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Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds about 1 km/sec and differ from deflagrations which have subsonic flame speeds about 1 m/sec. Detonation may form from an explosion of fuel-oxidizer mixture. Compared with deflagration, detonation doesn't need to have an external oxidizer. Oxidizers and fuel mix when deflagration occurs. Detonation is more destructive than deflagrations. In detonation, the flame front travels through the air-fuel faster than sound; while in deflagration, the flame front travels through the air-fuel slower than sound. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. TNT, dynamite, and C4 are examples of high power explosives that detonate. The detonation velocity, velocity of detonation in solid an ...
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Pulse Detonation Engine
A pulse detonation engine (PDE) is a type of propulsion system that uses detonation waves to combust the fuel and oxidizer mixture. The engine is pulsed because the mixture must be renewed in the combustion chamber between each detonation wave and the next. Theoretically, a PDE can operate from subsonic up to a hypersonic flight speed of roughly Mach 5. An ideal PDE design can have a thermodynamic efficiency higher than other designs like turbojets and turbofans because a detonation wave rapidly compresses the mixture and adds heat at constant volume. Consequently, moving parts like compressor spools are not necessarily required in the engine, which could significantly reduce overall weight and cost. Key issues for further development include fast and efficient mixing of the fuel and oxidizer, the prevention of autoignition, and integration with an inlet and nozzle. , no practical PDE has been put into production, but several testbed engines have been built and one was ...
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Detonation Velocity
Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonated explosive. Explosive velocities are always higher than the local speed of sound in the material. If the explosive is confined before detonation, such as in an artillery shell, the force produced is focused on a much smaller area, and the pressure is significantly intensified. This results in an explosive velocity that is higher than if the explosive had been detonated in open air. Unconfined velocities are often approximately 70 to 80 percent of confined velocities. Explosive velocity is increased with smaller particle size (i.e., increased spatial density), increased charge diameter, and increased confinement (i.e., higher pressure). Typical detonation velocities for organic dust mixtures range from 1400 to 1650m/s. Gas explosions can either deflagrate or detonate based on confinement; detonation velocities are ge ...
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Deflagration
Deflagration (Lat: ''de + flagrare'', 'to burn down') is subsonic combustion in which a pre-mixed flame propagates through an explosive or a mixture of fuel and oxidizer. Deflagrations in high and low explosives or fuel–oxidizer mixtures may transition to a detonation depending upon confinement and other factors. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/s differ from detonations which propagate supersonically with detonation velocities in the range of km/s. Applications Deflagrations are often used in engineering applications when the force of the expanding gas is used to move an object such as a projectile down a barrel, or a piston in an internal combustion engine. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Terminology of explosive safety When studying or discussing explosive ...
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Chapman–Jouguet Condition
The Chapman–Jouguet condition holds approximately in detonation waves in high explosives. It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as the reaction ceases. David Chapman and Émile Jouguet originally (c. 1900) stated the condition for an infinitesimally thin detonation. A physical interpretation of the condition is usually based on the later modelling (c. 1943) by Yakov Borisovich Zel'dovich, John von Neumann, and Werner Döring (the so-called ZND detonation model). In more detail (in the ZND model) in the frame of the leading shock of the detonation wave, gases enter at supersonic velocity and are compressed through the shock to a high-density, subsonic flow. This sudden change in pressure initiates the chemical (or sometimes, as in steam explosions, physical) energy release. The energy release re-accelerates the flow back to the local speed of sound. It can be sho ...
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ZND Theory
The ZND detonation model is a one-dimensional model for the process of detonation of an explosive. It was proposed during World War II independently by Yakov Zeldovich, John von Neumann, and Werner Döring, hence the name. This model admits finite-rate chemical reactions and thus the process of detonation consists of the following stages. First, an infinitesimally thin shock wave compresses the explosive to a high pressure called the von Neumann spike. At the von Neumann spike point the explosive still remains unreacted. The spike marks the onset of the zone of exothermic chemical reaction, which finishes at the Chapman–Jouguet condition The Chapman–Jouguet condition holds approximately in detonation waves in high explosives. It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as t .... After that, the detonation products expand backward. In the reference frame in which the sho ...
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Shock Front
In physics, a shock wave (also spelled shockwave), or shock, is a type of propagating disturbance that moves faster than the local speed of sound in the medium. Like an ordinary wave, a shock wave carries energy and can propagate through a medium, but is characterized by an abrupt, nearly discontinuous, change in pressure, temperature, and density of the medium. For the purpose of comparison, in supersonic flows, additional increased expansion may be achieved through an expansion fan, also known as a Prandtl–Meyer expansion fan. The accompanying expansion wave may approach and eventually collide and recombine with the shock wave, creating a process of destructive interference. The sonic boom associated with the passage of a supersonic aircraft is a type of sound wave produced by constructive interference. Unlike solitons (another kind of nonlinear wave), the energy and speed of a shock wave alone dissipates relatively quickly with distance. When a shock wave passes through ...
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Explosion
An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated by a slower expansion that would normally not be forceful, but is not allowed to expand, so that when whatever is containing the expansion is broken by the pressure that builds as the matter inside tries to expand, the matter expands forcefully. An example of this is a Volcano, volcanic eruption created by the expansion of magma in a magma chamber as it rises to the surface. Supersonic explosions created by high explosives are known as detonations and travel through shock waves. wikt:subsonic, Subsonic explosions are created by low explosives through a slower combustion process known as deflagration. Causes For an explosion to occur, there must be a rapid, forceful expansion of matter. There are numerous ways this can happen, both natura ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot e ...
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John Von Neumann
John von Neumann ( ; ; December 28, 1903 – February 8, 1957) was a Hungarian and American mathematician, physicist, computer scientist and engineer. Von Neumann had perhaps the widest coverage of any mathematician of his time, integrating Basic research, pure and Applied science#Applied research, applied sciences and making major contributions to many fields, including mathematics, physics, economics, computing, and statistics. He was a pioneer in building the mathematical framework of quantum physics, in the development of functional analysis, and in game theory, introducing or codifying concepts including Cellular automaton, cellular automata, the Von Neumann universal constructor, universal constructor and the Computer, digital computer. His analysis of the structure of self-replication preceded the discovery of the structure of DNA. During World War II, von Neumann worked on the Manhattan Project. He developed the mathematical models behind the explosive lense ...
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David Chapman (chemist)
David Leonard Chapman FRS (6 December 1869 – 17 January 1958) was an English physical chemist, whose name is associated with the Chapman-Jouguet treatment (on the theory of detonation in gases) and the Gouy-Chapman layer (the surface layer of ions distributed on a charged surface). He was a fellow of Jesus College, Oxford for 37 years, and was in charge there of the last college laboratory at the University of Oxford. Education and early life Chapman was born in Wells, Norfolk but moved with his family to Manchester and attended Manchester Grammar School. He then went to Christ Church, Oxford, obtaining degrees in chemistry (1893, 1st class) and physics (1894, 2nd class). Personal life Campman was by reputation something of a scientific recluse, difficult to dislodge from his laboratory, although he did play a full part in University and College affairs. Away from his teaching and research, he was reserved and somewhat eccentric, but enjoyed golf, cycling and walking. H ...
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Werner Döring
Werner Döring (2 September 1911, Berlin – 6 June 2006, Malente) was a German theoretical physicist. From 1963 until his retirement in 1977, he was a full professor (Ordinarius) at the Universität Hamburg. His main interest was the theory of magnetism. His textbooks on theoretical physics have influenced several generations of students. He is remembered today for the Becker–Döring theory of nucleation of liquid droplets in solids (in condensed matter physics), and for the Zel'dovich–von Neumann–Döring detonation model (in explosives engineering). Selected publications * R. Becker, W. Döring, ''Kínetische Behandlung der Keimbildung in übersättigten Dämpfen'', Annalen der Physik 416, 719-752 (1935); https://doi.org/10.1002/andp.19354160806 * R. Becker, W. Döring, ''Ferromagnetismus'', Berlin, Springer 1939 * W. Döring, ''Einführung in die Theoretische Physik'' (Sammlung Göschen; fünf Bände: Mechanik, Elektrodynamik, Optik, Thermodynamik, Statistische Mechanik ...
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