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Tetragonal
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the Cube (geometry), cube becomes a rectangular Prism (geometry), prism with a square base (''a'' by ''a'') and height (''c'', which is different from ''a''). Bravais lattices There are two tetragonal Bravais lattices: the primitive tetragonal and the body-centered tetragonal. The body-centered tetragonal lattice is equivalent to the primitive tetragonal lattice with a smaller unit cell, while the face-centered tetragonal lattice is equivalent to the body-centered tetragonal lattice with a smaller unit cell. Crystal classes The point groups that fall under this crystal system are listed below, followed by their representations in international notation, Schoenflies notation, orbifold notation, Coxeter notation and mineral examples.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Ma ...
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Crystal System
In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups of a configuration in space) are classified into crystal systems according to their point groups, and into lattice systems according to their Bravais lattices. Crystal systems that have space groups assigned to a common lattice system are combined into a crystal family. The seven crystal systems are ''triclinic'', ''monoclinic'', ''orthorhombic'', ''tetragonal'', ''trigonal'', ''hexagonal'', and ''cubic''. Informally, two crystals are in the same crystal system if they have similar symmetries (though there are many exceptions). Classifications Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system i ...
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Tetragonal
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the Cube (geometry), cube becomes a rectangular Prism (geometry), prism with a square base (''a'' by ''a'') and height (''c'', which is different from ''a''). Bravais lattices There are two tetragonal Bravais lattices: the primitive tetragonal and the body-centered tetragonal. The body-centered tetragonal lattice is equivalent to the primitive tetragonal lattice with a smaller unit cell, while the face-centered tetragonal lattice is equivalent to the body-centered tetragonal lattice with a smaller unit cell. Crystal classes The point groups that fall under this crystal system are listed below, followed by their representations in international notation, Schoenflies notation, orbifold notation, Coxeter notation and mineral examples.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Ma ...
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Crystal Lattice
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystal, crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of Three-dimensional space (mathematics), three-dimensional space in matter. The smallest group of particles in a material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive Translation (geometry), translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of principal axes/edges, of the unit cell and angles between them are lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of a crystal are described by the concept of space groups. All possi ...
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Cristobalite
Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, Si O2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico. It is used in dentistry as a component of alginate impression materials as well as for making models of teeth. Properties Metastability Cristobalite is stable only above 1470 °C, but can crystallize and persist metastably at lower temperatures. The persistence of cristobalite outside its thermodynamic stability range occurs because the transition from cristobalite to quartz or tridymite is "reconstructive", requiring the breaking up and reforming of the silica framework. These frameworks are composed of SiO4 tetrahedra in which every oxygen atom is shared with a neig ...
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Wulfenite
Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It often occurs as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore". It crystallizes in the tetragonal system, often occurring as stubby, pyramidal or tabular crystals. It also occurs as earthy, granular masses. It is found in many localities, associated with lead ores as a secondary mineral associated with the oxidized zone of lead deposits. It is also a secondary ore of molybdenum, and is sought by collectors. Discovery and occurrence Wulfenite was first described in 1845 for an occurrence in Bad Bleiberg, Carinthia, Austria. It was named for Franz Xaver von Wulfen (1728–1805), an Austrian mineralogist. It occurs as a secondary mineral in oxidized hydrothermal lead deposits. It occurs with cerussite, anglesite, smithsonite, hemimorphite, vanadinite, pyromorph ...
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Coxeter Notation
In geometry, Coxeter notation (also Coxeter symbol) is a system of classifying symmetry groups, describing the angles between fundamental reflections of a Coxeter group in a bracketed notation expressing the structure of a Coxeter-Dynkin diagram, with modifiers to indicate certain subgroups. The notation is named after H. S. M. Coxeter, and has been more comprehensively defined by Norman Johnson (mathematician), Norman Johnson. Reflectional groups For Coxeter groups, defined by pure reflections, there is a direct correspondence between the bracket notation and Coxeter-Dynkin diagram. The numbers in the bracket notation represent the mirror reflection orders in the branches of the Coxeter diagram. It uses the same simplification, suppressing 2s between orthogonal mirrors. The Coxeter notation is simplified with exponents to represent the number of branches in a row for linear diagram. So the ''A''''n'' group is represented by [3''n''−1], to imply ''n'' nodes connected by ''n ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 on the Mohs scale. Its Streak (mineralogy), streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). It is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Copper can be extracted from chalcopyrite ore using various methods. The two predominant methods are pyrometallurgy and hydrometallurgy, the former being the most commercially viable. Etymology The name chalcopyrite comes from the Greek words , which means cop ...
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Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list ...
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Hermann–Mauguin Notation
In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann (who introduced it in 1928) and the French mineralogist Charles-Victor Mauguin (who modified it in 1931). This notation is sometimes called international notation, because it was adopted as standard by the ''International Tables For Crystallography'' since their first edition in 1935. The Hermann–Mauguin notation, compared with the Schoenflies notation, is preferred in crystallography because it can easily be used to include translational symmetry elements, and it specifies the directions of the symmetry axes. Point groups Rotation axes are denoted by a number ''n'' – 1, 2, 3, 4, 5, 6, 7, 8, ... (angle of rotation ). For improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, that shows rotation-reflection axes. The rot ...
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Piypite
Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster. It was first described in 1982 for an occurrence in the Main Fracture of the Tolbachik volcano, Kamchatka Oblast, Russia. It has also been reported from Mount Vesuvius, Italy, and in a slag deposit in the Bad Ems District in the Rhineland-Palatinate, Germany. Piypite occurs as a sublimate phase in a fumarole environment. Associated minerals include halite, sylvite, langbeinite, tenorite, hematite, tolbachite, dolerophanite, urusovite, aphthitalite, ponomarevite, cotunnite, chalcocyanite, sofiite, euchlorine, averievite, fedotovite, alarsite Alarsite (AlAsO4) is an aluminium arsenate mineral with its name derived from its composition: aluminium and arsenate ...
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Cahnite
Cahnite (Cahnit in German, Cahnita in Spanish, Канит in Russian) is a brittle white or colorless mineral that has perfect cleavage and is usually transparent. It usually forms tetragonal-shaped crystals and it has a hardness of 3 mohs. Cahnite was discovered in the year 1921. It was named Cahnite to honor Lazard Cahn (1865–1940), who was a mineral collector and dealer. It is usually found in the Franklin Mine, in Franklin, New Jersey, but has also been found in Japan as well as in the Vallerano quarries in Rome, Italy. The geological environment that it occurs in is in pegmatites cutting a changed zinc orebody. The chemical formula for cahnite is Ca2B sO4OH)4. It is made up of 26.91% calcium, 3.63% boron, 25.15% arsenic, 1.35% hydrogen, and 42.96% oxygen. It has a molecular weight of 297.91 grams. Cahnite is not radioactive. Cahnite is associated with these other minerals: willemite, rhodonite, pyrochroite, hedyphane, datolite, and baryte Baryte, barite or baryte ...
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