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Optical Density
Absorbance is defined as "the logarithm of the ratio of incident to transmitted radiant power through a sample (excluding the effects on cell walls)". Alternatively, for samples which scatter light, absorbance may be defined as "the negative logarithm of one minus absorptance, as measured on a uniform sample". The term is used in many technical areas to quantify the results of an experimental measurement. While the term has its origin in quantifying the absorption of light, it is often entangled with quantification of light which is "lost" to a detector system through other mechanisms. What these uses of the term tend to have in common is that they refer to a logarithm of the ratio of a quantity of light incident on a sample or material to that which is detected after the light has interacted with the sample. The term absorption refers to the physical process of absorbing light, while absorbance does not always measure only absorption; it may measure attenuation (of transmitted ...
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Absorption (electromagnetic Radiation)
In physics, absorption of electromagnetic radiation is how matter (typically electrons bound in atoms) takes up a photon's energy—and so transforms electromagnetic energy into internal energy of the absorber (for example, thermal energy). A notable effect of the absorption of electromagnetic radiation is attenuation of the radiation; attenuation is the gradual reduction of the intensity of light waves as they propagate through a medium. Although the absorption of waves does not usually depend on their intensity (linear absorption), in certain conditions (optics) the medium's transparency changes by a factor that varies as a function of wave intensity, and saturable absorption (or nonlinear absorption) occurs. Quantifying absorption Many approaches can potentially quantify radiation absorption, with key examples following. * The absorption coefficient along with some closely related derived quantities * The attenuation coefficient (NB used infrequently with meaning ...
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Transmittance
Electromagnetic radiation can be affected in several ways by the medium in which it propagates.  It can be Scattering, scattered, Absorption (electromagnetic radiation), absorbed, and Fresnel equations, reflected and refracted at discontinuities in the medium.  This page is an overview of the last 3. The transmittance of a material and any surfaces is its effectiveness in transmitting radiant energy; the fraction of the initial (incident) radiation which propagates to a location of interest (often an observation location). This may be described by the transmission coefficient. Surface Transmittance Hemispherical transmittance Hemispherical transmittance of a surface, denoted ''T'', is defined as :T = \frac, where *Φet is the radiant flux ''transmitted'' by that surface into the hemisphere on the opposite side from the incident radiation; *Φei is the radiant flux received by that surface. Hemispheric transmittance may be calculated as an integral over the directional trans ...
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Laser Absorption Spectrometry
Laser absorption spectrometry (LAS) refers to techniques that use lasers to assess the concentration or amount of a species in gas phase by absorption spectrometry (AS). Optical spectroscopic techniques in general, and laser-based techniques in particular, have a great potential for detection and monitoring of constituents in gas phase. They combine a number of important properties, e.g. a high sensitivity and a high selectivity with non-intrusive and remote sensing capabilities. Laser absorption spectrometry has become the foremost used technique for quantitative assessments of atoms and molecules in gas phase. It is also a widely used technique for a variety of other applications, e.g. within the field of optical frequency metrology or in studies of light matter interactions. The most common technique is tunable diode laser absorption spectroscopy (TDLAS) which has become commercialized and is used for a variety of applications. Direct laser absorption spectrometry The most ...
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Molar Concentration
Molar concentration (also called molarity, amount concentration or substance concentration) is the number of moles of solute per liter of solution. Specifically, It is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter, having the unit symbol mol/L or mol/ dm3 (1000 mol/ m3) in SI units. A solution with a concentration of 1 mol/L is said to be 1 molar, commonly designated as 1 M or 1 M. Molarity is often depicted with square brackets around the substance of interest; for example, the molarity of the hydrogen ion is depicted as + Definition Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or ...
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Attenuation Coefficient
The linear attenuation coefficient, attenuation coefficient, or narrow-beam attenuation coefficient characterizes how easily a volume of material can be penetrated by a beam of light, sound, particles, or other energy or matter. A coefficient value that is large represents a beam becoming 'attenuated' as it passes through a given medium, while a small value represents that the medium had little effect on loss. The (derived) SI unit of attenuation coefficient is the reciprocal metre (m−1). Extinction coefficient is another term for this quantity, often used in meteorology and climatology. Most commonly, the quantity measures the exponential decay of intensity, that is, the value of downward ''e''-folding distance of the original intensity as the energy of the intensity passes through a unit (''e.g.'' one meter) thickness of material, so that an attenuation coefficient of 1 m−1 means that after passing through 1 metre, the radiation will be reduced by a factor of '' e'', and fo ...
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Beer–Lambert Law
The Beer–Bouguer–Lambert (BBL) extinction law is an empirical relationship describing the attenuation in intensity of a radiation beam passing through a macroscopically homogenous medium with which it interacts. Formally, it states that the intensity of radiation decays exponentially in the absorbance of the medium, and that said absorbance is proportional to the length of beam passing through the medium, the concentration of interacting matter along that path, and a constant representing said matter's propensity to interact. The extinction law's primary application is in chemical analysis, where it underlies the Beer–Lambert law, commonly called Beer's law. Beer's law states that a beam of visible light passing through a chemical solution of fixed geometry experiences absorption proportional to the solute concentration. Other applications appear in physical optics, where it quantifies astronomical extinction and the absorption of photons, neutrons, or rarefied gas ...
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Emissivity
The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is not visible to human eyes. A portion of the thermal radiation from very hot objects (see photograph) is easily visible to the eye. The emissivity of a surface depends on its chemical composition and geometrical structure. Quantitatively, it is the ratio of the thermal radiation from a surface to the radiation from an black body, ideal black surface at the same temperature as given by the Stefan–Boltzmann law. (A comparison with Planck's law is used if one is concerned with particular wavelengths of thermal radiation.) The ratio varies from 0 to 1. The surface of a perfect black body (with an emissivity of 1) emits thermal radiation at the rate of approximately 448 watts per square metre (W/m) at a room temperature of . Objects have emi ...
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Radiant Exitance
In radiometry, radiant exitance or radiant emittance is the radiant flux emitted by a surface per unit area, whereas spectral exitance or spectral emittance is the radiant exitance of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. This is the emitted component of radiosity. The SI unit of radiant exitance is the watt per square metre (), while that of spectral exitance in frequency is the watt per square metre per hertz (W·m−2·Hz−1) and that of spectral exitance in wavelength is the watt per square metre per metre (W·m−3)—commonly the watt per square metre per nanometre (). The CGS unit erg per square centimeter per second () is often used in astronomy. Radiant exitance is often called "intensity" in branches of physics other than radiometry, but in radiometry this usage leads to confusion with radiant intensity. Mathematical definitions Radiant exitance Radiant exitance of a ''surface' ...
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Transmittance
Electromagnetic radiation can be affected in several ways by the medium in which it propagates.  It can be Scattering, scattered, Absorption (electromagnetic radiation), absorbed, and Fresnel equations, reflected and refracted at discontinuities in the medium.  This page is an overview of the last 3. The transmittance of a material and any surfaces is its effectiveness in transmitting radiant energy; the fraction of the initial (incident) radiation which propagates to a location of interest (often an observation location). This may be described by the transmission coefficient. Surface Transmittance Hemispherical transmittance Hemispherical transmittance of a surface, denoted ''T'', is defined as :T = \frac, where *Φet is the radiant flux ''transmitted'' by that surface into the hemisphere on the opposite side from the incident radiation; *Φei is the radiant flux received by that surface. Hemispheric transmittance may be calculated as an integral over the directional trans ...
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Radiant Flux
In radiometry, radiant flux or radiant power is the radiant energy emitted, reflected, transmitted, or received per unit time, and spectral flux or spectral power is the radiant flux per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The SI unit of radiant flux is the watt (W), one joule per second (), while that of spectral flux in frequency is the watt per hertz () and that of spectral flux in wavelength is the watt per metre ()—commonly the watt per nanometre (). Mathematical definitions Radiant flux Radiant flux, denoted ('e' for "energetic", to avoid confusion with photometric quantities), is defined as \begin \Phi_\mathrm &= \frac \\ ptQ_\mathrm &= \int_ \int_ \mathbf\cdot \hat\mathbf\, dA dt \end where * is the time; * is the radiant energy passing out of a closed surface ; * is the Poynting vector, representing the current density of radiant energy; * is the normal vector of a point on ; * ...
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Optical Depth
In physics, optical depth or optical thickness is the natural logarithm of the ratio of incident to ''transmitted'' radiant power through a material. Thus, the larger the optical depth, the smaller the amount of transmitted radiant power through the material. Spectral optical depth or spectral optical thickness is the natural logarithm of the ratio of incident to transmitted spectral radiant power through a material. Optical depth is dimensionless, and in particular is not a length, though it is a monotonically increasing function of optical path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged. In chemistry, a closely related quantity called " absorbance" or "decadic absorbance" is used instead of optical depth: the common logarithm of the ratio of incident to transmitted radiant power through a material. It is the optical depth divided by , because of the different logarithm bases used ...
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