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Methyl Benzoate
Methyl benzoate is an organic compound. It is an ester with the chemical formula C6H5CO2CH3. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. Synthesis and reactions Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid.. Methyl benzoate reacts at both the ring and the ester, depending on the substrate. Electrophiles attack the ring, illustrated by acid-catalysed nitration with nitric acid to give methyl 3-nitrobenzoate. Nucleophiles attack the carbonyl center, illustrated by hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate. Occurrence Methyl benzoate can be isolated from the freshwater fern ''Salvinia molesta''. It is one of many com ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ethyl Benzoate
Ethyl benzoate, C9H10O2, is the ester formed by the condensation of benzoic acid and ethanol. It is a colorless liquid that is almost insoluble in water, but miscible with most organic solvents. As with many volatile esters, ethyl benzoate has a pleasant odor described as sweet, wintergreen, fruity, medicinal, cherry and grape. It is a component of some fragrances and artificial fruit flavors. Preparation A simple and commonly used method for the preparation of ethyl benzoate in laboratory is the acidic esterification of benzoic acid with ethanol and sulfuric acid as catalyst:Arthur Israel Vogel. Rev. by Brian S. Furniss: ''Vogel’s textbook of practical organic chemistry.'' 5. Auflage. Longman, Harlow 1989, , S. 1076 : References {{reflist External linksMaterial Safety Data Sheet Ethyl esters Benzoate esters Perfume ingredients Flavors Sweet-smelling chemicals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
