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Prismanes
The prismanes are a class of hydrocarbon compounds consisting of Prism (geometry), prism-like polyhedra of various numbers of sides on the polygonal base. Chemically, it is a series of fused cyclobutane rings (a ladderane, with all-cis–trans isomerism, cis/all-Syn and anti addition, syn geometry) that wraps around to join its ends and form a band, with cycloalkane edges. Their chemical formula is (C2H2)n, where ''n'' is the number of cyclobutane sides (the size of the cycloalkane base), and that number also forms the basis for a systematic nomenclature, system of nomenclature within this class. The first few chemicals in this class are: Triprismane, tetraprismane, and pentaprismane have been synthesized and studied experimentally, and many higher members of the series have been studied using computational chemistry, computer models. The first several members do indeed have the geometry of a regular prism, with flat ''n''-gon bases. As ''n'' becomes increasingly large, however, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prism (geometry)
In geometry, a prism is a polyhedron comprising an polygon Base (geometry), base, a second base which is a Translation (geometry), translated copy (rigidly moved without rotation) of the first, and other Face (geometry), faces, necessarily all parallelograms, joining corresponding sides of the two bases. All Cross section (geometry), cross-sections parallel to the bases are translations of the bases. Prisms are named after their bases, e.g. a prism with a pentagonal base is called a pentagonal prism. Prisms are a subclass of prismatoids. Like many basic geometric terms, the word ''prism'' () was first used in Euclid's Elements, Euclid's ''Elements''. Euclid defined the term in Book XI as "a solid figure contained by two opposite, equal and parallel planes, while the rest are parallelograms". However, this definition has been criticized for not being specific enough in regard to the nature of the bases (a cause of some confusion amongst generations of later geometry writers). ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Allotropes Of Carbon
Carbon is capable of forming many allotropy, allotropes (structurally different forms of the same element) due to its Valence (chemistry), valency (Tetravalence, tetravalent). Well-known forms of carbon include diamond and graphite. In recent decades, many more allotropes have been discovered and researched, including ball shapes such as buckminsterfullerene and sheets such as graphene. Larger-scale structures of carbon include carbon nano tube, nanotubes, Carbon nanobud, nanobuds and Graphene nanoribbon, nanoribbons. Other unusual forms of carbon exist at very high temperatures or extreme pressures. Around 500 hypothetical 3‑periodic allotropes of carbon are known at the present time, according to the Samara Carbon Allotrope Database (SACADA). Atomic and diatomic carbon Under certain conditions, carbon can be found in its atomic form. It can be formed by vaporizing graphite, by passing large electric currents to form a carbon arc under very low pressure. It is extrem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubane
Cubane is a synthetic hydrocarbon compound with the Chemical formula, formula . It consists of eight carbon atoms arranged at the corners of a Cube (geometry), cube, with one hydrogen atom attached to each carbon atom. A solid crystalline substance, cubane is one of the Platonic hydrocarbons and a member of the prismanes. It was first synthesized in 1964 by Philip Eaton and Thomas Cole. Before this work, Eaton believed that cubane would be impossible to synthesize due to the "required 90 degree molecular geometry, bond angles". The cubic shape requires the carbon atoms to adopt an unusually sharp 90° bonding angle, which would be highly strain (chemistry), strained as compared to the tetrahedral molecular geometry#Tetrahedral bond angle, 109.45° angle of a tetrahedral geometry, tetrahedral carbon. Once formed, cubane is quite kinetic stability, kinetically stable, due to a lack of readily available decomposition paths. It is the simplest hydrocarbon with octahedral symmetry. Havi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclohexane
Cyclohexane is a cycloalkane with the molecular formula . Cyclohexane is non-polar. Cyclohexane is a colourless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are Precursor (chemistry), precursors to nylon. Cyclohexyl () is the alkyl substituent of cyclohexane and is abbreviated Cy. Production Cyclohexane is one of components of naphtha, from which it can be extracted by advanced distillation methods. Distillation is usually combined with isomerization of methylcyclopentane, a similar component extracted from naphtha by similar methods. Together, these processes cover only a minority (15-20%) of the modern industrial demand, and are complemented by synthesis. Modern industrial synthesis On an industrial scale, cyclohexane is produced by hydrogenation of benzene in the presence of a Raney nickel catalyst. Prod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methylene Group
A methylene group is any part of a molecule that consists of two hydrogen atoms bound to a carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ... atom, which is connected to the remainder of the molecule by two single bonds. The group may be represented as or , where the '>' denotes the two bonds. This stands in contrast to a situation where the carbon atom is bound to the rest of the molecule by a double bond, which is preferably called a methylidene group, represented . Formerly the methylene name was used for both isomers. The name “ methylene bridge“ can be used for the single-bonded isomer, to emphatically exclude methylidene. The distinction is often important, because the double bond is chemically different from two single bonds. The methylene group should be d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Asterane
Asteranes are members of a series of cage hydrocarbons consisting of two cycloalkane rings linked to each other by methylene groups. Each linking face is thus a cyclohexane, which has a boat conformation. They can be considered as homologues of the prismanes, but with a carbon linker between the faces rather than direct bonding. The molecules having triangular and square bases, sterane and sterane, have been synthesized and studied experimentally, and many higher members of the series have been studied using computer models Computer simulation is the running of a mathematical model on a computer, the model being designed to represent the behaviour of, or the outcome of, a real-world or physical system. The reliability of some mathematical models can be determin .... Modeling experiments predict that the highly symmetric geometry is no longer stable starting with sterane. References {{reflist Hydrocarbons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flag Of Israel
The flag of the State of Israel ( ; ) was adopted on 28 October 1948, five months after the Israeli Declaration of Independence. It consists of a white background with a blue Star of David in the centre and two horizontal blue stripes at the top and bottom, recalling the design of the tallit (). The Israeli flag legislation states that the official measurements are 160 × 220 cm. Therefore, the official proportions are 8:11. Variants can be found at a wide range of proportions, with 2:3 being common. The blue color is described as "dark sky-blue",Israel Ministry of Foreign Affairs publicatioThe Flag and the Emblem by art historian Alec Mishory, wherein he quotes "The Provisional Council of State Proclamation of the Flag of the State of Israel" made on 28 October 1948 by Joseph Sprinzak, Speaker. and varies from flag to flag, ranging from a hue of pure blue, sometimes shaded almost as dark as navy blue, to hues about 75% toward pure cyan and shades as light as very light b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flag Of Switzerland
The national flag of Switzerland displays a white Greek cross in the center of a square red field. The white cross is known as the Swiss cross or the federal cross. Its arms are equilateral, and their ratio of length to width is 7:6. The size of the cross in relation to the field was set in 2017 as 5:8.Appendix 2 ''Wappenschutzgesetz'' (SR 232.21), 21 June 2013 (effective 1 January 2017) ength of an arm: 7 units, width of the cross: 20 units, width of the flag: 32 units; ratio of cross width to field width: 20:32 = 5:8 Alongside the [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Geometric Isomer
Geometry (; ) is a branch of mathematics concerned with properties of space such as the distance, shape, size, and relative position of figures. Geometry is, along with arithmetic, one of the oldest branches of mathematics. A mathematician who works in the field of geometry is called a '' geometer''. Until the 19th century, geometry was almost exclusively devoted to Euclidean geometry, which includes the notions of point, line, plane, distance, angle, surface, and curve, as fundamental concepts. Originally developed to model the physical world, geometry has applications in almost all sciences, and also in art, architecture, and other activities that are related to graphics. Geometry also has applications in areas of mathematics that are apparently unrelated. For example, methods of algebraic geometry are fundamental in Wiles's proof of Fermat's Last Theorem, a problem that was stated in terms of elementary arithmetic, and remained unsolved for several centuries. During t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dodecagon
In geometry, a dodecagon, or 12-gon, is any twelve-sided polygon. Regular dodecagon A regular polygon, regular dodecagon is a figure with sides of the same length and internal angles of the same size. It has twelve lines of reflective symmetry and rotational symmetry of order 12. A regular dodecagon is represented by the Schläfli symbol and can be constructed as a Truncation (geometry), truncated hexagon, t, or a twice-truncated triangle, tt. The internal angle at each vertex of a regular dodecagon is 150°. Area The area of a regular dodecagon of side length ''a'' is given by: :\begin A & = 3 \cot\left(\frac \right) a^2 = 3 \left(2+\sqrt \right) a^2 \\ & \simeq 11.19615242\,a^2 \end And in terms of the apothem ''r'' (see also inscribed figure), the area is: :\begin A & = 12 \tan\left(\frac\right) r^2 = 12 \left(2-\sqrt \right) r^2 \\ & \simeq 3.2153903\,r^2 \end In terms of the circumradius '' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Computational Chemistry
Computational chemistry is a branch of chemistry that uses computer simulations to assist in solving chemical problems. It uses methods of theoretical chemistry incorporated into computer programs to calculate the structures and properties of molecules, groups of molecules, and solids. The importance of this subject stems from the fact that, with the exception of some relatively recent findings related to the hydrogen molecular ion (dihydrogen cation), achieving an accurate quantum mechanical depiction of chemical systems analytically, or in a closed form, is not feasible. The complexity inherent in the many-body problem exacerbates the challenge of providing detailed descriptions of quantum mechanical systems. While computational results normally complement information obtained by chemical experiments, it can occasionally predict unobserved chemical phenomena. Overview Computational chemistry differs from theoretical chemistry, which involves a mathematical description of chem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
