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Red Rot
Red rot is a degradation process found in vegetable-tanned leather. Red rot is caused by prolonged storage or exposure to high relative humidity, environmental pollution, and high temperature. In particular, red rot occurs at pH values of 4.2 to 4.5. Sulfur dioxide converts to sulfurous acid which forms hydrogen peroxide. The peroxide combines with residual tannins in the leather to oxidize proteins, creating ammonium sulfate and ammonium bisulfate. Red rot is also caused by problems in the tanning or in the bookbinding. In the tanning examples are: sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ... residue, use of contaminated water and incomplete tanning. The bookbinding process can cause red rot when acids and bases are used when coloring the leather. The de ...
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Red Rot Leather
Red is the color at the long wavelength end of the visible spectrum of light, next to orange and opposite violet. It has a dominant wavelength of approximately 625–750 nanometres. It is a primary color in the RGB color model and a secondary color (made from magenta and yellow) in the CMYK color model, and is the complementary color of cyan. Reds range from the brilliant yellow-tinged scarlet and vermillion to bluish-red crimson, and vary in shade from the pale red pink to the dark red burgundy. Red pigment made from ochre was one of the first colors used in prehistoric art. The Ancient Egyptians and Mayans colored their faces red in ceremonies; Roman generals had their bodies colored red to celebrate victories. It was also an important color in China, where it was used to color early pottery and later the gates and walls of palaces. In the Renaissance, the brilliant red costumes for the nobility and wealthy were dyed with kermes and cochineal. The 19th century brought the ...
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Bookbinding
Bookbinding is the process of building a book, usually in codex format, from an ordered stack of paper sheets with one's hands and tools, or in modern publishing, by a series of automated processes. Firstly, one binds the sheets of papers along an edge with a thick needle and strong thread. One can also use loose-leaf rings, binding posts, twin-loop spine coils, plastic spiral coils, and plastic spine combs, but they last for a shorter time. Next, one encloses the bound stack of paper in a cover. Finally, one places an attractive cover onto the boards, and features the publisher's information and artistic decorations. The trade of bookbinding includes the binding of blank books and printed books. Blank books, or stationery bindings, are books planned to be written in. These include accounting ledgers, guestbooks, logbooks, notebooks, manifold books, day books, diary, diaries, and sketchbooks. Printed books are produced through letterpress printing, offset printing, offset litho ...
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Leather
Leather is a strong, flexible and durable material obtained from the tanning (leather), tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hogs, ostriches, and aquatic animals such as seals and alligators. Leather can be used to make a variety of items, including clothing, footwear, handbags, furniture, tools and sports equipment, and lasts for decades. Leather making has been practiced for more than 7,000 years and the leading producers of leather today are China and India. Critics of tanneries claim that they engage in unsustainable practices that pose health hazards to the people and the environment near them. Production processes The leather manufacturing process is divided into three fundamental subprocesses: preparatory stages, tanning, and crusting. A further subprocess, finishing, can be added into the leather process sequence, but not all leathers ...
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Journal Of The Institute Of Conservation
The Institute of Conservation (Icon) is the professional charitable body, representing and supporting the practice and profession of conservation. It has around 2500 members worldwide, including professional conservators, scientists and teachers involved with the care of heritage objects and buildings. Background The institute is the UK professional body for those who care for the cultural heritage.  This includes the items and collections held by public and private museums, art galleries, libraries, archives, record offices and historic houses; as well as privately owned possessions in people's homes, from furniture to family photographs.   Cultural heritage includes buildings as well as movable items in collections. Icon's members - conservators and restorers - care for things attached to buildings too, like wall paintings or sculpture, but the care of built structures themselves is mostly the domain of conservation architects represented by the Institute of Historic Build ...
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Aluminium Alkoxide
Aluminium (or aluminum in North American English) is a chemical element; it has symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has a great affinity towards oxygen, forming a protective layer of oxide on the surface when exposed to air. It visually resembles silver, both in its color and in its great ability to reflect light. It is soft, nonmagnetic, and ductile. It has one stable isotope, 27Al, which is highly abundant, making aluminium the 12th-most abundant element in the universe. The radioactivity of 26Al leads to it being used in radiometric dating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it has more polarizing power, and bonds formed by aluminium have a more covalent character. The strong af ...
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Renaissance Wax
Renaissance Wax is a brand of microcrystalline wax Polishing, polish used in Antiques restoration, antique restoration and museum conservation around the world. Commonly used to polish and conserve metal objects, it is also used on gemstones and such organic materials as wood, ivory, and tortoiseshell. The product is sometimes used by Historical reenactment, reenactors to protect armor and weapons. Waxes are more protective and longer-lasting than oil, especially for swords and helmets that are frequently touched by human hands. It has recently been introduced in the world of guitar building, as a finish that protects and gives colour to the wood. Wax coatings for conservation are most widely, and least controversially, applied to metals. This has several objectives: to produce a barrier that excludes moisture and oxygen from the metal surface, to preclude the introduction of contaminating elements by handling, and to provide a protective layer over anti-corrosion undercoatings ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Leather
Leather is a strong, flexible and durable material obtained from the tanning (leather), tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hogs, ostriches, and aquatic animals such as seals and alligators. Leather can be used to make a variety of items, including clothing, footwear, handbags, furniture, tools and sports equipment, and lasts for decades. Leather making has been practiced for more than 7,000 years and the leading producers of leather today are China and India. Critics of tanneries claim that they engage in unsustainable practices that pose health hazards to the people and the environment near them. Production processes The leather manufacturing process is divided into three fundamental subprocesses: preparatory stages, tanning, and crusting. A further subprocess, finishing, can be added into the leather process sequence, but not all leathers ...
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Ammonium Bisulfate
Ammonium bisulfate, also known as ammonium hydrogen sulfate, is a white, crystalline solid with the formula (NH4)HSO4. This salt is the product of the half-neutralization of sulfuric acid by ammonia. Production It is commonly collected as a byproduct of the "acetone cyanohydrin route" to the commodity chemical methyl methacrylate. It can also be obtained by hydrolysis of sulfamic acid in aqueous solution, which produces the salt in high purity: : It also arises by the thermal decomposition of ammonium sulfate: : Applications It can be further neutralized with ammonia to form ammonium sulfate, a valuable fertilizer A fertilizer or fertiliser is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from liming materials or other non-nutrient soil amendments. Man .... It can be used as a weaker alternative to sulfuric acid, although sodium bisulfate is much more common. Natural oc ...
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Ammonium Sulfate
Ammonium sulfate (American English and international scientific usage; ammonium sulphate in British English); (NH4)2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen and 24% sulfur. Uses Agriculture The primary use of ammonium sulfate is as a fertilizer for alkaline soils. In the soil, the ammonium ion is released and forms a small amount of acid, lowering the pH balance of the soil, while contributing essential nitrogen for plant growth. One disadvantage to the use of ammonium sulfate is its low nitrogen content relative to ammonium nitrate, which elevates transportation costs. It is also used as an agricultural spray adjuvant for water-soluble insecticides, herbicides, and fungicides. There, it functions to bind iron and calcium cations that are present in both well water and plant cells. It is particularly effective as an adjuvant for 2,4-D (amine), glyphosate, and glufosinate herbicides. ...
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