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Ferroalloys
Ferroalloy refers to various alloys of iron with a high proportion of one or more other elements such as manganese (Mn), aluminium (Al), or silicon (Si). They are used in the production of steels and alloys. The alloys impart distinctive qualities to steel and cast iron or serve important functions during production and are, therefore, closely associated with the iron and steel industry, the leading consumer of ferroalloys. The leading producers of ferroalloys in 2014 were China, South Africa, India, Russia and Kazakhstan, which accounted for 84% of the world production. World production of ferroalloys was estimated as 52.8 million tonnes in 2015. Compounds The main ferroalloys are: *FeAl – ferroaluminum *FeB – ferroboron – 12–20% of boron, max. 3% of silicon, max. 2% aluminium, max. 1% of carbon *FeCe – ferrocerium *FeCr – ferrochromium *FeMg – ferromagnesium *FeMn – ferromanganese *FeMo – ferromolybdenum – min. 60% Mo, max. 1% Si, max. 0.5% Cu *FeNb � ...
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Ferromanganese
Ferromanganese is an alloy of iron and manganese, with other elements such as silicon, carbon, sulfur, nitrogen and phosphorus. The primary use of ferromanganese is as a type of processed manganese source to add to different types of steel, such as stainless steel. Global production of low-carbon ferromanganese (i.e. alloys with less than 2% carbon content) reached 1.5 megatons in 2010. Physical and chemical properties The properties of ferromanganese vary considerably with the precise type and composition of the alloy. The melting point is generally between and . The density of the alloy depend slightly on the types of impurities present, but is generally around . Production Sources of manganese ore generally also contain iron oxides. As manganese has a more negative free energy of oxidation than iron, i.e. is chemically harder to reduce, during the reduction of manganese ore, iron is also reduced and mixed with the manganese in the melt. This is unlike other oxides such a ...
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Ferrotitanium
Ferrotitanium is a ferroalloy, an alloy of iron and titanium with between 10 and 20% iron and 45–75% titanium and sometimes a small amount of carbon. It is used in steelmaking as a cleansing agent for iron and steel; the titanium is highly reactive with sulfur, carbon, oxygen, and nitrogen, forming insoluble compounds and sequestering them in slag, and is therefore used for deoxidizing, and sometimes for desulfurization and denitrogenation. In steelmaking, the addition of titanium yields metal with finer grain structure. Ferrotitanium can be manufactured by mixing titanium sponge and scrap with iron and melting them together in an induction furnace. Ferrotitanium powder can be also used as a fuel in some pyrotechnic compositions. References External links *{{cite web , url = http://minerals.usgs.gov/minerals/pubs/commodity/ferroalloys/myb1-2006-feall.pdf , title =Minerals Yearbook 2006: Ferroalloys , publisher = United States Geological Survey The United States Ge ...
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Ferrosilicon Magnesium
Ferrosilicon is an alloy of iron and silicon. It has a typical silicon content of 15–90% by weight and a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in the presence of iron. Typical sources of iron are scrap iron or millscale. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. The usual formulations on the market are ferrosilicons with 15%, 45%, 75%, and 90% silicon. The remainder is iron, with about 2% consisting of other elements like aluminium and calcium. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct. A mineral perryite is similar to ferrosilicon, with its composition Fe5Si2. In contact with water, ferrosilicon may slowly produce hydrogen. The reaction, which is accelerated in the presence o ...
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Ferrosilicon
Ferrosilicon is an ferroalloy, alloy of iron and silicon. It has a typical silicon content of 15–90% by weight and a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke (fuel), coke in the presence of iron. Typical sources of iron are scrap iron or millscale. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. The usual formulations on the market are ferrosilicons with 15%, 45%, 75%, and 90% silicon. The remainder is iron, with about 2% consisting of other elements like aluminium and calcium. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct. A mineral perryite is similar to ferrosilicon, with its composition Fe5Si2. In contact with water, ferrosilicon may slowly produce hydrogen. The reaction, which is accelerate ...
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Ferromolybdenum
Ferro molybdenum is an important iron-molybdenum metal alloy, with a molybdenum content of 60–75% It is the main source for molybdenum alloying of HSLA steel. Production The alloy is produced by heating a mixture of molybdenum(VI) oxide MoO3, aluminium, and iron. The oxide and the aluminium combine via an aluminothermic reaction Aluminothermic reactions are exothermic reaction, exothermic chemical reactions using aluminium as the reducing agent at high temperature. The process is industrially useful for production of alloys of iron. The most prominent example is the the ... to give molybdenum in situ. The ferromolybdenum can be purified by electron beam melting or used as it is. For alloying with steel the ferromolybdenum is added to molten steel before casting. References External links * * Ferroalloys Molybdenum {{alloy-stub ...
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Ferrochromium
Ferrochrome or ferrochromium (FeCr) is a type of ferroalloy, that is, an alloy of chromium and iron, generally containing 50 to 70% chromium by weight. Ferrochrome is produced by electric arc carbothermic reduction of chromite. Most of the global output is produced in South Africa, Kazakhstan and India, which have large domestic chromite resources. Increasing amounts are coming from Russia and China. Production of steel, especially that of stainless steel with chromium content of 10 to 20%, is the largest consumer and the main application of ferrochrome. Usage Over 80% of the world's ferrochrome is utilised in the production of stainless steel. In 2006, 28,000,000 tons of stainless steel were produced. Stainless steel depends on chromium for its appearance and resistance to corrosion. Average chrome content in stainless steel is approx. 18%. It is also used to add chromium to carbon steel. FeCr from South Africa, known as "charge chrome" and produced from a Cr containing ore wi ...
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Ferrocerium
Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and some iron – about 95% lanthanides and 5% iron) hardened by blending in oxides of iron and/or magnesium. When struck with a harder material, friction produces hot fragments that oxidize rapidly when exposed to the oxygen in the air, producing sparks that can reach temperatures of . The effect is due to the low ignition temperature of cerium, between . Ferrocerium has many commercial applications, such as the ignition source for lighters, strikers for gas welding and cutting torches, deoxidization in metallurgy, and ferrocerium rods. Because of ferrocerium's ability to ignite in adverse conditions, rods of ferrocerium (also called ferro rods, spark rods, and flint-spark-lighters) are commonly used as an emergency firelighting device in survival kits. The ferrocerium is referred to as a "flint" in this case, as bot ...
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Ferroniobium
Ferroniobium is an important iron-niobium alloy, with a niobium content of 60-70%. It is the main source for niobium alloying of HSLA steel and covers more than 80% of the worldwide niobium production. The niobium is mined from pyrochlore deposits and is subsequently transformed into the niobium pentoxide Nb2O5. This oxide is mixed with iron oxide and aluminium and is reduced in an aluminothermic reaction to niobium and iron. The component metals can be purified in an electron beam furnace or the alloy can be used as it is. For alloying with steel the ferroniobium is added to molten steel before casting. The largest producers of ferroniobium are the same as for niobium and are located in Brazil and Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun .... External links * *ISO ...
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Ferroboron
Ferroboron (FeB) is a ferroalloy consisting of iron and boron. The metal usually contains 17.5% to 20% boron and is used to produce boron steels. Description Ferroboron ( CAS Registry Number 11108–67-1) is a ferroalloy of iron and boron with boron content between 17.5 and 20%. It is manufactured either by carbothermic reduction of boric acid in an electric arc furnace together with carbon steel, or by the aluminothermic reduction of boric acid in the presence of iron. Ferroboron is added to C-Mn and other low-alloy steels to improve hardenability (see boron steel), and can also act as a nitrogen scavenger in steel, and in the production of Neodymium magnets. See also * Iron boride *Boriding Boriding, also called boronizing, is the process by which boron is added to a metal or alloy. It is a type of surface hardening. In this process boron atoms are diffused into the surface of a metal component. The resulting surface contains metal ... References {{reflist, refs = {{Cit ...
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Ferroaluminum
Ferroaluminum (FeAl) is a ferroalloy, consisting of iron and aluminium. The metal usually consists of 40% to 60% aluminium. Applications of ferroaluminum include the deoxidation of steel, hardfacing applications, reducing agent, thermite reactions, AlNiCo magnets, and alloying additions to welding wires and fluxes. The alloy is also known for the ability to manufacture low melting point alloys and its ability to carry out aluminothermic welding. Ferroaluminum does not currently have a CAS Registry Number. The presence of iron in aluminum helps in the decrease of casting defects, improves tensile, yield, hardness, and maintains strength at high temperatures. The first recorded usage of the word "ferroaluminum" was in 1887. Ferroaluminum can also be nitrided, as the aluminium bonds well with the nitrogen forming a hard case. The aluminum provided in the alloy helps with this process. The majority of the world's ferroaluminum is produced by Australia, China, Russia, the US and Cana ...
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Ferrovanadium
Ferrovanadium (FeV) is an alloy formed by combining iron and vanadium with a vanadium content range of 35–85%. The production of this alloy results in a grayish silver crystalline solid that can be crushed into a powder called "ferrovanadium dust".Hathaway, G. J.; Proctor, N. H. ''Proctor and Hughes chemical hazards of the workplace''; Wiley-Interscience: Hoboken, 2004. Ferrovanadium is a universal hardener, strengthener and anti-corrosive additive for steels like high-strength low-alloy steel, tool steels, as well as other ferrous-based products. It has significant advantages over both iron and vanadium individually. Ferrovanadium is used as an additive to improve the qualities of ferrous alloys. One such use is to improve corrosion resistance to alkaline reagents as well as sulfuric and hydrochloric acids. It is also used to improve the tensile strength to weight ratio of the material. One application of such steels is in the chemical processing industry for high pressure hig ...
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