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Ionic Conductivity (solid State)
Ionic conductivity (denoted by ) is a measure of a substance's tendency towards ionic conduction. Ionic conduction is the movement of ions. The phenomenon is observed in solids and solutions. Ionic conduction is one mechanism of current. In crystalline solids In most solids, ions rigidly occupy fixed positions, strongly embraced by neighboring atoms or ions. In some solids, selected ions are highly mobile allowing ionic conduction. The mobility increases with temperature. Materials exhibiting this property are used in batteries. A well-known ion conductive solid is β''-alumina ("BASE"), a form of aluminium oxide that has channels through which sodium cations can hop. When this ceramic is complexed with a mobile ion, such as Na+, it behaves as so-called fast ion conductor. BASE is used as a membrane in several types of molten salt electrochemical cell. History Ionic conduction in solids has been a subject of interest since the beginning of the 19th century. Michael Fa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superionic Ice Conducting
Variations in pressure and temperature give rise to different phases of ice, which have varying properties and molecular geometries. Currently, twenty-one phases, including both crystalline and amorphous ices have been observed. In modern history, phases have been discovered through scientific research with various techniques including pressurization, force application, nucleation agents, and others. On Earth, most ice is found in the hexagonal Ice Ih phase. Less common phases may be found in the atmosphere and underground due to more extreme pressures and temperatures. Some phases are manufactured by humans for nano scale uses due to their properties. In space, amorphous ice is the most common form as confirmed by observation. Thus, it is theorized to be the most common phase in the universe. Various other phases could be found naturally in astronomical objects. Theory Most liquids under increased pressure freeze at ''higher'' temperatures because the pressure helps to hold ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead(II) Fluoride
Lead(II) fluoride is the inorganic compound with the formula Pb F2. It is a white solid. The compound is polymorphic, at ambient temperatures it exists in orthorhombic (PbCl2 type) form, while at high temperatures it is cubic ( Fluorite type). Preparation Lead(II) fluoride can be prepared by treating lead(II) hydroxide or lead(II) carbonate with hydrofluoric acid: : Pb(OH)2 + 2 HF → PbF2 + 2 H2O Alternatively, it is precipitated by adding hydrofluoric acid to a lead(II) salt solution, or by adding a fluoride salt to a lead salt, such as potassium fluoride to a lead(II) nitrate solution, : 2 KF + Pb(NO3)2 → PbF2 + 2 KNO3 or sodium fluoride to a lead(II) acetate solution. : 2 NaF + Pb(CH3COO)2 → PbF2 + 2 NaCH3COO It appears as the very rare mineral fluorocronite. Uses Lead(II) fluoride is used in low melting glasses, in glass coatings to reflect infrared rays, in phosphors for television-tube screens, and as a catalyst for the manufacture of picoline. The Muon g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
NASICON
NASICON is an acronym for sodium (Na) superionic conductor, super ionic conductor, which usually refers to a family of solids with the chemical formula Na1+xZr2SixP3−xO12, 0 < x < 3. In a broader sense, it is also used for similar compounds where Na, Zr and/or Si are replaced by isovalent elements. NASICON compounds have high Ionic conductivity (solid state), ionic conductivities, on the order of 10−3 S/cm, which rival those of liquid electrolytes. They are caused by hopping of Na ions among interstitial sites of the NASICON crystal lattice. Properties The crystal structure of NASICON compounds was characterized in 1968. It is a covalent network consisting of ZrO6 octahedra and PO4/SiO4 tetrahedra that share common corners. Sodium ions are located at two types of interstitial positions. They move among those sites through bottlenecks, whose size, and thus the NASICON electrical conductivity, de ...[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fast Ion Conductor
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors. Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure. Mechanism Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors. Classification In solid electrolytes (glasses or crystals), the ionic cond ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lattice Energy
In chemistry, the lattice energy is the energy change (released) upon formation of one mole of a crystalline compound from its infinitely separated constituents, which are assumed to initially be in the gaseous state at 0 K. It is a measure of the cohesive forces that bind crystalline solids. The size of the lattice energy is connected to many other physical properties including solubility, hardness, and volatility. Since it generally cannot be measured directly, the lattice energy is usually deduced from experimental data via the Born–Haber cycle. Lattice energy and lattice enthalpy The concept of lattice energy was originally applied to the formation of compounds with structures like rocksalt ( NaCl) and sphalerite ( ZnS) where the ions occupy high-symmetry crystal lattice sites. In the case of NaCl, lattice energy is the energy change of the reaction: Na^+ (g) + Cl^- (g) -> NaCl (s) which amounts to −786 kJ/mol.David Arthur Johnson, ''Metals and Chemical Change' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium–sulfur Battery
A sodium–sulfur (NaS) battery is a type of molten-salt battery, molten-salt battery (electricity), battery that uses liquid sodium and liquid sulfur electrodes. This type of battery has a similar energy density to lithium-ion battery, lithium-ion batteries, and is fabricated from inexpensive and low-toxicity materials. Due to the high operating temperature required (usually between 300 and 350 °C), as well as the highly reactive nature of sodium and sodium polysulfides, these batteries are primarily suited for grid energy storage, stationary energy storage applications, rather than for use in vehicles. Molten Na-S batteries are scalable in size: there is a 1 MW microgrid support system on Santa Catalina Island (California), Catalina Island CA (USA) and a 50 MW/300 MWh system in Fukuoka, Kyushu, (Japan). In 2024, only one company (NGK Insulators) produced molten NaS batteries on a commercial scale. BASF Stationary Energy Storage GmbH, a wholly owned subsidiary of BASF SE, a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Vehicle
An electric vehicle (EV) is a motor vehicle whose propulsion is powered fully or mostly by electricity. EVs encompass a wide range of transportation modes, including road vehicle, road and rail vehicles, electric boats and Submersible, submersibles, electric aircraft and electrically powered spacecraft propulsion, electric spacecraft. Early electric vehicles first came into existence in the late 19th century, when the Second Industrial Revolution brought forth electrification and mass utilization of DC motor, DC and AC motor, AC electric motors. Using electricity was among the preferred methods for motor vehicle propulsion as it provided a level of quietness, comfort and ease of operation that could not be achieved by the gasoline engine cars of the time, but range anxiety due to the limited energy storage offered by history of the battery, contemporary battery technologies hindered any mass adoption of private electric vehicles throughout the 20th century. Internal combustion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ford Motor Company
Ford Motor Company (commonly known as Ford) is an American multinational corporation, multinational automobile manufacturer headquartered in Dearborn, Michigan, United States. It was founded by Henry Ford and incorporated on June 16, 1903. The company sells automobiles and commercial vehicles under the List of Ford vehicles, Ford brand, and luxury cars under its Lincoln Motor Company, Lincoln brand. The company is listed on the New York Stock Exchange under the single-letter ticker symbol F and is controlled by the Ford family (Michigan), Ford family. They have minority ownership but a plurality of the voting power. Ford introduced methods for large-scale manufacturing of cars and large-scale management of an industrial workforce using elaborately engineered manufacturing sequences typified by moving assembly lines. By 1914, these methods were known around the world as Fordism. Ford's former British subsidiaries Jaguar Cars, Jaguar and Land Rover, acquired in 1989 and 2000, r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superionic Conductor
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors. Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure. Mechanism Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors. Classification In solid electrolytes (glasses or crystals), the ionic conduc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver Iodide
Silver iodide is an inorganic compound with the formula Ag I. The compound is a bright yellow solid, but samples almost always contain impurities of metallic silver that give a grey colouration. The silver contamination arises because some samples of AgI can be highly photosensitive. This property is exploited in silver-based photography. Silver iodide is also used as an antiseptic and in cloud seeding. Structure The structure adopted by silver iodide is temperature dependent: * Below 420 K, the β phase of AgI, with the wurtzite structure, is most stable. This phase is encountered in nature as the mineral iodargyrite. * Above 420 K, the α phase becomes more stable. This motif is a body-centered cubic structure which has the silver centers distributed randomly between 6 octahedral, 12 tetrahedral and 24 trigonal sites. At this temperature, Ag+ ions can move rapidly through the solid, allowing fast ion conduction. The transition between the β and α forms repre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver Sulfide
Silver sulfide is an inorganic compound with the formula . A dense black solid, it is the only sulfide of silver. It is useful as a photosensitizer in photography. It constitutes the tarnish that forms over time on silverware and other silver objects. Silver sulfide is insoluble in most solvents, but is degraded by strong acids. Silver sulfide is a network solid made up of silver (electronegativity of 1.98) and sulfur (electronegativity of 2.58) where the bonds have low ionic character (approximately 10%). Formation Silver sulfide naturally occurs as the tarnish on silverware. When combined with silver, hydrogen sulfide gas creates a layer of black silver sulfide patina on the silver, protecting the inner silver from further conversion to silver sulfide. Silver whiskers can form when silver sulfide forms on the surface of silver electrical contacts operating in an atmosphere rich in hydrogen sulfide and high humidity. Such atmospheres can exist in sewage treatment and paper m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolysis
In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of chemical element, elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. The word "lysis" means to separate or break, so in terms, electrolysis would mean "breakdown via electricity." Etymology The word "electrolysis" was introduced by Michael Faraday in 1834, using the Greek language, Greek words "amber", which since the 17th century was associated with electrical phenomena, and ' meaning "dissolution". Nevertheless, electrolysis, as a tool to study chemical reactions and obtain pure chemical element, elements, precedes the coinage of the term and formal description by Faraday. History In the early nineteenth century, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
