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Rotational Spectroscopy
Rotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase. The spectra of polar molecules can be measured in absorption or emission by microwave spectroscopy or by far infrared spectroscopy. The rotational spectra of non-polar molecules cannot be observed by those methods, but can be observed and measured by Raman spectroscopy. Rotational spectroscopy is sometimes referred to as ''pure'' rotational spectroscopy to distinguish it from rotational-vibrational spectroscopy where changes in rotational energy occur together with changes in vibrational energy, and also from ro-vibronic spectroscopy (or just vibronic spectroscopy) where rotational, vibrational and electronic energy changes occur simultaneously. For rotational spectroscopy, molecules are classified according to symmetry into spherical top, linear and symmetric top; analytical expressions can be derived for the rotational ene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
CF3I Spectrum2
Trifluoroiodomethane, also referred to as trifluoromethyl iodide is a halomethane with the formula CF3I. It is an experimental alternative to Halon 1301 (CBrF3) in unoccupied areas. It would be used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. Chemistry It is used in the rhodium-catalyzed α-trifluoromethylation of α,β-unsaturated ketones. It can be used as a new generation fire extinguishing agent to replace Halon in fire protection systems. The mechanism of extinguishing fires for CF3I is active and primarily based on interruption of the chain reaction in the combustion area of the flame by so-called "negative" catalytic action. It is also used as an eco-friendly insulation gas to replace Sulfur hexafluoride , SF6 in electrical power industry. In the presence of sunlight or at temperatures above 100 °C it can react with water, forming hazardous by-products such as hydrogen fluoride (HF), hydrogen iodide (HI) and c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Moment Of Inertia
The moment of inertia, otherwise known as the mass moment of inertia, angular mass, second moment of mass, or most accurately, rotational inertia, of a rigid body is a quantity that determines the torque needed for a desired angular acceleration about a rotational axis, akin to how mass determines the force needed for a desired acceleration. It depends on the body's mass distribution and the axis chosen, with larger moments requiring more torque to change the body's rate of rotation. It is an extensive (additive) property: for a point mass the moment of inertia is simply the mass times the square of the perpendicular distance to the axis of rotation. The moment of inertia of a rigid composite system is the sum of the moments of inertia of its component subsystems (all taken about the same axis). Its simplest definition is the second moment of mass with respect to distance from an axis. For bodies constrained to rotate in a plane, only their moment of inertia about an axis ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atacama Large Millimeter Array
The Atacama Large Millimeter/submillimeter Array (ALMA) is an astronomical interferometer of 66 radio telescopes in the Atacama Desert of northern Chile, which observe electromagnetic radiation at millimeter and submillimeter wavelengths. The array has been constructed on the elevation Chajnantor plateau - near the Llano de Chajnantor Observatory and the Atacama Pathfinder Experiment. This location was chosen for its high elevation and low humidity, factors which are crucial to reduce noise and decrease signal attenuation due to Earth's atmosphere. ALMA provides insight on star birth during the early Stelliferous era and detailed imaging of local star and planet formation. ALMA is an international partnership amongst Europe, the United States, Canada, Japan, South Korea, Taiwan, and Chile. Costing about US$1.4 billion, it is the most expensive ground-based telescope in operation. ALMA began scientific observations in the second half of 2011 and the first images were relea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atmospheric Chemistry
Atmospheric chemistry is a branch of atmospheric science in which the chemistry of the Earth's atmosphere and that of other planets is studied. It is a multidisciplinary approach of research and draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology and other disciplines. Research is increasingly connected with other areas of study such as climatology. The composition and chemistry of the Earth's atmosphere is of importance for several reasons, but primarily because of the interactions between the atmosphere and living organisms. The composition of the Earth's atmosphere changes as result of natural processes such as volcano emissions, lightning and bombardment by solar particles from corona. It has also been changed by human activity and some of these changes are harmful to human health, crops and ecosystems. Examples of problems which have been addressed by atmospheric chemistry include acid rain, ozone depletion, photo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorine Monoxide
Chlorine monoxide is a chemical radical with the chemical formula ClO•. It plays an important role in the process of ozone depletion. In the stratosphere, chlorine atoms react with ozone molecules to form chlorine monoxide and oxygen. :Cl• + O3 → ClO• + O2 This reaction causes the depletion of the ozone layer. The resulting ClO• radicals can further react: : ClO• + O• → Cl• + O2 regenerating the chlorine radical. In this way, the overall reaction for the decomposition of ozone is catalyzed by chlorine, as ultimately chlorine remains unchanged. The overall reaction is: :O• + O3 → 2 O2 This has been a significant impact of the use of CFCs on the upper stratosphere, however many countries have agreed to ban the use of CFCs. The nonreactive nature of CFCs allows them to pass into the stratosphere, where they undergo photo-dissociation to form Cl radicals. These then readily form chlorine monoxide, and this cycle can continue until two radicals react ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyatomic
A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zero. The term molecule may or may not be used to refer to a polyatomic ion, depending on the definition used. The prefix ''poly-'' carries the meaning "many" in Greek, but even ions of two atoms are commonly described as polyatomic. In older literature, a polyatomic ion may instead be referred to as a ''radical'' (or less commonly, as a ''radical group''). In contemporary usage, the term ''radical'' refers to various free radicals, which are species that have an unpaired electron and need not be charged. A simple example of a polyatomic ion is the hydroxide ion, which consists of one oxygen atom and one hydrogen atom, jointly carrying a net charge of −1; its chemical formula is . In contrast, an ammonium ion consists of one nitrogen atom and four hydrogen atoms, with a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radio Astronomy
Radio astronomy is a subfield of astronomy that studies celestial objects at radio frequencies. The first detection of radio waves from an astronomical object was in 1933, when Karl Jansky at Bell Telephone Laboratories reported radiation coming from the Milky Way. Subsequent observations have identified a number of different sources of radio emission. These include stars and galaxies, as well as entirely new classes of objects, such as radio galaxies, quasars, pulsars, and masers. The discovery of the cosmic microwave background radiation, regarded as evidence for the Big Bang theory, was made through radio astronomy. Radio astronomy is conducted using large radio antennas referred to as radio telescopes, that are either used singularly, or with multiple linked telescopes utilizing the techniques of radio interferometry and aperture synthesis. The use of interferometry allows radio astronomy to achieve high angular resolution, as the resolving power of an interferometer is set ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halogen Bond
A halogen bond occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity. Like a hydrogen bond, the result is not a formal chemical bond, but rather a strong electrostatic attraction. Mathematically, the interaction can be decomposed in two terms: one describing an electrostatic, orbital-mixing charge-transfer and another describing electron-cloud dispersion. Halogen bonds find application in supramolecular chemistry; drug design and biochemistry; crystal engineering and liquid crystals; and organic catalysis. Definition Halogen bonds occur when a halogen atom is electrostatically attracted to a partial negative charge. Necessarily, the atom must be covalently bonded in an antipodal σ-bond; the electron concentration associated with that bond leaves a positively charged "hole" on the other side. Although all halogens can t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Bond
In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are the second-row elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of the same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction, and weaker than fully covalent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Der Waals Force
In molecular physics, the van der Waals force is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; they are comparatively weak and therefore more susceptible to disturbance. The van der Waals force quickly vanishes at longer distances between interacting molecules. Named after Dutch physicist Johannes Diderik van der Waals, the van der Waals force plays a fundamental role in fields as diverse as supramolecular chemistry, structural biology, polymer science, nanotechnology, surface science, and condensed matter physics. It also underlies many properties of organic compounds and molecular solids, including their solubility in polar and non-polar media. If no other force is present, the distance between atoms at which the force becomes repulsive rather than attractive as the atoms approach one another is called the van der Waals contact distance; this phenomenon resul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorotoluene
Chlorotoluene is a group of three isomeric chemical compounds. They (''ortho''-chlorotoluene, ''meta''-chlorotoluene, and ''para''-chlorotoluene) consist of a disubstituted benzene ring with one chlorine atom and one methyl group. Properties The isomers differ in the location of the chlorine, but have the same chemical formula. All have very similar boiling points, although p-chlorotoluene has a much higher melting point due to a more tightly packed crystal structure. Benzyl chloride is an isomer, which has a chlorine substituted for one of the hydrogens of toluene's methyl group, and it is sometimes named α-chlorotoluene. Preparation A laboratory route to 2- and 4-chlorotoluene proceeds from 2- and 4-toluidines (i.e. 2- and 4-aminotoluene). These compounds are diazotiized followed by treatment with cuprous chloride. Industrially, the diazonium method is reserved for 3-chlorotoluene. The industrial route to 2- and 4-chlorotoluene entails direct reaction of toluene with ch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radio Telescope
A radio telescope is a specialized antenna and radio receiver used to detect radio waves from astronomical radio sources in the sky. Radio telescopes are the main observing instrument used in radio astronomy, which studies the radio frequency portion of the electromagnetic spectrum emitted by astronomical objects, just as optical telescopes are the main observing instrument used in traditional optical astronomy which studies the light wave portion of the spectrum coming from astronomical objects. Unlike optical telescopes, radio telescopes can be used in the daytime as well as at night. Since astronomical radio sources such as planets, stars, nebulas and galaxies are very far away, the radio waves coming from them are extremely weak, so radio telescopes require very large antennas to collect enough radio energy to study them, and extremely sensitive receiving equipment. Radio telescopes are typically large parabolic ("dish") antennas similar to those employed in tracking an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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