICE](_blank)
Surface Temperature Reconstructions for the Last 2,000 Years (2006), pp 81,82 Board on Atmospheric Sciences and Climate (BASC), National Academy of Science,
Borehole temperatures in Greenland were responsible for an important revision to the isotopic temperature reconstruction, revealing that the former assumption that "spatial slope equals temporal slope" was incorrect.
Corals
Ocean
The ocean is the body of salt water that covers approximately 70.8% of Earth. The ocean is conventionally divided into large bodies of water, which are also referred to as ''oceans'' (the Pacific, Atlantic, Indian Ocean, Indian, Southern Ocean ...
coral
Corals are colonial marine invertebrates within the subphylum Anthozoa of the phylum Cnidaria. They typically form compact Colony (biology), colonies of many identical individual polyp (zoology), polyps. Coral species include the important Coral ...
skeletal
A skeleton is the structural frame that supports the body of most animals. There are several types of skeletons, including the exoskeleton, which is a rigid outer shell that holds up an organism's shape; the endoskeleton, a rigid internal fram ...
rings, or bands, also share paleoclimatological information, similarly to tree rings. In 2002, a report was published on the findings of Drs. Lisa Greer and Peter Swart, associates of University of Miami
The University of Miami (UM, UMiami, Miami, U of M, and The U) is a private university, private research university in Coral Gables, Florida, United States. , the university enrolled 19,852 students in two colleges and ten schools across over ...
at the time, in regard to stable oxygen isotopes in the calcium carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
of coral. Cooler temperatures tend to cause coral to use heavier isotopes in its structure, while warmer temperatures result in more normal oxygen isotopes
There are three known stable isotopes of oxygen (8O): , , and .
Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope is ...
being built into the coral structure. Denser water salinity
Salinity () is the saltiness or amount of salt (chemistry), salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensio ...
also tends to contain the heavier isotope. Greer's coral sample from the Atlantic Ocean
The Atlantic Ocean is the second largest of the world's five borders of the oceans, oceanic divisions, with an area of about . It covers approximately 17% of Earth#Surface, Earth's surface and about 24% of its water surface area. During the ...
was taken in 1994 and dated back to 1935. Greer recalls her conclusions, "When we look at the averaged annual data from 1935 to about 1994, we see it has the shape of a sine wave
A sine wave, sinusoidal wave, or sinusoid (symbol: ∿) is a periodic function, periodic wave whose waveform (shape) is the trigonometric function, trigonometric sine, sine function. In mechanics, as a linear motion over time, this is ''simple ...
. It is periodic and has a significant pattern of oxygen isotope composition that has a peak at about every twelve to fifteen years." Surface water temperatures have coincided by also peaking every twelve and a half years. However, since recording this temperature has only been practiced for the last fifty years, correlation between recorded water temperature and coral structure can only be drawn so far back.
Pollen grains
Pollen can be found in sediments. Plants produce pollen
Pollen is a powdery substance produced by most types of flowers of seed plants for the purpose of sexual reproduction. It consists of pollen grains (highly reduced Gametophyte#Heterospory, microgametophytes), which produce male gametes (sperm ...
in large quantities and it is extremely resistant to decay. It is possible to identify a plant species from its pollen grain. The identified plant community of the area at the relative time from that sediment layer, will provide information about the climatic condition. The abundance of pollen of a given vegetation
Vegetation is an assemblage of plants and the ground cover they provide. It is a general term, without specific reference to particular Taxon, taxa, life forms, structure, Spatial ecology, spatial extent, or any other specific Botany, botanic ...
period or year depends partly on the weather conditions of the previous months, hence pollen density provides information on short-term climatic conditions. The study of prehistoric pollen is palynology
Palynology is the study of microorganisms and microscopic fragments of mega-organisms that are composed of acid-resistant organic material and occur in sediments, sedimentary rocks, and even some metasedimentary rocks. Palynomorphs are the mic ...
.
Dinoflagellate cysts
Dinoflagellates occur in most aquatic environments and during their life cycle, some species produce highly resistant organic-walled cysts
A cyst is a closed Wikt:sac, sac, having a distinct Cell envelope, envelope and cell division, division compared with the nearby Biological tissue, tissue. Hence, it is a cluster of Cell (biology), cells that have grouped together to form a sac ...
for a dormancy period when environmental conditions are not appropriate for growth. Their living depth is relatively shallow (dependent upon light penetration), and closely coupled to diatoms on which they feed. Their distribution patterns in surface waters are closely related to physical characteristics of the water bodies, and nearshore assemblages can also be distinguished from oceanic assemblages. The distribution of dinocysts in sediments has been relatively well documented and has contributed to understanding the average sea-surface conditions that determine the distribution pattern and abundances of the taxa (). Several studies, including and have compiled box and gravity cores in the North Pacific analyzing them for palynological content to determine the distribution of dinocysts and their relationships with sea surface temperature, salinity, productivity and upwelling. Similarly, and use a box core at 576.5 m of water depth from 1992 in the central Santa Barbara Basin to determine oceanographic and climatic changes during the past 40 kyr in the area.
Lake and ocean sediments
Similar to their study on other proxies, paleoclimatologists examine oxygen isotopes
There are three known stable isotopes of oxygen (8O): , , and .
Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope is ...
in the contents of ocean sediments
Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...
. Likewise, they measure the layers of varve
A varve is an annual layer of sediment or sedimentary rock.
The word 'varve' derives from the Swedish word ''varv'' whose meanings and connotations include 'revolution', 'in layers', and 'circle'.
Of the many rhythmites in the geological record ...
(deposited fine and coarse silt or clay) laminating lake sediments. Lake varves are primarily influenced by:
* Summer temperature, which shows the energy available to melt seasonal snow and ice
* Winter snowfall, which determines the level of disturbance to sediments when melting occurs
* Rainfall
Diatom
A diatom (Neo-Latin ''diatoma'') is any member of a large group comprising several Genus, genera of algae, specifically microalgae, found in the oceans, waterways and soils of the world. Living diatoms make up a significant portion of Earth's B ...
s, foraminifera
Foraminifera ( ; Latin for "hole bearers"; informally called "forams") are unicellular organism, single-celled organisms, members of a phylum or class (biology), class of Rhizarian protists characterized by streaming granular Ectoplasm (cell bio ...
, radiolaria
The Radiolaria, also called Radiozoa, are unicellular eukaryotes of diameter 0.1–0.2 mm that produce intricate mineral skeletons, typically with a central capsule dividing the cell into the inner and outer portions of endoplasm and ect ...
ns, ostracod
Ostracods, or ostracodes, are a Class (biology), class of the crustacean, Crustacea (class Ostracoda), sometimes known as seed shrimp. Some 33,000 species (only 13,000 of which are extant taxon, extant) have been identified,Brandão, S.N.; Antoni ...
s, and coccolithophore
Coccolithophores, or coccolithophorids, are single-celled organisms which are part of the phytoplankton, the autotrophic (self-feeding) component of the plankton community. They form a group of about 200 species, and belong either to the kingdom ...
s are examples of biotic proxies for lake and ocean conditions that are commonly used to reconstruct past climates. The distribution of the species of these and other aquatic creatures preserved in the sediments are useful proxies. The optimal conditions for species preserved in the sediment act as clues. Researchers use these clues to reveal what the climate and environment was like when the creatures died. The oxygen isotope ratios in their shells can also be used as proxies for temperature.
Water isotopes and temperature reconstruction
Ocean water is mostly H216O, with small amounts of HD16O and H218O, where D denotes deuterium
Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more c ...
, i.e. hydrogen with an extra neutron. In Vienna Standard Mean Ocean Water (VSMOW) the ratio of D to H is 155.76x10−6 and O-18 to O-16 is 2005.2x10−6. Isotope fractionation
Isotope fractionation describes fractionation processes that affect the relative abundance of isotopes, a phenomena that occurs (and so advantage is taken of it) in the study geochemistry, biochemistry, food science, and other fields. Normally, ...
occurs during changes between condensed and vapour phases: the vapour pressure of heavier isotopes is lower, so vapour contains relatively more of the lighter isotopes and when the vapour condenses the precipitation preferentially contains heavier isotopes. The difference from VSMOW is expressed as δ18O = 1000‰ ; and a similar formula for δD. δ values for precipitation are always negative. The major influence on δ is the difference between ocean temperatures where the moisture evaporated and the place where the final precipitation occurred; since ocean temperatures are relatively stable the δ value mostly reflects the temperature where precipitation occurs. Taking into account that the precipitation forms above the inversion layer, we are left with a linear relation:
δ 18O = aT + b
This is empirically calibrated from measurements of temperature and δ as a = 0.67 ‰/°C for Greenland
Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...
and 0.76 ‰/°C for East Antarctica
Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean (also known as the Antarctic Ocean), it contains the geographic South Pole. ...
. The calibration was initially done on the basis of ''spatial'' variations in temperature and it was assumed that this corresponded to ''temporal'' variations. More recently, borehole thermometry has shown that for glacial-interglacial variations, a = 0.33 ‰/°C, implying that glacial-interglacial temperature changes were twice as large as previously believed.
A study published in 2017 called the previous methodology to reconstruct paleo ocean temperatures 100 million years ago into question, suggesting it has been relatively stable during that time, much colder.
Membrane lipids
A novel climate proxy obtained from peat
Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
( lignites, ancient peat) and soils, membrane lipids known as glycerol dialkyl glycerol tetraether (GDGT) is helping to study paleo environmental factors, which control relative distribution of differently branched GDGT isomers
In chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. ''Isomerism'' refers to the existence or possibili ...
. The study authors note, "These branched membrane lipids are produced by an as yet unknown group of anaerobic soil bacteria." , there is a decade of research demonstrating that in mineral soils the degree of methylation
Methylation, in the chemistry, chemical sciences, is the addition of a methyl group on a substrate (chemistry), substrate, or the substitution of an atom (or group) by a methyl group. Methylation is a form of alkylation, with a methyl group replac ...
of bacteria (brGDGTs), helps to calculate mean annual air temperatures. This proxy method was used to study the climate of the early Palaeogene, at the Cretaceous–Paleogene boundary, and researchers found that annual air temperatures, over land and at mid-latitude, averaged about 23–29 °C (± 4.7 °C), which is 5–10 °C higher than most previous findings.
Pseudoproxies
The skill of algorithms used to combine proxy records into an overall hemispheric temperature reconstruction may be tested using a technique known as " pseudoproxies". In this method, output from a climate model
Numerical climate models (or climate system models) are mathematical models that can simulate the interactions of important drivers of climate. These drivers are the atmosphere, oceans, land surface and ice. Scientists use climate models to st ...
is sampled at locations corresponding to the known proxy network, and the temperature record produced is compared to the (known) overall temperature of the model.
See also
*Carbon dioxide in Earth's atmosphere
In Earth's atmosphere, carbon dioxide is a trace gas that plays an integral part in the greenhouse effect, carbon cycle, photosynthesis and oceanic carbon cycle. It is one of three main greenhouse gases in the atmosphere of Earth. The conce ...
* Dendrochronology
Dendrochronology (or tree-ring dating) is the scientific method of chronological dating, dating tree rings (also called growth rings) to the exact year they were formed in a tree. As well as dating them, this can give data for dendroclimatology, ...
* Historical climatology, the study of climate over human history (as opposed to the Earth
Earth is the third planet from the Sun and the only astronomical object known to Planetary habitability, harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all ...
's)
*Ice core
An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier
A glacier (; or ) is a persistent body of dense ice, a form of rock, that is constantly moving downhill under its own weight. A glacier ...
*Karst
Karst () is a topography formed from the dissolution of soluble carbonate rocks such as limestone and Dolomite (rock), dolomite. It is characterized by features like poljes above and drainage systems with sinkholes and caves underground. Ther ...
, spelaeology
* Paleotempestology
* Paleothermometer
*Palynology
Palynology is the study of microorganisms and microscopic fragments of mega-organisms that are composed of acid-resistant organic material and occur in sediments, sedimentary rocks, and even some metasedimentary rocks. Palynomorphs are the mic ...
*Speleothem
A speleothem (; ) is a geological formation made by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depen ...
References
Further reading
* "Borehole Temperatures Confirm Global Warming Pattern." UniSci. 27 Feb. 2001. 7 Oct. 2009
* Bruckner, Monica. "Paleoclimatology: How Can We Infer Past Climates?" Microbial Life. 29 Sept. 2008. 23 Nov. 2009
* "Climate Change 2001: 2.3.2.1 Palaeoclimate proxy indicators." IPCC. 2003. Sept. 23, 2009.
* "Coral Layers Good Proxy for Atlantic Climate Cycles." Earth Observatory. Webmaster: Paul Przyborski. 7 Dec. 2002. 2 Nov. 2009
* "Core Location Maps." National Ice Core Laboratory. 9 Apr. 2009. 23 Nov. 2009
* "Dendrochronology." Merriam-Webster Online Dictionary. Merriam-Webster Online. 2009. 2 Oct. 2009
* Environmental News Network staff. "Borehole temperatures confirm global warming." CNN.com. 17 Feb. 2000. 7 Oct. 2009
* "The GRIP Coring Effort." NCDC. 26 Sept. 2009
* "Growth ring." Encyclopædia Britannica. Encyclopædia Britannica Online. 2009. 23 Oct. 2009
* Huang, Shaopeng, et al. "Temperature trends over the past five centuries reconstructed from borehole temperatures." Nature. 2009. 6 Oct. 2009
* "Objectives – Kola Superdeep Borehole (KSDB) – IGCP 408: 'Rocks and Minerals at Great Depths and on the Surface.'" International Continental Scientific Drilling Program. 18 July 2006. 6 Oct. 2009
* "Paleoclimatology: the Oxygen Balance." Earth Observatory. Webmaster: Paul Przyborski. 24 Nov. 2009. 24 Nov. 2009
* Schweingruber, Fritz Hans. ''Tree Rings: Basics and Application of Dendrochronology.'' Dordrecht: 1988. 2, 47–8, 54, 256–7.
* Strom, Robert. ''Hot House.'' New York: Praxis, 2007. 255.
* "Varve." Merriam-Webster Online Dictionary. Merriam-Webster Online. 2009. 2 Nov. 2009
* Wolff, E. W. (2000) ''History of the atmosphere from ice cores''; ERCA vol 4 pp 147–177
External links
Chemical climate proxies
at Royal Society of Chemistry
The Royal Society of Chemistry (RSC) is a learned society and professional association in the United Kingdom with the goal of "advancing the chemistry, chemical sciences". It was formed in 1980 from the amalgamation of the Chemical Society, the ...
, January 23, 2013
*Quintana, Favia et al., 2018 ″Multiproxy response to climate- and human-driven changes in a remote lake of southern Patagonia (Laguna Las Vizcachas, Argentina) during the last 1.6 kyr″, BoletÃn de la Sociedad Geológica Mexicana, Mexico, VOL. 70 NO. 1 P. 173 ‒ 18
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