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Deflagration
Deflagration (Lat: ''de + flagrare'', 'to burn down') is subsonic combustion in which a pre-mixed flame propagates through an explosive or a mixture of fuel and oxidizer. Deflagrations in high and low explosives or fuel–oxidizer mixtures may transition to a detonation depending upon confinement and other factors. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/s differ from detonations which propagate supersonically with detonation velocities in the range of km/s. Applications Deflagrations are often used in engineering applications when the force of the expanding gas is used to move an object such as a projectile down a barrel, or a piston in an internal combustion engine. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Terminology of explosive safety When studying or discussing explosive ...
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Explosives
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or Dust explosion, grain dust * pressure, pressurized gas compressor, gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear weapon, nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high ...
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Deflagration To Detonation Transition
Deflagration to detonation transition (DDT) refers to a phenomenon in ignitable mixtures of a flammable gas and air (or oxygen) when a sudden transition takes place from a deflagration type of combustion to a detonation type of explosion. Description A deflagration is characterized by a subsonic flame propagation velocity, typically far below , and relatively modest overpressures, typically below . The main mechanism of combustion propagation is of a flame front that moves forward through the gas mixture - in technical terms the reaction zone (chemical combustion) progresses through the medium by processes of diffusion of heat and mass. In its most benign form, a deflagration may simply be a flash fire. In contrast, a detonation is characterized by supersonic flame propagation velocities, perhaps up to , and substantial overpressures, up to . The main mechanism of detonation propagation is of a powerful pressure wave that compresses the unburnt gas ahead of the wave to a temp ...
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Explosions
An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated by a slower expansion that would normally not be forceful, but is not allowed to expand, so that when whatever is containing the expansion is broken by the pressure that builds as the matter inside tries to expand, the matter expands forcefully. An example of this is a volcanic eruption created by the expansion of magma in a magma chamber as it rises to the surface. Supersonic explosions created by high explosives are known as detonations and travel through shock waves. Subsonic explosions are created by low explosives through a slower combustion process known as deflagration. Causes For an explosion to occur, there must be a rapid, forceful expansion of matter. There are numerous ways this can happen, both naturally and artificially, ...
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Detonation Velocity
Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonated explosive. Explosive velocities are always higher than the local speed of sound in the material. If the explosive is confined before detonation, such as in an artillery shell, the force produced is focused on a much smaller area, and the pressure is significantly intensified. This results in an explosive velocity that is higher than if the explosive had been detonated in open air. Unconfined velocities are often approximately 70 to 80 percent of confined velocities. Explosive velocity is increased with smaller particle size (i.e., increased spatial density), increased charge diameter, and increased confinement (i.e., higher pressure). Typical detonation velocities for organic dust mixtures range from 1400 to 1650m/s. Gas explosions can either deflagrate or detonate based on confinement; detonation velocities are ge ...
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Conflagration
A conflagration is a large fire in the built environment that spreads via structure to structure ignition due to radiant or convective heat, or ember transmission. Conflagrations often damage human life, animal life, health, and/or property. A conflagration can begin Fire prevention, accidentally or be intentionally created (arson). A very large fire can produce a firestorm, in which the central column of rising heated air induces strong inward winds, which supply oxygen to the fire. Conflagrations can cause Casualty (person), casualties including deaths or injuries from burns, collapse of structures and attempts to escape, and smoke inhalation. Firefighting is the practice of extinguishing a conflagration, protecting life and property and minimizing damage and injury. One of the goals of fire prevention is to avoid conflagrations. When a conflagration is extinguished, there is often a fire investigation to determine the cause of the fire. Causes and types During a conflagrati ...
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Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds about 1 km/sec and differ from deflagrations which have subsonic flame speeds about 1 m/sec. Detonation may form from an explosion of fuel-oxidizer mixture. Compared with deflagration, detonation doesn't need to have an external oxidizer. Oxidizers and fuel mix when deflagration occurs. Detonation is more destructive than deflagrations. In detonation, the flame front travels through the air-fuel faster than sound; while in deflagration, the flame front travels through the air-fuel slower than sound. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. TNT, dynamite, and C4 are examples of high power explosives that detonate. The detonation velocity, velocity of detonation in solid an ...
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Fire
Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction Product (chemistry), products. Flames, the most visible portion of the fire, are produced in the combustion reaction when the fuel reaches its ignition point temperature. Flames from hydrocarbon fuels consist primarily of carbon dioxide, water vapor, oxygen, and nitrogen. If hot enough, the gases may become ionized to produce Plasma (physics), plasma. The color and Intensity (heat transfer), intensity of the flame depend on the type of fuel and composition of the surrounding gases. Fire, in its most common form, has the potential to result in conflagration, which can lead to permanent physical damage. It directly impacts land-based ecological systems worldwide. The positive effects of fire include stimulating plant growth and maintaining ecological balance. Its negative effects include hazards to life and property, atmospheric pollution, and water ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot e ...
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Pressure Piling
Pressure piling is a phenomenon related to combustion of gases in a tube or long vessel. When a flame front propagates along a tube, the unburned gases ahead of the front are compressed, and hence heated. The amount of compression varies depending on the geometry and can range from twice to eight times the initial pressure. Where multiple vessels are connected by piping, ignition of gases in one vessel and pressure piling may result in a deflagration to detonation transition and very large explosion pressure. In electrical equipment in hazardous areas, if two electrical enclosures are connected by a conduit, an explosion of a gas in one of the compartments travels through the conduit into the next enclosure.Ernest C. Magison, ''Electrical Instruments in Hazardous Locations 4th edition'', International Society of Automation, 1998 , page 153 The pressure of the 'primary' explosion together with the pressure from the 'secondary' explosion in the other compartment produces one huge ...
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Thermal Diffusivity
In thermodynamics, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It is a measure of the rate of heat transfer inside a material and has SI, SI units of m2/s. It is an intensive property. Thermal diffusivity is usually denoted by lowercase alpha (), but , , (kappa), , , D_T are also used. The formula is \alpha = \frac, where : is thermal conductivity (W/(m·K)), : is specific heat capacity (J/(kg·K)), : is density (kg/m3). Together, can be considered the volumetric heat capacity (J/(m3·K)). Thermal diffusivity is a positive coefficient in the heat equation: \frac = \alpha \nabla^2 T. One way to view thermal diffusivity is as the ratio of the time derivative of temperature to its Second derivative#Generalization to higher dimensions, curvature, quantifying the rate at which temperature concavity is "smoothed out". In a substance with high thermal diffusivity, heat moves rapidly through it because the ...
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