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Nickel Sulfide
Nickel sulfide is any inorganic compound with the formula NiSx. They range in color from bronze (Ni3S2) to black (NiS2). The nickel sulfide with simplest stoichiometry is NiS, also known as the mineral millerite. From the economic perspective, Ni9S8, the mineral pentlandite, is the chief source of mined nickel. Other minerals include heazlewoodite (Ni3S2) and polydymite (Ni3S4). The mineral Vaesite is NiS2. Some nickel sulfides are used commercially as catalysts. Structure Like many related materials, nickel sulfide adopts the nickel arsenide motif. In this structure, nickel is octahedral and the sulfide centers are in trigonal prismatic sites. NiS has two polymorphs. The α-phase has a hexagonal unit cell, while the β-phase has a rhombohedral cell. The α-phase is stable at temperatures above , and converts into the β-phase at lower temperatures. That phase transition causes an increase in volume by 2-4%. Synthesis and reactions The precipitation of solid black nickel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitric Acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as pigments in inks and dyes. Nitric acid is also commonly used as a strong oxidizing agen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymorphism (materials Science)
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for chemical elements. Polymorphism is of practical relevance to pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, and explosives. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure." According to McCrone, polymorphs are "different in crystal structure but identical in the liquid or vapor states." Materials with two polymorphs are called dimorphic, with three polymorphs, trimorphic, etc. Examples Many compounds exhibit polymorphism. It has been claimed that "every compound has different polymorphic forms, and that, in general, the n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nickel Compounds
Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems. Nickel forms simple binary compounds with non metals including halogens, chalcogenides, and pnictides. Nickel ions can act as a cation in salts with many acids, including common oxoacids. Salts of the hexaaqua ion (Ni2+) are especially well known. Many double salts containing nickel with another cation are known. There are organic acid salts. N ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tension (physics)
In physics, tension is described as the pulling force transmitted axially by the means of a string, a rope, chain, or similar object, or by each end of a rod, truss member, or similar three-dimensional object; tension might also be described as the action-reaction pair of forces acting at each end of said elements. Tension could be the opposite of compression (physics), compression. At the atomic level, when atoms or molecules are pulled apart from each other and gain potential energy with a restoring force still existing, the restoring force might create what is also called tension. Each end of a string or rod under such tension could pull on the object it is attached to, in order to restore the string/rod to its relaxed length. Tension (as a transmitted force, as an action-reaction pair of forces, or as a restoring force) is measured in newton (unit), newtons in the International System of Units (or pounds-force in Imperial units). The ends of a string or other object transmitt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tempered Glass
Tempered or toughened glass is a type of safety glass processed by controlled thermal or chemical treatments to increase its strength compared with normal glass. Tempering puts the outer surfaces into compression and the interior into tension. Such stresses cause the glass, when broken, to shatter into small granular chunks instead of splintering into jagged shards as ordinary annealed glass does. The granular chunks are less likely to cause injury. Tempered glass is used for its safety and strength in a variety of applications, including passenger vehicle windows, shower doors, aquariums, architectural glass doors and tables, refrigerator trays, mobile phone screen protectors, bulletproof glass components, diving masks, and plates and cookware. Properties Tempered glass is about four times stronger than annealed glass. The greater contraction of the inner layer during manufacturing induces compressive stresses in the surface of the glass balanced by tensile stresses in the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Float Glass
Float glass is a sheet of glass made by floating molten glass on a bed of molten metal, typically tin, although lead and other various low- melting-point alloys were used in the past. This method gives the sheet uniform thickness and very flat surfaces. Modern windows are made from float glass. Most float glass is soda-lime glass, although relatively minor quantities of specialty borosilicate and flat panel display glass are also produced using the float glass process. The float glass process is also known as the Pilkington process, named after the British glass manufacturer Pilkington, which pioneered the technique in the 1950s at their production site in St Helens, Merseyside. History Until the 16th century, window glass or other flat glass was generally cut from large discs (or rondels) of crown glass. Larger sheets of glass were made by blowing large cylinders which were cut open and flattened, then cut into panes. Most window glass in the early 19th century was made usin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid State Metathesis
Self-propagating high-temperature synthesis (SHS) is a method for producing both inorganic and organic compounds by exothermic combustion reactions in solids of different nature. Reactions can occur between a solid reactant coupled with either a gas, liquid, or other solid. If the reactants, intermediates, and products are all solids, it is known as a solid flame. If the reaction occurs between a solid reactant and a gas phase reactant, it is called infiltration combustion. Since the process occurs at high temperatures, the method is ideally suited for the production of refractory materials including powders, metallic alloys, or ceramics. The modern SHS process was reported and patented in 1971,"''Self-propagated high-temperature synthesis of refractory inorganic compounds''", A.G. Merzhanov, I.P. Borovinskaya. Doklady Akademii Nauk SSSR, Vol. 204, N 2, pp. 366-369, May, 1972 although some SHS-like processes were known previously. Advantages and Disadvantages Self-propagating high- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Qualitative Inorganic Analysis
Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution, therefore materials in other forms may need to be brought to this state before using standard methods. The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes. Qualitative inorganic analysis is that branch or method of analytical chemistry which seeks to establish the elemental composition of inorganic compounds through various reagents. Physical appearance of inorganic salts Detecting cations According to their properties, cations are usually classified into six groups. Each group has a common reagent which can be used to separate them from the solution. To obtain meaningful results, the separation must be done in the sequence specified below, as some ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Transition
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trigonal Prismatic Molecular Geometry
In chemistry, the trigonal prismatic molecular geometry describes the shape of compounds where six atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triangular prism. Examples Hexamethyltungsten (W(CH3)6) was the first example of a molecular trigonal prismatic complex. The figure shows the six carbon atoms arranged at the vertices of a triangular prism with the tungsten at the centre. The hydrogen atoms are not shown. Some other transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...s have trigonal prismatic hexamethyl complexes, including both neutral molecules such as Mo(CH3)6 and Re(CH3)6 and ions such as and . The complex Mo(S−CH=CH−S)3 is also trigonal prismatic, with each S−CH=CH−S group acting as a bident ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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