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Mercerised Cotton
Mercerisation is a textile finishing treatment for cellulose fabric and yarn, mainly cotton and flax, which improves dye uptake and tear strength, reduces fabric shrinkage, and imparts a silk-like luster. Development The process was devised in 1844 by John Mercer, who treated cotton with solutions of20–30% sodium hydroxide followed by washing. Mercer observed that the treatment shrank the fabric and increased its tensile strength and affinity for dyes. In the original process of Mercer, no tension was applied. The product was termed ''fulled cotton'', a nod to the process of fulling in woven wool fabric. Mercer regarded the increased affinity for dyes as the most important technical aspect. Mercer also experimented with sulfuric acid and zinc chloride solutions and discovered the parchmentising effect of sulfuric acid. The silk-like lustre now commonly associated with mercerising is produced by tension and was discovered by Horace Lowe in 1889. Process Treatment with ...
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Fulling
Fulling, also known as felting, tucking or walking ( Scots: ''waukin'', hence often spelled waulking in Scottish English), is a step in woollen clothmaking which involves the cleansing of woven or knitted cloth (particularly wool) to eliminate (lanoline) oils, dirt, and other impurities, and to make it shrink by friction and pressure. The work delivers a smooth, tightly finished fabric that is isolating and water repellent. Well known example are duffel cloth, first produced in Flanders in the 14th century and loden, produced in Austria from the 16th century on. The practice to do this by hand or feet died out with the introduction of machines during the industrial revolution. Process Fulling involves two processes: scouring and milling (thickening). Originally, fulling was carried out by the pounding of the woollen cloth with a club, or the fuller's feet or hands. In Scottish Gaelic tradition, this process was accompanied by waulking songs, which women sang to set th ...
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Cotton
Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor percentages of waxes, fats, pectins, and water. Under natural conditions, the cotton bolls will increase the dispersal of the seeds. The plant is a shrub native to tropical and subtropical regions around the world, including the Americas, Africa, Egypt and India. The greatest diversity of wild cotton species is found in Mexico, followed by Australia and Africa. Cotton was independently domesticated in the Old and New Worlds. The fiber is most often spun into yarn or thread and used to make a soft, breathable, and durable textile. The use of cotton for fabric is known to date to prehistoric times; fragments of cotton fabric dated to the fifth millennium BC have been found in the Indus Valley civilization, as well as fabric remnants dat ...
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Fibers
Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene. Synthetic fibers can often be produced very cheaply and in large amounts compared to natural fibers, but for clothing natural fibers can give some benefits, such as comfort, over their synthetic counterparts. Natural fibers Natural fibers develop or occur in the fiber shape, and include those produced by plants, animals, and geological processes. They can be classified according to their origin: * Vegetable fibers are generally based on arrangements of cellulose, often with lignin: examples include cotton, hemp, jute, flax, abaca, piña, ramie, sisal, bagasse, and banana. Plant fibers are employed in the manufacture of paper and textile (cloth), an ...
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Stenter
A stenter (sometimes called a tenter) is a specialist oven used in the textile industry for drying and heat treating fabric after wet processing. It consists of heated chambers, adjustable to the width of the fabric being treated. Fabric is fed into the heated chamber supported at either selvedge by a series of stenter pins or clamps which support the fabric as it is moved through the drying chambers. (Note: Stenter pins are the modern equivalent of tenterhooks) The input and output speed of the fabric is closely controlled, as is the output width, determining the moisture content of the fabric after drying, and the dimensional stability. Etymology and History ''Stenter'' is derived from ''tenter'', which comes from the Latin ''tendere'', to stretch, via a French intermediate. The main purpose of the machine is to stretch and dry. The frames were called tenters and the tentering hooks were the metal hooks used for holding the fabric to the frame. Tenters were used to process ...
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Ullmann's Encyclopedia Of Industrial Chemistry
''Ullmann's Encyclopedia of Industrial Chemistry'' is a major reference work related to industrial chemistry by Chemist Fritz Ullmann, first published in 1914, and exclusively in German as "Enzyklopädie der Technischen Chemie" until 1984. History Ullmann's Encyclopedia of Industrial Chemistry is a major reference work related to industrial chemistry by chemist Fritz Ullmann. Its 1st edition was published in German by Fritz Ullmann in 1914. The 4th edition, published 1972 to 1984, already contained 25 volumes. The 5th edition, published 1985 to 1996, was the first version available in English. In 1997, the first online version was published. 2014 marked its centenary. As of 2016, Ullmann's Encyclopedia was in its 7th edition, in 40 volumes including one index volume and more than 1,050 articles (200 more than the 6th edition), approx. 30,000 pages, 22,000 images, 8,000 tables, 19,000 references and 85,000 indices. Editions * 1914–1922: 1st edition in 12 volumes, which can ...
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Wetting Agent
Surfactants are chemical compounds that decrease the surface tension between two liquids, between a gas and a liquid, or interfacial tension between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming agents, or dispersants. The word "surfactant" is a blend of ''surface-active agent'', coined . Agents that increase surface tension are "surface active" in the literal sense but are not called surfactants as their effect is opposite to the common meaning. A common example of surface tension increase is salting out: by adding an inorganic salt to an aqueous solution of a weakly polar substance, the substance will precipitate. The substance may itself be a surfactant – this is one of the reasons why many surfactants are ineffective in sea water. Composition and structure Surfactants are usually organic compounds that are amphiphilic, meaning each molecule contains both a hydrophilic "water-seeking" group (the ''head''), and a hydr ...
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Cellulose Hydrate
Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms. Cellulose is the most abundant organic polymer on Earth. The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%. Cellulose is mainly used to produce paperboard and paper. Smaller quantities are converted into a wide variety of derivative products such as cellophane and rayon. Conversion of cellulose from energy crops into biofuels such as cellulosic ethanol is under development as a renewable fuel source. Cellulose for industrial use is mainly obtained from wood pulp and cotton. Some animals, particularly ruminants and termites, can digest cellulose with the ...
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Alkali Cellulose
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases. Etymology The word "alkali" is derived from Arabic ''al qalīy'' (or ''alkali''), meaning ''the calcined ashes'' (see calcination), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called potash and composed mostly of potassium carbonate, was mildly basic. After heating this substance with calcium hydroxide (''slaked li ...
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Horace Arthur Lowe
Quintus Horatius Flaccus (; 8 December 65 – 27 November 8 BC), known in the English-speaking world as Horace (), was the leading Roman lyric poet during the time of Augustus (also known as Octavian). The rhetorician Quintilian regarded his ''Odes'' as just about the only Latin lyrics worth reading: "He can be lofty sometimes, yet he is also full of charm and grace, versatile in his figures, and felicitously daring in his choice of words."Quintilian 10.1.96. The only other lyrical poet Quintilian thought comparable with Horace was the now obscure poet/metrical theorist, Caesius Bassus (R. Tarrant, ''Ancient Receptions of Horace'', 280) Horace also crafted elegant hexameter verses (''Satires'' and '' Epistles'') and caustic iambic poetry ('' Epodes''). The hexameters are amusing yet serious works, friendly in tone, leading the ancient satirist Persius to comment: "as his friend laughs, Horace slyly puts his finger on his every fault; once let in, he plays about the heartstri ...
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Parchmentised Cotton
Parchmentising or parchmentizing is a kind of aesthetic finish for textiles. It is a finishing treatment for cellulose fabric that stiffens the fabric and imparts a degree of translucency. Parchment Parchment was a material for writing created in ancient times. It was created with animal skin. It means "stuff from Pregamos" in both the Latin and Greek language. Eumenes II developed parchment when papyrus was banned for export to Pregamos by Ptolemy V Epiphanes. The skin of sheep, goats, or cattle was used to create parchment. The parchmentising process involves the application of sulfuric acid to cellulosic textiles in order to achieve the characteristics of parchment. Organdy Parchmentising offers a stiffened and somewhat translucent finish. Organdy is one of the sheerest cloths produced by the process. Development Parchmentising was described in 1850 by John Mercer, who treated cotton with solutions of 110–125 °Tw sulfuric acid, at room temperature, followed by was ...
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Zinc Chloride
Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This salt is hygroscopic and even deliquescent. Zinc chloride finds wide application in textile processing, metallurgical fluxes, and chemical synthesis. No mineral with this chemical composition is known aside from the very rare mineral simonkolleite, Zn5(OH)8Cl2·H2O. Structure and properties Four crystalline forms ( polymorphs) of ZnCl2 are known: α, β, γ, and δ. Each case features tetrahedral Zn2+ centers. Here ''a'', ''b'', and ''c'' are lattice constants, ''Z'' is the number of structure units per unit cell, and ρ is the density calculated from the structure parameters. The orthorhombic form (δ) rapidly changes to one of the other forms on exposure to the atmosphere. A possible explanation is that the OH− ions originating from the absorbed water f ...
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