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Plutonium-241
Plutonium-241 ( or Pu-241) is an isotope of plutonium formed when plutonium-240 captures a neutron. Like some other plutonium isotopes (especially 239Pu), 241Pu is fissile, with a neutron absorption cross section about one-third greater than that of 239Pu, and a similar probability of fissioning on neutron absorption, around 73%. In the non-fission case, neutron capture produces plutonium-242. In general, isotopes with an odd number of neutrons are both more likely to absorb a neutron and more likely to undergo fission on neutron absorption than isotopes with an even number of neutrons. Decay properties Plutonium-241 is a beta emitter with a half-life of 14.3 years, corresponding to a decay of about 5% of 241Pu nuclei over a one-year period. This decay has a ''Q''-value of and a mean of , and does not emit gamma rays. The longer spent nuclear fuel waits before reprocessing, the more 241Pu decays to americium-241, which is nonfissile (although fissionable by fast neutrons ...
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Isotope Of Plutonium
Plutonium (Pu) is an artificial element, except for trace quantities resulting from neutron capture by uranium, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized before being found in nature, with the first isotope synthesized being Pu in 1940. Twenty-two plutonium radioisotopes have been characterized. The most stable are Pu with a half-life of 81.3 million years; Pu with a half-life of 373,300 years; Pu with a half-life of 24,110 years; and Pu with a half-life of 6,560 years. This element also has eight meta states; all have half-lives of less than one second. The known isotopes of plutonium range from Pu to Pu. The primary decay modes before the most stable isotope, Pu, are spontaneous fission and alpha decay; the primary mode after is beta emission. The primary decay products before Pu are isotopes of uranium and neptunium (not considering fission products), and the primary decay products after are is ...
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Plutonium-240
Plutonium-240 ( or Pu-240) is an isotope of plutonium formed when plutonium-239 captures a neutron. The detection of its spontaneous fission led to its discovery in 1944 at Los Alamos and had important consequences for the Manhattan Project. 240Pu undergoes spontaneous fission as a secondary decay mode at a small but significant rate. The presence of 240Pu limits plutonium's use in a nuclear bomb, because the neutron flux from spontaneous fission initiates the chain reaction prematurely, causing an early release of energy that physically disperses the core before full implosion is reached. It decays by alpha emission to uranium-236. Nuclear properties About 62% to 73% of the time when 239Pu captures a neutron, it undergoes fission; the remainder of the time, it forms 240Pu. The longer a nuclear fuel element remains in a nuclear reactor, the greater the relative percentage of 240Pu in the fuel becomes. The isotope 240Pu has about the same thermal neutron capture cros ...
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Americium-241
Americium-241 (Am, Am-241) is an isotope of americium. Like all isotopes of americium, it is radioactive, with a half-life of . Am is the most common isotope of americium as well as the most prevalent isotope of americium in nuclear waste. It is commonly found in ionization type smoke detectors and is a potential fuel for long-lifetime radioisotope thermoelectric generators (RTGs). Its common parent nuclides are β from Pu, EC from Cm, and α from Bk. Am is not fissile, but is fissionable, and the critical mass of a bare sphere is and a sphere diameter of . Americium-241 has a specific activity of . It is commonly found in the form of americium-241 dioxide (AmO). This isotope also has one meta state, Am, with an excitation energy of and a half-life of . The presence of Am in plutonium is determined by the original concentration of plutonium-241 and the sample age. Because of the low penetration of alpha radiation, americium-241 only poses a health risk when ingested ...
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Nuclear Waste
Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment. Radioactive waste is broadly classified into 3 categories: low-level waste (LLW), such as paper, rags, tools, clothing, which contain small amounts of mostly short-lived radioactivity; intermediate-level waste (ILW), which contains higher amounts of radioactivity and requires some shielding; and high-level waste (HLW), which is highly radioactive and hot due to decay heat, thus requiring cooling and shielding. Spent nuclear fuel can be processed in nuclear reprocessing plants. One third of the total amount have already been reprocessed. With nuclear reprocessing 96% of the spent fue ...
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Uranium-237
Uranium (U) is a naturally occurring radioactive element (radioelement) with no stable isotopes. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from U to U (except for U). The standard atomic weight of natural uranium is . Natural uranium consists of three main isotopes, U (99.2739–99.2752% natural abundance), U (0.7198–0.7202%), and U (0.0050–0.0059%). All three isotopes are radioactive (i.e., they are radioisotopes), and the most abundant and stable is uranium-238, with a half-life of (about the age of the Earth). Uranium-238 is an alpha emitter, decaying through the 18-member uranium series into lead-206. The decay series of ur ...
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Spent Nuclear Fuel
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and, depending on its point along the nuclear fuel cycle, it will have different isotopic constituents than when it started. Nuclear fuel rods become progressively more radioactive (and less thermally useful) due to neutron activation as they are fissioned, or "burnt", in the reactor. A fresh rod of low enriched uranium pellets (which can be safely handled with gloved hands) will become a highly lethal gamma emitter after 1–2 years of core irradiation, unsafe to approach unless under many feet of water shielding. This makes their invariable accumulation and safe temporary storage in spent fuel pools a prime source of high level radioactive waste and a major ongoing issue for future permanent disposal. Nature of spent fuel Nanomaterial pro ...
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Plutonium-242
Plutonium-242 (Pu or Pu-242) is the second longest-lived isotope of plutonium, with a half-life of 375,000 years. The half-life of Pu is about 15 times that of Pu; so it is one-fifteenth as radioactive, and not one of the larger contributors to nuclear waste radioactivity. Pu's gamma ray emissions are also weaker than those of the other isotopes. It is not fissile (but it is fissionable by fast neutrons), and its neutron capture cross section is low. In the nuclear fuel cycle Plutonium-242 is produced by successive neutron capture on Pu, Pu, and Pu. The odd-mass isotopes Pu and Pu have about a 3/4 chance of undergoing fission on capture of a thermal neutron and about a 1/4 chance of retaining the neutron and becoming the following isotope. The proportion of Pu is low at low burnup but increases nonlinearly. Pu has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to become another fissile isotope (either curium-245 or pl ...
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Fissionable
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal chain reaction can only be achieved with fissile material. The predominant neutron energy in a system may be typified by either slow neutrons (i.e., a thermal system) or fast neutrons. Fissile material can be used to fuel thermal-neutron reactors, fast-neutron reactors and nuclear explosives. Fissile vs fissionable The term ''fissile'' is distinct from ''fissionable''. A nuclide that can undergo nuclear fission (even with a low probability) after capturing a neutron of high or low energy is referred to as ''fissionable''. A fissionable nuclide that can undergo fission with a high probability after capturing a low-energy thermal neutron is referred to as ''fissile''. Fissionable materials include those (such as uranium-238) for which fission can be induced only by high-energy neutrons. As a result, fissile materials (s ...
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Fissile
In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissile material. The predominant Neutron temperature, neutron energy in a system may be typified by either slow neutrons (i.e., a thermal system) or fast neutrons. Fissile material can be used to fuel thermal-neutron reactors, fast-neutron reactors and nuclear explosives. Fissile vs fissionable The term ''fissile'' is distinct from ''fissionable''. A nuclide that can undergo nuclear fission (even with a low probability) after capturing a neutron of high or low energy is referred to as ''fissionable''. A fissionable nuclide that can undergo fission with a high probability after capturing a low-energy thermal neutron is referred to as ''fissile''. Fissionable materials include those (such as uranium-238) for which fission can be induce ...
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Uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactive decay, radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes of uranium, isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordial nuclide, primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few Parts-per notation#Parts-per expressions, parts per million in soil, ...
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Neptunium
Neptunium is a chemical element; it has chemical symbol, symbol Np and atomic number 93. A radioactivity, radioactive actinide metal, neptunium is the first transuranic element. It is named after Neptune, the planet beyond Uranus in the Solar System, which uranium is named after. A neptunium atom has 93 protons and 93 electrons, of which seven are valence electrons. Neptunium metal is silvery and tarnishes when exposed to air. The element occurs in three allotrope, allotropic forms and it normally exhibits five oxidation states, ranging from +3 to +7. Like all actinides, it is Radioactive decay, radioactive, radiation poisoning, poisonous, pyrophoricity, pyrophoric, and capable of accumulating in bones, which makes the handling of neptunium dangerous. Although many false claims of its discovery were made over the years, the element was first synthesized by Edwin McMillan and Philip H. Abelson at the Berkeley Radiation Laboratory in 1940. Since then, most neptunium has been and still ...
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Electronegativity
Electronegativity, symbolized as , is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity, the more an atom or a substituent group attracts electrons. Electronegativity serves as a simple way to quantitatively estimate the bond energy, and the sign and magnitude of a bond's chemical polarity, which characterizes a bond along the continuous scale from covalent to ionic bonding. The loosely defined term electropositivity is the opposite of electronegativity: it characterizes an element's tendency to donate valence electrons. On the most basic level, electronegativity is determined by factors like the nuclear charge (the more protons an atom has, the more "pull" it will have on electrons) and the number and lo ...
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