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Regenerative Fuel Cell
A regenerative fuel cell or reverse fuel cell (RFC) is a fuel cell run in reverse mode, which consumes electricity and chemical B to produce chemical A. By definition, the process of any fuel cell could be reversed. However, a given device is usually optimized for operating in one mode and may not be built in such a way that it can be operated backwards. Standard fuel cells operated backwards generally do not make very efficient systems unless they are purpose-built to do so as with high-pressure electrolysers, regenerative fuel cells, solid-oxide electrolyser cells and unitized regenerative fuel cells. Process description A hydrogen fueled proton exchange membrane fuel cell, for example, uses hydrogen gas (H2) and oxygen (O2) to produce electricity and water (H2O); a regenerative hydrogen fuel cell uses electricity and water to produce hydrogen and oxygen. When the fuel cell is operated in regenerative mode, the anode for the electricity production mode (fuel cell mode) becomes ...
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Fuel Cell
A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen fuel, hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most battery (electricity), batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied. The first fuel cells were invented by Sir William Robert Grove, William Grove in 1838. The first commercial use of fuel cells came more than a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932. The alkaline fuel cell, also known as the Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for sat ...
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High-pressure Electrolysis
High-pressure electrolysis (HPE) is the electrolysis of water by decomposition of water (H2O) into oxygen (O2) and hydrogen gas (H2) due to the passing of an electric current through the water. The difference with a standard proton exchange membrane electrolyzer is the compressed hydrogen output around at 70 °C. By pressurising the hydrogen in the electrolyser the need for an external hydrogen compressor is eliminated, the average energy consumption for internal differential pressure compression is around 3%. Approaches As the required compression power for water is less than that for hydrogen-gas the water is pumped up to a high-pressure, in the other approach differential pressure is used. There is also an importance for the electrolyser stacks to be able to accept a fluctuating electrical input, such as that found with renewable energy. This then enables the ability to help with grid balancing and energy storage. Ultrahigh-pressure electrolysis Ultrahigh-pressure el ...
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Solid-oxide Electrolyser Cell
A solid oxide electrolyzer cell (SOEC) is a solid oxide fuel cell that runs in regenerative mode to achieve the electrolysis of water (and/or carbon dioxide) by using a solid oxide, or ceramic, electrolyte to produce hydrogen gas (and/or carbon monoxide) and oxygen. The production of pure hydrogen is compelling because it is a clean fuel that can be stored, making it a potential alternative to batteries, methane, and other energy sources (see hydrogen economy). Electrolysis is currently the most promising method of hydrogen production from water due to high efficiency of conversion and relatively low required energy input when compared to thermochemical and photocatalytic methods. Principle Solid oxide electrolyzer cells operate at temperatures which allow high-temperature electrolysis to occur, typically between 500 and 850 °C. These operating temperatures are similar to those conditions for a solid oxide fuel cell. The net cell reaction yields hydrogen and oxygen gases. T ...
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Unitized Regenerative Fuel Cell
A unitized regenerative fuel cell (URFC) is a fuel cell based on the proton exchange membrane which can do the electrolysis of water in regenerative mode and function in the other mode as a fuel cell recombining oxygen and hydrogen gas to produce electricity. Both modes are done with the same fuel cell stack By definition, the process of any fuel cell could be reversed. However, a given device is usually optimized for operating in one mode and may not be built in such a way that it can be operated backwards. Fuel cells operated backwards generally do not make very efficient systems unless they are purpose-built to do so as in high pressure electrolyzers, unitized regenerative fuel cells and regenerative fuel cells. History Livermore physicist Fred Mitlitsky studied the possibilities of reversible technology. In the mid-1990s Mitlitsky received some funding from NASA for development of Helios and from the Department of Energy for leveling peak and intermittent power usage with ...
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Proton Exchange Membrane Fuel Cell
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei). One or more protons are present in the nucleus of every atom. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol ''Z''). Since each element has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element. The word ''proton'' is Greek for "first", and this name was given to the ...
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Hydrogen Gas
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the abundance of the chemical elements, most abundant chemical substance in the universe, constituting roughly 75% of all baryon, normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in Molecular geometry, molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral ...
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Solid Oxide Fuel Cell
A solid oxide fuel cell (or SOFC) is an electrochemical conversion device that produces electricity directly from oxidizing a fuel. Fuel cells are characterized by their electrolyte material; the SOFC has a solid oxide or ceramic electrolyte. Advantages of this class of fuel cells include high combined heat and power efficiency, long-term stability, fuel flexibility, low emissions, and relatively low cost. The largest disadvantage is the high operating temperature which results in longer start-up times and mechanical and chemical compatibility issues. Introduction Solid oxide fuel cells are a class of fuel cells characterized by the use of a solid oxide material as the electrolyte. SOFCs use a solid oxide electrolyte to conduct negative oxygen ions from the cathode to the anode. The electrochemical oxidation of the hydrogen, carbon monoxide or other organic intermediates by oxygen ions thus occurs on the anode side. More recently, proton-conducting SOFCs (PC-SOFC) are being deve ...
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Glossary Of Fuel Cell Terms
The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few. A Activation loss : See overpotential Adsorption : Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a film of molecules or atoms (the adsorbate). Alkali : In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Alkali anion exchange membrane An alkali anion exchange membrane (AAEM) is a semipermeable membrane generally made from ionomers and designed to conduct anions while being impermeable to gases such as oxygen or hydrogen. Alkaline fuel cell : Alkaline fuel cell (AFC) also known as the Bacon fuel cell. Alloy : An alloy is a solid solution or homogeneous mixture of two or m ...
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Hydrogen Technologies
Hydrogen technologies are technologies that relate to the production and use of hydrogen as a part hydrogen economy. Hydrogen technologies are applicable for many uses. Some hydrogen technologies are carbon neutral and could have a role in preventing climate change and a possible future hydrogen economy. Hydrogen is a chemical widely used in various applications including ammonia production, oil refining and energy. The most common methods for producing hydrogen on an industrial scale are: Steam reforming, oil reforming, coal gasification, water electrolysis. Hydrogen is not a primary energy source, because it is not naturally occurring as a fuel. It is, however, widely regarded as an ideal energy storage medium, due to the ease with which electricity can convert water into hydrogen and oxygen through electrolysis and can be converted back to electrical power using a fuel cell. There are a wide number of different types of fuel and electrolysis cells. The potential envir ...
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Flow Battery
A flow battery, or redox flow battery (after reduction–oxidation), is a type of electrochemical cell where chemical energy is provided by two chemical components dissolved in liquids that are pumped through the system on separate sides of a membrane. Ion transfer inside the cell (accompanied by flow of electric current through an external circuit) occurs through the membrane while both liquids circulate in their own respective space. Cell voltage is chemically determined by the Nernst equation and ranges, in practical applications, from 1.0 to 2.43 volts. The energy capacity is a function of the electrolyte volume and the power is a function of the surface area of the electrodes. A flow battery may be used like a fuel cell (where the spent fuel is extracted and new fuel is added to the system) or like a rechargeable battery (where an electric power source drives regeneration of the fuel). While flow batteries have certain technical advantages over conventional rechargeable ...
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