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Pollucite
Pollucite is a zeolite mineral with the formula with iron, calcium, rubidium and potassium as common substituting elements. It is important as a significant ore of caesium and sometimes rubidium. It forms a solid solution series with analcime. It crystallizes in the isometric - hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well formed crystals are rare. It has a Mohs hardness of 6.5 and a specific gravity of 2.9. It has a brittle fracture and no cleavage. Discovery and occurrence It was first described by August Breithaupt in 1846 for occurrences on the island of Elba, Italy. It is named for Pollux, the twin of Castor on the grounds that it is often found associated with petalite (previously known as ''castorite''). The high caesium content was missed by the first analysis by Karl Friedrich Plattner in 1848, but after the discovery of caesium in 1860 a second analysis in 1864 was able to show the high caesium content of pollucite. It ...
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Cesium
Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at . It is the least electronegative element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. The element has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the newly developed method of flame spectroscopy. The first small-scale applications for caesium were a ...
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Caesium
Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at . It is the least electronegative element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. The element has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the newly developed method of flame spectroscopy. The first small-scale applications for caesium ...
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Pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known. Many of the world's largest crystals are found within pegmatites. These include crystals of microcline, quartz, mica, spodumene, beryl, and tourmaline. Some individual crystals are over long. Most pegmatites are thought to form from the last fluid fraction of a large crystallizing magma body. This residual fluid is highly enriched in volatiles and trace elements, and its very low viscosity allows molecules to migrate rapidly to join an existing crystal rather than coming together to form new crystals. This allows a few very large crystals to form. While most pegmatites have a simple composition of minerals common in ordinary igneous rock, a few ...
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Zeolite
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. exchanged zeolites are particularly useful as solid acid catalysts. The term ''zeolite'' was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating a material, believed to have been stilbite, produced large amounts of steam from water that had been adsorbed by the material. Based on this, he called the material ''zeolite'', from the Greek , meaning "to boil" and , meaning "stone". Zeolites occur naturally but are also produced industrially on a large scale. , 253 unique zeolite frameworks have been identified, and over 40 naturally occurring zeolite frameworks are known. Every new zeolite structure that is ob ...
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Elbaite
Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, is a mineral species belonging to the six-member ring cyclosilicate tourmaline group. Elbaite forms three series, with dravite, with fluor-liddicoatite, and with schorl. Due to these series, specimens with the ideal endmember formula are not found occurring naturally. As a gemstone, elbaite is a desirable member of the tourmaline group because of the variety and depth of its colours and quality of the crystals. Originally discovered on the island of Elba, Italy in 1913, it has since been found in many parts of the world. In 1994, a major locality was discovered in Canada, at O'Grady Lakes in the Yukon. Elbaite forms in igneous and metamorphic rocks and veins in association with lepidolite, microcline, and spodumene in granite pegmatites; with andalusite and biotite in schist; and with molybdenite and cassiterite in massive hydrothermal replacement deposits. ...
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Lepidolite
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula . It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium. Lepidolite is found with other lithium-bearing minerals, such as spodumene, in pegmatite bodies. It has also been found in high-temperature quartz veins, greisens and granite. Description Lepidolite is a phyllosilicate mineral and a member of the polylithionite-trilithionite series. Lepidolite is part of a three-part series consisting of polylithionite, lepidolite, and trilithionite. All three minerals share similar properties and are caused because of varying ratios of lithium and aluminum in their chemical formulas. The Li:Al ratio varies from 2:1 in polylithionite up to 1.5:1.5 in trilithionite. Lepidolite is found naturally in a variety of colors, mainly pink, purple, and red, but also gray and, rarely, yellow and colorless. Because ...
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Amblygonite
Amblygonite () is a fluorophosphate mineral, , composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with ''montebrasite'', the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France. History The mineral was first discovered in Saxony by August Breithaupt in 1817, and named by him from the Greek ''amblus'', blunt, and ''gonia'', angle, because of the obtuse angle between the cleavages. Later it was found at Montebras, Creuse, France, a ...
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Spodumene
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of in size are reported from the Black Hills of South Dakota, United States. The naturally-occurring low-temperature form α-spodumene is in the monoclinic system , and the high-temperature β-spodumene crystallizes in the tetragonal system. α-spodumene converts to β-spodumene at temperatures above 900 °C. Crystals are typically heavily striated parallel to the principal axis. Crystal faces are often etched and pitted with triangular markings. Discovery and occurrence Spodumene was first described in 1800 for an occurrence in the type locality in Utö, Södermanland, Sweden. It was discovered by Brazilian naturalist Jose Bonifacio de Andrada e Silva. The name is derived fro ...
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Quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO2. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar. Quartz exists in two forms, the normal α-quartz and the high-temperature β-quartz, both of which are chiral. The transformation from α-quartz to β-quartz takes place abruptly at . Since the transformation is accompanied by a significant change in volume, it can easily induce microfracturing of ceramics or rocks passing through this temperature threshold. There are many different varieties of quartz, several of which are classified as gemstones. Since antiquity, varieties of quartz have been the most commonly used minerals in the making of jewelry and hardstone carvings, especially in Eurasia. Quartz is the mineral defining the val ...
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Karl Friedrich Plattner
Karl Friedrich Plattner (2 January 1800 – 22 January 1858) was a German metallurgical chemist. He was born at Kleinwaltersdorf, near Freiberg in the Electorate of Saxony, on 2 January 1800. His father, though only a poor working miner, found the means to have him educated first at the ''Bergschule'' (mining school) and then at the ''Bergakademie'' of Freiberg. After he had completed his courses there in 1820 he obtained employment, chiefly as an assayer, in connexion with the royal mines and metal works. Having taken up the idea of quantitative mouth blowpipe assaying, which was then almost unknown, he succeeded in devising dependable methods for all the ordinary useful metals. In particular his modes of assaying for nickel and cobalt Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element ...
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Petalite
Petalite, also known as castorite, is a lithium aluminum phyllosilicate mineral Li Al Si4 O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumen formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones. Discovery and occurrence Petalite was discovered in 1800, by Brazilian naturalist and statesman Jose Bonifacio de Andrada e Silva. Type locality: Utö Island, Haninge, Stockholm, Sweden. The name is der ...
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