Angular Momentum Diagrams (quantum Mechanics)
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Angular Momentum Diagrams (quantum Mechanics)
In quantum mechanics and its applications to quantum many-particle systems, notably quantum chemistry, angular momentum diagrams, or more accurately from a mathematical viewpoint angular momentum graphs, are a diagrammatic method for representing angular momentum quantum states of a quantum system allowing calculations to be done symbolically. More specifically, the arrows encode angular momentum states in bra–ket notation and include the abstract nature of the state, such as tensor products and transformation rules. The notation parallels the idea of Penrose graphical notation and Feynman diagrams. The diagrams consist of arrows and vertices with quantum numbers as labels, hence the alternative term "graphs". The sense of each arrow is related to Hermitian conjugation, which roughly corresponds to time reversal of the angular momentum states (c.f. Schrödinger equation). The diagrammatic notation is a considerably large topic in its own right with a number of specialized featu ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Bra–ket Notation
In quantum mechanics, bra–ket notation, or Dirac notation, is used ubiquitously to denote quantum states. The notation uses angle brackets, and , and a vertical bar , to construct "bras" and "kets". A ket is of the form , v \rangle. Mathematically it denotes a vector, \boldsymbol v, in an abstract (complex) vector space V, and physically it represents a state of some quantum system. A bra is of the form \langle f, . Mathematically it denotes a linear form f:V \to \Complex, i.e. a linear map that maps each vector in V to a number in the complex plane \Complex. Letting the linear functional \langle f, act on a vector , v\rangle is written as \langle f , v\rangle \in \Complex. Assume that on V there exists an inner product (\cdot,\cdot) with antilinear first argument, which makes V an inner product space. Then with this inner product each vector \boldsymbol \phi \equiv , \phi\rangle can be identified with a corresponding linear form, by placing the vector in the anti-line ...
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Molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not consid ...
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Multielectron Atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. Atoms are extremely small, typically around 100 picometers across. They are so small that accurately predicting their behavior using classical physics, as if they were tennis balls for example, is not possible due to quantum effects. More than 99.94% of an atom's mass is in the nucleus. The protons have a positive electric charge, the electrons have a negative electric charge, and the neutrons have no electric charge. If the number of protons and electrons are equal, then the atom is electrically neutral. If an atom has more or fewer electrons than protons, then it has an overall negative or positive charge, respectively – such atoms are called ions. The electrons of an atom are attra ...
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Clebsch–Gordan Coefficients
In physics, the Clebsch–Gordan (CG) coefficients are numbers that arise in angular momentum coupling in quantum mechanics. They appear as the expansion coefficients of total angular momentum eigenstates in an uncoupled tensor product basis. In more mathematical terms, the CG coefficients are used in representation theory, particularly of compact Lie groups, to perform the explicit direct sum decomposition of the tensor product of two irreducible representations (i.e., a reducible representation into irreducible representations, in cases where the numbers and types of irreducible components are already known abstractly). The name derives from the German mathematicians Alfred Clebsch and Paul Gordan, who encountered an equivalent problem in invariant theory. From a vector calculus perspective, the CG coefficients associated with the SO(3) group can be defined simply in terms of integrals of products of spherical harmonics and their complex conjugates. The addition of spins in qu ...
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AM Diagrams Outer Product Contraction
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AM Diagrams Inner Product Contraction
AM or Am may refer to: Arts and entertainment Music * A minor, a minor scale in music * ''A.M.'' (Chris Young album) * ''A.M.'' (Wilco album) * ''AM'' (Abraham Mateo album) * ''AM'' (Arctic Monkeys album) * AM (musician), American musician * Am, the A minor chord symbol * ''Armeemarschsammlung'' (Army March Collection), catalog of German military march music * Andrew Moore (musician), Canadian musician known as A.M. * DJ AM, American DJ and producer * Skengdo & AM, British hip hop duo Television and radio * ''AM'' (ABC Radio), Australian current affairs radio program * '' American Morning'', American morning television news program * ''Am, Antes del Mediodía'', Argentine current affairs television program * Am, a character in the anthology '' Star Wars: Visions'' Other media * Allied Mastercomputer, the antagonist of the short story " I Have No Mouth, and I Must Scream" Education * Active Minds, a mental health awareness charity * Arts et Métiers ParisTech, a French ...
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Tensor Contraction
In multilinear algebra, a tensor contraction is an operation on a tensor that arises from the natural pairing of a finite-dimensional vector space and its dual. In components, it is expressed as a sum of products of scalar components of the tensor(s) caused by applying the summation convention to a pair of dummy indices that are bound to each other in an expression. The contraction of a single mixed tensor occurs when a pair of literal indices (one a subscript, the other a superscript) of the tensor are set equal to each other and summed over. In Einstein notation this summation is built into the notation. The result is another tensor with order reduced by 2. Tensor contraction can be seen as a generalization of the trace. Abstract formulation Let ''V'' be a vector space over a field ''k''. The core of the contraction operation, and the simplest case, is the natural pairing of ''V'' with its dual vector space ''V''∗. The pairing is the linear transformation from the tensor p ...
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Angular Momentum Operator
In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum problems involving rotational symmetry. Such an operator is applied to a mathematical representation of the physical state of a system and yields an angular momentum value if the state has a definite value for it. In both classical and quantum mechanical systems, angular momentum (together with linear momentum and energy) is one of the three fundamental properties of motion.Introductory Quantum Mechanics, Richard L. Liboff, 2nd Edition, There are several angular momentum operators: total angular momentum (usually denoted J), orbital angular momentum (usually denoted L), and spin angular momentum (spin for short, usually denoted S). The term ''angular momentum operator'' can (confusingly) refer to either the total or the orbital angular momen ...
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