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Polychloroprene
Neoprene (also polychloroprene) is a family of synthetic rubbers that are produced by polymerization of chloroprene.Werner Obrecht, Jean-Pierre Lambert, Michael Happ, Christiane Oppenheimer-Stix, John Dunn and Ralf Krüger "Rubber, 4. Emulsion Rubbers" in Ullmann's Encyclopedia of Industrial Chemistry, 2012, Wiley-VCH, Weinheim. Neoprene exhibits good chemical stability and maintains flexibility over a wide temperature range. Neoprene is sold either as solid rubber or in latex form and is used in a wide variety of commercial applications, such as laptop sleeves, orthopaedic braces (wrist, knee, etc.), electrical insulation, liquid and sheet-applied elastomeric membranes or flashings, and automotive fan belts. Production Neoprene is produced by free-radical polymerization of chloroprene. In commercial production, this polymer is prepared by free radical emulsion polymerization. Polymerization is initiated using potassium persulfate. Bifunctional nucleophiles, metal oxides (e.g ...
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Chloroprene
Chloroprene is the common name for 2-chlorobuta-1,3-diene (IUPAC name) with the chemical formula CH2=CCl−CH=CH2. Chloroprene is a colorless volatile liquid, almost exclusively used as a monomer for the production of the polymer polychloroprene, better known as neoprene, a type of synthetic rubber. History Although it may have been discovered earlier, chloroprene was largely developed by DuPont during the early 1930s, specifically with the formation of neoprene in mind. The chemists Elmer K. Bolton, Wallace Carothers, Arnold Collins and Ira Williams are generally accredited with its development and commercialisation although the work was based upon that of Julius Arthur Nieuwland, with whom they collaborated. Production Chloroprene is produced in three steps from 1,3-butadiene: (i) chlorination, (ii) isomerization of part of the product stream, and (iii) dehydrochlorination of 3,4-dichlorobut-1-ene. Chlorine adds to 1,3-butadiene to afford a mixture of 3,4-dichlorobut-1-ene ...
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Hydrogen Chloride
The compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colourless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry. Hydrochloric acid, the aqueous solution of hydrogen chloride, is also commonly given the formula HCl. Reactions Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a polar covalent bond. The chlorine atom is much more electronegative than the hydrogen atom, which makes this bond polar. Consequently, the molecule has a large dipole moment with a negative partial charge (δ−) at the chlorine atom and a positive partial charge (δ+) at the hydrogen atom. In part because of its high polarity, HCl is very soluble in water (and in other polar solvents). Upon contact, and HCl combine to form hydronium cations and ...
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Thiourea
Thiourea () is an organosulfur compound with the formula and the structure . It is structurally similar to urea (), except that the oxygen atom is replaced by a sulfur atom (as implied by the ''thio-'' prefix); however, the properties of urea and thiourea differ significantly. Thiourea is a reagent in organic synthesis. "Thioureas" refer to a broad class of compounds with the general structure . Thioureas are related to thioamides, e.g. , where R is methyl, ethyl, etc. Structure and bonding Thiourea is a planar molecule. The C=S bond distance is 1.71 Å. The C-N distances average 1.33 Å. The weakening of the C-S bond by C-N pi-bonding is indicated by the short C=S bond in thiobenzophenone, which is 1.63 Å. Thiourea occurs in two tautomeric forms, of which the thione form predominates in aqueous solutions. The equilibrium constant has been calculated as ''K''eq is . The thiol form, which is also known as an isothiourea, can be encountered in substituted compounds such as i ...
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Dry Suit
A dry suit or drysuit provides the wearer with environmental protection by way of thermal insulation and exclusion of water, and is worn by divers, boaters, water sports enthusiasts, and others who work or play in or near cold or contaminated water. A dry suit normally protects the whole body except the head, hands, and possibly the feet. In hazmat configurations, however, all of these are covered as well. The main difference between dry suits and wetsuits is that dry suits are designed to prevent water from entering. This generally allows better insulation, making them more suitable for use in cold water. Dry suits can be uncomfortably hot in warm or hot air, and are typically more expensive and more complex to don. For divers, they add some degree of operational complexity and hazard as the suit must be inflated and deflated with changes in depth in order to minimize "squeeze" on descent or uncontrolled rapid ascent due to excessive buoyancy, which requires additional skills ...
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Chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a Chemical reaction, reaction with other Chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties ...
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Hose (tubing)
A hose is a flexible hollow tube designed to carry fluids from one location to another. Hoses are also sometimes called ''pipes'' (the word ''pipe'' usually refers to a rigid tube, whereas a hose is usually a flexible one), or more generally '' tubing''. The shape of a hose is usually cylindrical (having a circular cross section). Hose design is based on a combination of application and performance. Common factors are size, pressure rating, weight, length, straight hose or coilhose, and chemical compatibility. Applications mostly use nylon, polyurethane, polyethylene, PVC, or synthetic or natural rubbers, based on the environment and pressure rating needed. In recent years, hoses can also be manufactured from special grades of polyethylene (LDPE and especially LLDPE). Other hose materials includPTFE(Teflon), stainless steel, and other metals. Dredge rubber hoses have a long story, which features high strength and flexibility. A flexible dredging hose widely used in dredgers ...
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Gasket
Some seals and gaskets A gasket is a mechanical seal which fills the space between two or more mating surfaces, generally to prevent leakage from or into the joined objects while under compression. It is a deformable material that is used to create a static seal and maintain that seal under various operating conditions in a mechanical assembly. Gaskets allow for "less-than-perfect" mating surfaces on machine parts where they can fill irregularities. Gaskets are commonly produced by cutting from sheet materials. Given the potential cost and safety implications of faulty or leaking gaskets, it is critical that the correct gasket material is selected to fit the needs of the application. Gaskets for specific applications, such as high pressure steam systems, may contain asbestos. However, due to health hazards associated with asbestos exposure, non-asbestos gasket materials are used when practical. It is usually desirable that the gasket be made from a material that is to some de ...
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Natural Rubber
Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and Indonesia are three of the leading rubber producers. Types of polyisoprene that are used as natural rubbers are classified as elastomers. Currently, rubber is harvested mainly in the form of the latex from the rubber tree (''Hevea brasiliensis'') or others. The latex is a sticky, milky and white colloid drawn off by making incisions in the bark and collecting the fluid in vessels in a process called "tapping". The latex then is refined into the rubber that is ready for commercial processing. In major areas, latex is allowed to coagulate in the collection cup. The coagulated lumps are collected and processed into dry forms for sale. Natural rubber is used extensively in many applications and products, either alone or in combination wit ...
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Xtra Tufs
Extra or Xtra may refer to: Arts, entertainment and media Film * ''The Extra'' (1962 film), a Mexican film * ''The Extra'' (2005 film), an Australian film Literature * ''Extra'' (newspaper), a Brazilian newspaper * ''Extra!'', an American media criticism magazine * ''Diario Extra'' (Costa Rica), a newspaper * Newspaper extra, a supplemental issue * ''Xtra'' (newspaper), by the Norwegian Young Conservatives, 1922-2010 * ''Xtra Magazine'', a Canadian website and former newspaper Music * ''Extra'' (Gilberto Gil album), 1983, and the title track * '' Extra, Vol. 1'', an album by KMFDM * "Extra", a 2019 song by Future from ''Save Me (EP)'' * "Extra", a 1966 song by Tages from their album ''Extra Extra'' Television and radio * Extra (Australian TV channel) * ''Extra'' (Australian TV program), 1991–2009 * ''Extra'' (American TV program), since 1994 * ''extra'' (franchise), or extr@, a language education television program 2002–2004 * ''Extra'', a TV game by Norsk Tipping ...
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Ira Williams
Ira Williams (1894–1977) was an American chemist at DuPont's Jackson Laboratory in New Jersey, who in 1930 made commercial Neoprene possible by producing a soft, plastic form of chloroprene that could be processed by the rubber industry. He won the 1946 Charles Goodyear Medal The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, and consists of a gold medal, a framed c .... References 20th-century American chemists Polymer scientists and engineers 1894 births 1977 deaths {{US-chemist-stub ...
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Arnold M
Arnold may refer to: People * Arnold (given name), a masculine given name * Arnold (surname), a German and English surname Places Australia * Arnold, Victoria, a small town in the Australian state of Victoria Canada * Arnold, Nova Scotia United Kingdom * Arnold, East Riding of Yorkshire * Arnold, Nottinghamshire United States * Arnold, California, in Calaveras County * Arnold, Carroll County, Illinois * Arnold, Morgan County, Illinois * Arnold, Iowa * Arnold, Kansas * Arnold, Maryland * Arnold, Mendocino County, California * Arnold, Michigan * Arnold, Minnesota * Arnold, Missouri * Arnold, Nebraska * Arnold, Ohio * Arnold, Pennsylvania * Arnold, Texas * Arnold, Brooke County, West Virginia * Arnold, Lewis County, West Virginia * Arnold, Wisconsin * Arnold Arboretum of Harvard University, Massachusetts * Arnold Township, Custer County, Nebraska Other uses * Arnold (automobile), a short-lived English car * Arnold of Manchester, a former English coachbuilder * Arnold (band ...
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Wallace Carothers
Wallace Hume Carothers (; April 27, 1896 – April 29, 1937) was an American chemist, inventor and the leader of organic chemistry at DuPont, who was credited with the invention of nylon. Carothers was a group leader at the DuPont Experimental Station laboratory, near Wilmington, Delaware, where most polymer research was done. Carothers was an organic chemist who, in addition to first developing nylon, also helped lay the groundwork for neoprene. After receiving his Ph.D., he taught at several universities before he was hired by DuPont to work on fundamental research. He married Helen Sweetman on February 21, 1936. Carothers had been troubled by periods of depression since his youth. Despite his success with nylon, he felt that he had not accomplished much and had run out of ideas. His unhappiness was exacerbated by the death of his sister, and on April 28, 1937, he committed suicide by drinking potassium cyanide. His daughter, Jane, was born on November 27, 1937. Educatio ...
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