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Octaazacubane
Octaazacubane is a hypothetical explosive allotrope of nitrogen with formula N8, whose molecules have eight atoms arranged into a cube. (By comparison, nitrogen usually occurs as the diatomic molecule N2.) It can be regarded as a cubane-type cluster, where all eight corners are nitrogen atoms bonded along the edges. It is predicted to be a metastable molecule, in which despite the thermodynamic instability caused by bond strain, and the high energy of the N–N single bonds, the molecule remains kinetically stable for reasons of orbital symmetry. Explosive and fuel Octaazacubane is predicted to have an energy density (assuming decomposition into N2) of 22.9 MJ/ kg, which is over 5 times the standard value of TNT. It has therefore been proposed (along with other exotic nitrogen allotropes) as an explosive, and as a component of high performance rocket fuel. Its velocity of detonation is predicted to be 15,000 m/s, much (48.5%) more than octanitrocubane, the fastes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive Material
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are sai ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubane-type Cluster
A cubane-type cluster is an arrangement of atoms in a molecular structure that forms a cube. In the simplest case, the eight vertices are symmetry equivalent and the species has Oh symmetry group, symmetry. Such structure occurs in the hydrocarbon cubane (chemical formula ), which has carbon atoms at the corners of a cube and covalent bonds forming the edges. : Other compounds in the class have different elements in the corners, and various atoms or groups bonded to the corners. Most cubanes have more complicated structures, usually with nonequivalent vertices. They may be simple covalent compounds or macromolecular or supramolecular cluster compounds. Examples Heavier adamantogen cubanes with all vertices identical are all known, and exhibit only about half as much strain energy as cubane per molecule. The inert pair effect is believed to drive stability in cubanes with heavy main group elements: the bonding orbitals are almost entirely orbital hybridization, unhybridized ''p' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octanitrocubane
Octanitrocubane (molecular formula: C8(NO2)8) is a proposed high explosive that, like TNT, is shock-insensitive (not readily detonated by shock). The octanitrocubane molecule has the same chemical structure as cubane (C8H8) except that each of the eight hydrogen atoms is replaced by a nitro group (NO2). As of 1998, octanitrocubane had not been produced in quantities large enough to test its performance as an explosive. It is, however, not as powerful an explosive as once thought, as the high-density theoretical crystal structure has not been achieved. For this reason, heptanitrocubane, the slightly less nitrated form, is believed to have marginally better performance, despite having a worse oxygen balance. Octanitrocubane is thought to have 20–25% greater performance than HMX (octogen). This increase in power is due to its highly expansive breakdown into CO2 and N2, as well as to the presence of strained chemical bonds in the molecule which have stored potential energy. In a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
TNT Equivalent
TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. A ton of TNT equivalent is a unit of energy defined by convention to be (). It is the approximate energy released in the detonation of a metric ton (1,000 kilograms) of trinitrotoluene (TNT). In other words, for each gram of TNT exploded, (or 4184 joules) of energy are released. This convention intends to compare the destructiveness of an event with that of conventional explosive materials, of which TNT is a typical example, although other conventional explosives such as dynamite contain more energy. A related concept is the physical quantity TNT-equivalent mass (or mass of TNT equivalent), expressed in the ordinary units of mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a body, until the discovery of the atom and particle physics. It was found that different atoms and diff ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetranitrogen
Tetranitrogen is a neutrally charged polynitrogen allotrope of the chemical formula and consists of four nitrogen atoms. The tetranitrogen cation is the positively charged ion, , which is more stable than the neutral tetranitrogen molecule and is thus more studied. Tetranitrogen anions ( and ) have also been reported. Laniel, D., Winkler, B., Koemets, E. et al. Synthesis of magnesium-nitrogen salts of polynitrogen anions. Nat Commun 10, 4515 (2019). https://doi.org/10.1038/s41467-019-12530-w History Polynitrogen compounds have been well known and characterized by chemists for many years. The commonplace molecular (diatomic) nitrogen () was first isolated by Daniel Rutherford in 1772 and the azide ion () was discovered by Theodor Curtius in 1890. Discoveries of other related nitrogenous allotypes during the twentieth century include the aromatic molecule pentazole and the radical molecule . However, none of these complexes could be isolated or synthesized on a macroscopic scale ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Allotrope
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: the atoms of the element are bonded together in different manners. For example, the allotropes of carbon include diamond (the carbon atoms are bonded together to form a cubic lattice of tetrahedra), graphite (the carbon atoms are bonded together in sheets of a hexagonal lattice), graphene (single sheets of graphite), and fullerenes (the carbon atoms are bonded together in spherical, tubular, or ellipsoidal formations). The term ''allotropy'' is used for elements only, not for compounds. The more general term, used for any compound, is polymorphism, although its use is usually restricted to solid materials such as crystals. Allotropy refers only to different forms of an element within the same physical phase (the state of matter, such as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive Chemicals
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or Dust explosion, grain dust * pressure, pressurized gas compressor, gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear weapon, nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexazine
Hexazine (also known as hexaazabenzene) is a hypothetical allotrope of nitrogen composed of 6 nitrogen atoms arranged in a ring-like structure analogous to that of benzene. As a neutrally charged species, it would be the final member of the azabenzene (azine) series, in which all of the methine groups of the benzene molecule have been replaced with nitrogen atoms. The two last members of this series, hexazine and pentazine, have not been observed, although all other members of the azine series have (such as pyridine, pyrimidine, pyridazine, pyrazine, triazines, and tetrazines). While a neutrally charged hexazine species has not yet been synthesized, two negatively charged variants, 6sup>2- and 6sup>4-, have been produced in potassium-nitrogen compounds under very high pressures (> 40 GPa) and temperatures (> 2000 K). In particular, 6sup>4- is aromatic, respecting Hückel's rule, while 6sup>2- is anti-aromatic. Stability The hexazine molecule bears a structural similarity t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pentazole
Pentazole is an aromatic molecule consisting of a five-membered ring with all nitrogen atoms, one of which is bonded to a hydrogen atom. It has the molecular formula . Although strictly speaking a homocyclic, inorganic compound, pentazole has historically been classed as the last in a series of heterocyclic azole compounds containing one to five nitrogen atoms. This set contains pyrrole, imidazole, pyrazole, triazoles, tetrazole, and pentazole. Derivatives Substituted analogs of pentazole are collectively known as pentazoles. As a class, they are unstable and often highly explosive compounds. The first pentazole synthesized was phenylpentazole, where the pentazole ring is highly stabilized by conjugation with the phenyl ring. The derivative 4-dimethylaminophenylpentazole is among the most stable pentazole compounds known, although it still decomposes at temperatures over 50 °C. It is known that electron-donating groups stabilize aryl pentazole compounds. Ions ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
1,1′-Azobis-1,2,3-triazole
1,1'-Azobis-1,2,3-triazole is a moderately explosive but comparatively stable chemical compound which contains a long continuous chain of nitrogen atoms, with an unbroken chain of eight nitrogen atoms cyclised into two 1,2,3-triazole rings. It is stable up to 194 °C. The compound exhibits ''cis''–''trans'' isomerism at the central azo group: the ''trans'' isomer is more stable and is yellow, while the ''cis'' isomer is less stable and is blue. The two rings are aromatic and form a conjugated system with the azo linkage. This chromophore allows the ''trans'' compound to be isomerised to the ''cis'' when treated with an appropriate wavelength of ultraviolet light. Related compounds In 2011, 1,1'-azobis(1,2,3,4-tetrazole) with formula was prepared by Klapötke and Piercey which has a 10-nitrogen chain. The record was later taken by a 11-nitrogen chain compound synthesized by a group of Chinese researchers. A branched chain of 11-nitrogen system has also been reported as p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Chemistry Chemical Physics
''Physical Chemistry Chemical Physics'' is a weekly peer-reviewed scientific journal publishing research and review articles on any aspect of physical chemistry, chemical physics, and biophysical chemistry. It is published by the Royal Society of Chemistry on behalf of eighteen participating societies. The editor-in-chief is Anouk Rijs, (Vrije Universiteit Amsterdam). Retrieved on 2023-05-29. The journal was established in 1999 as the results of a merger between '' Faraday Transactions'' and a number of other physical chemistry journals published by different societies. Owner societies The journal is run by an Ownership Board, on which all the member societ ...[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
