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PLX
PLX, abbreviation of Picatinny Liquid Explosive, is a liquid binary explosive. It is a mixture of 95% nitromethane (NM) along with 5% ethylene diamine (EDA) as a sensitizer. Other amine compounds can be used instead of ethylene diamine, such as triethylene tetramine, diethylenetriamine or ethanolamine, but EDA has been found to be the most effective amine additive. PLX is a fairly powerful high explosive, marginally exceeding the destructive yield of TNT. Properties PLX, when mixed, is a transparent liquid with a yellowish tint. Ethylene diamine is very volatile, requiring the contents to be sealed if any storage is intended. Generally, for safety purposes, the contents are transported separately and mixed on site. PLX is known to have a velocity of detonation (VoD) of anywhere between 6,000 and 7,000 m/s, depending on diameter. Although greatly sensitized by the addition of EDA, PLX still requires a powerful blasting cap or a small booster charge to successfully detonate. U ...
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Ethylene Diamine
Ethylenediamine (abbreviated as en when a ligand) is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a basic amine. It is a widely used building block in chemical synthesis, with approximately 500,000 tonnes produced in 1998.Karsten Eller, Erhard Henkes, Roland Rossbacher, Hartmut Höke "Amines, Aliphatic" in Ullmann's Encyclopedia of Industrial Chemistry, 2005 Wiley-VCH Verlag, Weinheim. Ethylenediamine is the first member of the so-called polyethylene amines. Synthesis Ethylenediamine is produced industrially by treating 1,2-dichloroethane with ammonia under pressure at 180 °C in an aqueous medium:Hans-Jürgen Arpe, Industrielle Organische Chemie, 6. Auflage (2007), Seite 245, Wiley VCH : In this reaction hydrogen chloride is generated, which forms a salt with the amine. The amine is liberated by addition of sodium hydroxide and can then be recovered by . Diethylenetriamine (DETA) and triethylenetetramine (TETA) are ...
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Korean Air Flight 858
Korean Air Flight 858 was a scheduled international passenger flight between Baghdad, Iraq, and Seoul, South Korea. On 29 November 1987, the aircraft flying that route exploded in mid-air upon the detonation of a bomb planted inside an overhead storage bin in the airplane's passenger cabin by two North Korean agents. The agents, acting upon orders from the North Korean government, planted the device before disembarking from the aircraft during the first stop-over, in Abu Dhabi, United Arab Emirates. While the aircraft was flying over the Andaman Sea to its second stop-over, in Bangkok, Thailand, the bomb detonated and destroyed the Korean Air Boeing 707-3B5C. Everyone aboard the airliner was killed, a total of 104 passengers and 11 crew members (almost all were South Koreans). The attack occurred 34 years after the Korean Armistice Agreement that ended the hostilities of the Korean War on 27 July 1953. The two bombers were traced to Bahrain, where they both took ampules of c ...
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Diethylenetriamine
Diethylenetriamine (abbreviated and also known as 2,2’-Iminodi(ethylamine)) is an organic compound with the formula HN(CH2CH2NH2)2. This colourless hygroscopic liquid is soluble in water and polar organic solvents, but not simple hydrocarbons. Diethylenetriamine is structural analogue of diethylene glycol. Its chemical properties resemble those for ethylene diamine, and it has similar uses. It is a weak base and its aqueous solution is alkaline. DETA is a byproduct of the production of ethylenediamine from ethylene dichloride. Reactions and uses Diethylenetriamine is a common curing agent for epoxy resins in epoxy adhesives and other thermosets. It is N-alkylated upon reaction with epoxide groups forming crosslinks. In coordination chemistry, it serves as a tridentate ligand forming complexes such as Co(dien)(NO2)3. Like some related amines, it is used in oil industry for the extraction of acid gas. Like ethylenediamine, DETA can also be used to sensitize nitromethane ...
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Nitromethane
Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in extractions, as a reaction medium, and as a cleaning solvent. As an intermediate in organic synthesis, it is used widely in the manufacture of pesticides, explosives, fibers, and coatings. Nitromethane is used as a fuel additive in various motorsports and hobbies, e.g. Top Fuel drag racing and miniature internal combustion engines in radio control, control line and free flight model aircraft. Preparation Nitromethane is produced industrially by combining propane and nitric acid in the gas phase at 350–450 °C (662–842 °F). This exothermic reaction produces the four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction involves free radicals, includin ...
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Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosi ...
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Nitrate
Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate. Structure The ion is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a formal charge of −1. This charge results from a combination formal charge in which each of the three oxygens carries a − charge, whereas the nitrogen carries a +1 charge, all these adding up to formal charge of the polyatomic nitrate ion. This arrangement is commonly used as an example of resonance. Like the isoelectronic carbonate ion, the nitrate ion can be represented by resonance structures: Dietary nitrate A rich source of inorganic nitrate in the human diets come from leafy green foods, ...
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C-4 (explosive)
C-4 or Composition C-4 is a common variety of the plastic explosive family known as Composition C, which uses RDX as its explosive agent. C-4 is composed of explosives, plastic binder, plasticizer to make it malleable, and usually a marker or odorizing taggant chemical. C-4 has a texture similar to modelling clay and can be molded into any desired shape. C-4 is relatively insensitive and can be detonated only by the shock wave from a detonator or blasting cap. A similar British plastic explosive, also based on RDX but with a plasticizer different from that used in Composition C-4, is known as PE-4 (Plastic Explosive No. 4). Development C-4 is a member of the Composition C family of chemical explosives. Variants have different proportions and plasticisers and include compositions C-2, C-3, and C-4. The original RDX-based material was developed by the British during World War II and redeveloped as Composition C when introduced to the U.S. military. It was replaced by Compo ...
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Die Hard With A Vengeance
''Die Hard with a Vengeance'' is a 1995 American action thriller film directed by John McTiernan (who directed the first installment). It was written by Jonathan Hensleigh, based on the screenplay ''Simon Says'' by Hensleigh and on the characters created by Roderick Thorp for his 1979 novel '' Nothing Lasts Forever''. ''Die Hard with a Vengeance'' is the third film in the ''Die Hard'' film series, after ''Die Hard 2'' (1990). It is followed by ''Live Free or Die Hard'' (2007) and ''A Good Day to Die Hard'' (2013). The film stars Bruce Willis as NYPD Lieutenant John McClane and Samuel L. Jackson as McClane's reluctant partner Zeus Carver, who team up to stop bomb threats across New York City carried out by "Simon" (Jeremy Irons). It was released on May 19, 1995 to mixed reviews and became the highest-grossing film of the year. The film later gained a cult following and has been considered by many critics and fans as the best sequel of the franchise. Plot The Bonwit Teller ...
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Thermobaric
A thermobaric weapon, also called an aerosol bomb, a vacuum bomb or a fuel air explosive (FAE), is a type of explosive that uses oxygen from the surrounding air to generate a high-temperature explosion. The fuel–air explosive is one of the best-known types of thermobaric weapons. Thermobaric weapons are almost 100% fuel and as a result are significantly more energetic than conventional explosives of equal weight. Many types of thermobaric weapons can be fitted to hand-held launchers, and can also be launched from airplanes. The largest Russian bomb contains a charge of approximately 7 tons of a liquid fuel that when detonated creates an explosion of 39.9 tons TNT equivalent. Terminology The term ''thermobaric'' is derived from the Greek words for 'heat' and 'pressure': ''thermobarikos'' (θερμοβαρικός), from ''thermos'' (θερμός) 'hot' + ''baros'' (βάρος) 'weight, pressure' + suffix ''-ikos'' (-ικός) '-ic'. Other terms used for the family of weapon ...
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Detonation Velocity
Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonated explosive. Explosive velocities are always faster than the local speed of sound in the material. If the explosive is confined before detonation, such as in an artillery shell, the force produced is focused on a much smaller area, and the pressure is significantly intensified. This results in an explosive velocity that is higher than if the explosive had been detonated in open air. Unconfined velocities are often approximately 70 to 80 percent of confined velocities. Explosive velocity is increased with smaller particle size (i.e., increased spatial density), increased charge diameter, and increased confinement (i.e., higher pressure). Typical detonation velocities for organic dust mixtures range from 1400–1650m/s. Gas explosions can either deflagrate or detonate based on confinement; detonation velocities are genera ...
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Brisance
In explosives engineering, brisance (; , ) is the shattering capability of a high explosive, determined mainly by its detonation pressure. Practical uses Brisance is of practical importance for determining the effectiveness of an explosion in fragmenting shells, bomb casings, grenades, structures, and the like. The sand crush teand Trauzl lead block test are commonly used to determine the relative brisance in comparison to TNT (which is considered a standard reference for many purposes). The value of brisance depends on the application. At one extreme, if an explosive is to be used for propulsion, e.g. by driving a piston or a bullet, brisance is likely to be undesirable, because the objective will be to ''move'' the load, not to shatter it or the engine or firearm, nor to produce a loud report. Such propulsive charges are designed to burn controllably, such as carburetted fuel/air mixes in vehicle piston engines, or nitrocellulose fibres or grains of controlled textures in ...
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Fuel
A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy (via nuclear fission and nuclear fusion). The heat energy released by reactions of fuels can be converted into mechanical energy via a heat engine. Other times, the heat itself is valued for warmth, cooking, or industrial processes, as well as the illumination that accompanies combustion. Fuels are also used in the cells of organisms in a process known as cellular respiration, where organic molecules are oxidized to release usable energy. Hydrocarbons and related organic molecules are by far the most common source of fuel used by humans, but other substances, including radioactive metals, are also utilized. Fuels are contrasted with other substance ...
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