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Heavy Water
Heavy water (deuterium oxide, , ) is a form of water (molecule), water in which hydrogen atoms are all deuterium ( or D, also known as ''heavy hydrogen'') rather than the common hydrogen-1 isotope (, also called ''protium'') that makes up most of the hydrogen in normal water. The presence of the heavier isotope gives the water different nuclear properties, and the increase in mass gives it slightly different physical and chemical properties when compared to normal water. Deuterium is a heavy Isotopes of hydrogen, hydrogen isotope. Heavy water contains deuterium atoms and is used in nuclear reactors. Semiheavy water (HDO) is more common than pure heavy water, while heavy-oxygen water is denser but lacks unique properties. Tritiated water is radioactive due to tritium content. Heavy water has different physical properties from regular water, such as being 10.6% denser and having a higher melting point. Heavy water is less Dissociation (chemistry), dissociated at a given temperatur ...
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Deuterium
Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more common H has no neutrons. The name ''deuterium'' comes from Greek '' deuteros'', meaning "second". American chemist Harold Urey discovered deuterium in 1931. Urey and others produced samples of heavy water in which the H had been highly concentrated. The discovery of deuterium won Urey a Nobel Prize in 1934. Nearly all deuterium found in nature was synthesized in the Big Bang 13.8 billion years ago, forming the primordial ratio of H to H (~26 deuterium nuclei per 10 hydrogen nuclei). Deuterium is subsequently produced by the slow stellar proton–proton chain, but rapidly destroyed by exothermic fusion reactions. The deuterium–deuterium reaction has the second-lowest energy threshold, and is the most astrophysically acce ...
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Water (molecule)
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy or organic micronutrients. Its chemical formula, , indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. In liquid form, is also called "water" at standard temperature and pressure. Because Earth's environment is relatively close to water's triple point, water exists on Earth as a solid, a liquid, and a gas. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice ...
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Bond Energy
In chemistry, bond energy (''BE'') is one measure of the strength of a chemical bond. It is sometimes called the mean bond, bond enthalpy, average bond enthalpy, or bond strength. IUPAC defines bond energy as the average value of the gas-phase bond-dissociation energy (usually at a temperature of 298.15 K) for all bonds of the same type within the same chemical species. The bond dissociation energy (enthalpy) is also referred to as bond disruption energy, bond energy, bond strength, or binding energy (abbreviation: ''BDE'', ''BE'', or ''D''). It is defined as the standard enthalpy change of the following fission: R—''X'' → R + ''X''. The ''BDE'', denoted by Dº(R—''X''), is usually derived by the thermochemical equation, : \begin \mathrmX) \ = \Delta H^\circ_f\mathrm + \Delta H^\circ_f(X) - \Delta H^\circ_f(\mathrmX) \end This equation tells us that the ''BDE'' for a given bond is equal to the energy of the individual components that make up the bond when they are free ...
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Stable Isotope
Stable nuclides are Isotope, isotopes of a chemical element whose Nucleon, nucleons are in a configuration that does not permit them the surplus energy required to produce a radioactive emission. The Atomic nucleus, nuclei of such isotopes are not radioactive and unlike radionuclides do not spontaneously undergo radioactive decay. When these nuclides are referred to in relation to specific elements they are usually called that element's stable isotopes. The 80 elements with one or more stable isotopes comprise a total of 251 nuclides that have not been shown to decay using current equipment. Of these 80 elements, 26 have only one stable isotope and are called monoisotopic element, monoisotopic. The other 56 have more than one stable isotope. Tin has ten stable isotopes, the largest number of any element. Definition of stability, and naturally occurring nuclides Most naturally occurring nuclides are stable (about 251; see list at the end of this article), and about 35 more (tot ...
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Isotopologue
In chemistry, isotopologues (also spelled isotopologs) are molecules that differ only in their isotopic composition. They have the same chemical formula and bonding arrangement of atoms, but at least one atom has a different number of neutrons than the parent. An example is water, whose hydrogen-related isotopologues are: "light water" (HOH or ), " semi-heavy water" with the deuterium isotope in equal proportion to protium (HDO or ), "heavy water" with two deuterium atoms ( or ); and "super-heavy water" or tritiated water ( or , as well as and , where some or all of the hydrogen is the radioactive tritium isotope). Oxygen-related isotopologues of water include the commonly available form of heavy-oxygen water () and the more difficult to separate version with the isotope. Both elements may be replaced by isotopes, for example in the doubly labeled water isotopologue . Altogether, there are 9 different stable water isotopologues, and 9 radioactive isotopologues involving tr ...
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Radioactive Decay
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is considered ''radioactive''. Three of the most common types of decay are Alpha decay, alpha, Beta decay, beta, and Gamma ray, gamma decay. The weak force is the Fundamental interactions, mechanism that is responsible for beta decay, while the other two are governed by the electromagnetic force, electromagnetic and nuclear forces. Radioactive decay is a randomness, random process at the level of single atoms. According to quantum mechanics, quantum theory, it is impossible to predict when a particular atom will decay, regardless of how long the atom has existed. However, for a significant number of identical atoms, the overall decay rate can be expressed as a decay constant or as a half-life. The half-lives of radioactive atoms have a huge range: f ...
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Oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other chemical compound, compounds. Oxygen is abundance of elements in Earth's crust, the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. It is abundance of chemical elements, the third-most abundant element in the universe after hydrogen and helium. At standard temperature and pressure, two oxygen atoms will chemical bond, bind covalent bond, covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula ...
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CANDU Reactor
The CANDU (CANada Deuterium Uranium) is a Canadian pressurized heavy-water reactor design used to generate electric power. The acronym refers to its deuterium oxide (heavy water) moderator and its use of (originally, natural) uranium fuel. CANDU reactors were first developed in the late 1950s and 1960s by a partnership between Atomic Energy of Canada Limited (AECL), the Hydro-Electric Power Commission of Ontario, Canadian General Electric, and other companies. There have been two major types of CANDU reactors, the original design of around 500  MWe that was intended to be used in multi-reactor installations in large plants, and the optimized CANDU 6 in the 600 MWe class that is designed to be used in single stand-alone units or in small multi-unit plants. CANDU 6 units were built in Quebec and New Brunswick, as well as Pakistan, Argentina, South Korea, Romania, and China. A single example of a non-CANDU 6 design was sold to India. The multi-unit design was used onl ...
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Semiheavy Water
Semiheavy water is the result of replacing one of the protium (normal hydrogen, H) in normal water with deuterium (H; or D). It exists whenever there is water with H and H in the mix. This is because hydrogen atoms (H) are rapidly exchanged between water molecules. Water with 50% H and 50% H, is about 50% HHO and 25% each of HO and HO, in dynamic equilibrium. In normal water, about 1 molecule in 3,200 is HDO (HHO) (one hydrogen in 6,400 is H). By comparison, heavy water DO or HO occurs at a proportion of about 1 molecule in 41 million (i.e., 1 in 6,400). This makes semiheavy water far more common than "normal" heavy water. The freezing point of semiheavy water is close to the freezing point of heavy water at 3.81°C compared to the 3.82°C of heavy water. Production On Earth, semiheavy water occurs naturally in normal water at a proportion of about 1 molecule in 3,200; because 1 in 6,400 hydrogen atoms in water is deuterium, which is 1 part in 3,200 by weight. HDO may be separ ...
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Vienna Standard Mean Ocean Water
Vienna Standard Mean Ocean Water (VSMOW) is an isotopic standard for water, that is, a particular sample of water whose proportions of different isotopes of hydrogen and oxygen are accurately known. VSMOW is distilled from ocean water and does not contain salt or other impurities. Published and distributed by the Vienna-based International Atomic Energy Agency in 1968, the standard and its essentially identical successor, VSMOW2, continue to be used as a reference material. Water samples made up of different isotopes of hydrogen and oxygen have slightly different physical properties. As an extreme example, heavy water, which contains two deuterium (2H) atoms instead of the usual, lighter hydrogen-1 (1H), has a melting point of and boiling point of . Different rates of evaporation cause water samples from different places in the water cycle to contain slightly different ratios of isotopes. Ocean water (richer in heavy isotopes) and rain water (poorer in heavy isotopes) roughly ...
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International Union Of Pure And Applied Chemistry
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. IUPAC's executive director heads this administrative office, currently Greta Heydenrych. IUPAC was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry. Its members, the National Adhering Organizations, can be national chemistry societies, national academies of sciences, or other bodies representing chemists. There are fifty-four National Adhering Organizations and three Associate National Adhering Organizations. IUPAC's Inter-divisional Committee ...
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Proton
A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an electron (the proton-to-electron mass ratio). Protons and neutrons, each with a mass of approximately one Dalton (unit), dalton, are jointly referred to as ''nucleons'' (particles present in atomic nuclei). One or more protons are present in the Atomic nucleus, nucleus of every atom. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol ''Z''). Since each chemical element, element is identified by the number of protons in its nucleus, each element has its own atomic number, which determines the number of atomic electrons and consequently the chemical characteristi ...
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