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Sublimatory
image:sublimation apparatus.svg, 200px, Simple sublimation apparatus. Water usually cold, is circulated in cold finger to allow the desired compound to be deposited.1 Cooling water in 2 Cooling water out 3 Vacuum/gas line 4 Sublimation chamber 5 Sublimed compound 6 Crude material 7 External heating A sublimatory or sublimation apparatus is equipment, commonly laboratory glassware, for purification of Chemical compound, compounds by selective Sublimation (chemistry), sublimation. In principle, the operation resembles purification by distillation, except that the products do not pass through a liquid, liquid phase. Overview A typical sublimation apparatus separates a mix of appropriate solid materials in a vessel in which it applies heat under a controllable atmosphere (air, vacuum or inert gas). If the material is not at first solid, then it may freeze under reduced pressure. Conditions are so chosen that the solid volatility (chemistry), volatilizes and condenses as a purified comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Batch Production
Batch production is a method of manufacturing in which products are made as specified groups or amounts, within a time frame. A batch can go through a series of steps in a large manufacturing process to make the final desired product. Batch production is used for many types of manufacturing that may need smaller amounts of production at a time to ensure specific quality standards or changes in the process. This is opposed to large mass production Mass production, also known as mass production, series production, series manufacture, or continuous production, is the production of substantial amounts of standardized products in a constant flow, including and especially on assembly lines ... or continuous production methods, where the product or process does not need to be checked or changed as frequently or periodically. Characteristics In the manufacturing batch production process, the machines are in chronological order directly related to the manufacturing process. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Separation Processes
A separation process is a method that converts a mixture or a solution of chemical substances into two or more distinct product mixtures, a scientific process of separating two or more substances in order to obtain purity. At least one product mixture from the separation is enriched in one or more of the source mixture's constituents. In some cases, a separation may fully divide the mixture into pure constituents. Separations exploit differences in chemical properties or physical properties (such as size, shape, charge, mass, density, or chemical affinity) between the constituents of a mixture. Processes are often classified according to the particular properties they exploit to achieve separation. If no single difference can be used to accomplish the desired separation, multiple operations can often be combined to achieve the desired end. Different processes are also sometimes categorized by their separating agent, i.e. ''mass separating agents'' or ''energy separating agents ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laboratory Glassware
Laboratory glassware is a variety of equipment used in science, scientific work, traditionally made of glass. Glass may be blown, bent, cut, molded, or formed into many sizes and shapes. It is commonly used in chemistry, biology, and analytical laboratory, laboratories. Many laboratories have training programs to demonstrate how glassware is used and to alert first–time users to the Laboratory safety#Safety hazards, safety hazards involved with using glassware. History Ancient era The history of glassware dates back to the Phoenicians who fused obsidian together in campfires, making the first glassware. Glassware evolved as other ancient civilizations including the Syrians, Egyptians, and Romans refined the art of glassmaking. Mary the Jewess, an alchemist in Alexandria during the 1st century AD, is credited for the creation of some of the first glassware for chemical such as the ''kerotakis'' which was used for the collection of fumes from a heated material. Despite thes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alchemical Processes
Alchemy (from the Arabic word , ) is an ancient branch of natural philosophy, a philosophical and protoscientific tradition that was historically practised in China, India, the Muslim world, and Europe. In its Western form, alchemy is first attested in a number of pseudepigraphical texts written in Greco-Roman Egypt during the first few centuries AD.. Greek-speaking alchemists often referred to their craft as "the Art" (τέχνη) or "Knowledge" (ἐπιστήμη), and it was often characterised as mystic (μυστική), sacred (ἱɛρά), or divine (θɛíα). Alchemists attempted to purify, mature, and perfect certain materials. Common aims were chrysopoeia, the transmutation of "base metals" (e.g., lead) into "noble metals" (particularly gold); the creation of an elixir of immortality; and the creation of panaceas able to cure any disease. The perfection of the human body and soul was thought to result from the alchemical ''magnum opus'' ("Great Work"). The conce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Purification Methods In Chemistry
Purification in a chemical context is the physical separation of a chemical substance of interest from foreign or contaminating substances. Pure results of a successful purification process are termed isolate. The following list of chemical purification methods should not be considered exhaustive. * Affinity purification purifies proteins by retaining them on a column through their affinity to antibodies, enzymes, or receptors that have been immobilised on the column. *Filtration is a mechanical method to separate solids from liquids or gases by passing the feed stream through a porous sheet such as a cloth or membrane, which retains the solids and allows the liquid to pass through. *Centrifugation is a process that uses an electric motor to spin a vessel of fluid at high speed to make heavier components settle to the bottom of the vessel. *Evaporation removes volatile liquids from non-volatile solutes, which cannot be done through filtration due to the small size of the subs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Distillation
Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixture and the condensation of the vapors in a still. Distillation can operate over a wide range of pressures from 0.14 bar (e.g., ethylbenzene/ styrene) to nearly 21 bar (e.g., propylene/propane) and is capable of separating feeds with high volumetric flowrates and various components that cover a range of relative volatilities from only 1.17 ( o-xylene/ m-xylene) to 81.2 (water/ ethylene glycol). Distillation provides a convenient and time-tested solution to separate a diversity of chemicals in a continuous manner with high purity. However, distillation has an enormous environmental footprint, resulting in the consumption of approximately 25% of all industrial energy use. The key issue is that distillation operates based on phase changes, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vapor Pressure
Vapor pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid (or solid) in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as '' volatile''. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the attractive interactions between liquid molecules become less significant in comparison to the entropy of those molecules in the gas phase, increasing the vapor pressure. Thus, liquids with strong intermolecular interactions are likely to have smaller vapor pressures, with the reverse true for weaker interactions. The vapor p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sublimation Point
Sublimation is the transition of a substance directly from the solid to the gas state, without passing through the liquid state. The verb form of sublimation is ''sublime'', or less preferably, ''sublimate''. ''Sublimate'' also refers to the product obtained by sublimation. The point at which sublimation occurs rapidly (for further details, see below) is called critical sublimation point, or simply sublimation point. Notable examples include sublimation of dry ice at room temperature and atmospheric pressure, and that of solid iodine with heating. The reverse process of sublimation is ''deposition'' (also called ''desublimation''), in which a substance passes directly from a gas to a solid phase, without passing through the liquid state. Technically, all solids may sublime, though most sublime at extremely low rates that are hardly detectable under usual conditions. At normal pressures, most chemical compounds and elements possess three different states at different t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Distribution
In statistics, an empirical distribution function ( an empirical cumulative distribution function, eCDF) is the distribution function associated with the empirical measure of a sample. This cumulative distribution function is a step function that jumps up by at each of the data points. Its value at any specified value of the measured variable is the fraction of observations of the measured variable that are less than or equal to the specified value. The empirical distribution function is an estimate of the cumulative distribution function that generated the points in the sample. It converges with probability 1 to that underlying distribution, according to the Glivenko–Cantelli theorem. A number of results exist to quantify the rate of convergence of the empirical distribution function to the underlying cumulative distribution function. Definition Let be independent, identically distributed real random variables with the common cumulative distribution function . The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Processes
Classical thermodynamics considers three main kinds of thermodynamic processes: (1) changes in a system, (2) cycles in a system, and (3) flow processes. (1) A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored. A state of thermodynamic equilibrium endures unchangingly unless it is interrupted by a thermodynamic operation that initiates a thermodynamic process. The equilibrium states are each respectively fully specified by a suitable set of thermodynamic state variables, that depend only on the current state of the system, not on the path taken by the processes that produce the state. In general, during the actual course of a thermodynamic process, the system may pass through physical states which are not describable as th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Recrystallization (chemistry)
Recrystallization is a broad class of List of purification methods in chemistry , chemical purification techniques characterized by the dissolution of an impure sample in a solvent or solvent mixture, followed by some change in conditions that encourages the formation of pure isolate as solid crystals. Recrystallization as a purification technique is driven by spontaneous process , spontaneous processes of molecular self-assembly , self-assembly that leverage the highly ordered (i.e. low-entropy) and periodic characteristics of a crystal's molecular structure to produce purification. Basic principles The driving force of this purification emerges from the difference in molecular interactions between the isolate and the impurities: if a molecule of the desired isolate interacts with any isolate crystal present, it is likely the molecule Deposition (chemistry) , deposits on the crystal's ordered surface and contributes to the crystal's growth; if a molecule of the impurity inter ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
