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Morse Potential
The Morse potential, named after physicist Philip M. Morse, is a convenient Interatomic potential, interatomic interaction model for the potential energy of a diatomic molecule. It is a better approximation for the oscillation, vibrational structure of the molecule than the quantum harmonic oscillator because it explicitly includes the effects of bond breaking, such as the existence of unbound states. It also accounts for the anharmonicity of real bonds and the non-zero transition probability for overtone band, overtone and Hot band#Combination bands, combination bands. The Morse potential can also be used to model other interactions such as the interaction between an atom and a surface. Due to its simplicity (only three fitting parameters), it is not used in modern spectroscopy. However, its mathematical form inspired the MLR (Morse/Long-range potential, Morse/Long-range) potential, which is the most popular potential energy function used for fitting spectroscopic data. Potential ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Philip M
Philip, also Phillip, is a male name derived from the Macedonian Old Koine language, Greek (''Philippos'', lit. "horse-loving" or "fond of horses"), from a compound of (''philos'', "dear", "loved", "loving") and (''hippos'', "horse"). Prominent Philips who popularized the name include List of kings of Macedonia, kings of Macedonia and one of the apostles of early Christianity. ''Philip'' has #Philip in other languages, many alternative spellings. One derivation often used as a surname is Phillips (surname), Phillips. The original Greek spelling includes two Ps as seen in Philippides (other), Philippides and Philippos, which is possible due to the Greek endings following the two Ps. To end a word with such a double consonant—in Greek or in English—would, however, be incorrect. It has many diminutive (or even hypocorism, hypocoristic) forms including Phil, Philly (other)#People, Philly, Phillie, Lip (other), Lip, and Pip (other), Pip. There ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Factorization Method
In mathematics, factorization (or factorisation, see English spelling differences) or factoring consists of writing a number or another mathematical object as a product of several '' factors'', usually smaller or simpler objects of the same kind. For example, is an ''integer factorization'' of , and is a ''polynomial factorization'' of . Factorization is not usually considered meaningful within number systems possessing division, such as the real or complex numbers, since any x can be trivially written as (xy)\times(1/y) whenever y is not zero. However, a meaningful factorization for a rational number or a rational function can be obtained by writing it in lowest terms and separately factoring its numerator and denominator. Factorization was first considered by ancient Greek mathematicians in the case of integers. They proved the fundamental theorem of arithmetic, which asserts that every positive integer may be factored into a product of prime numbers, which cannot be fur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Mechanics
Molecular mechanics uses classical mechanics to model molecular systems. The Born–Oppenheimer approximation is assumed valid and the potential energy of all systems is calculated as a function of the nuclear coordinates using Force field (chemistry), force fields. Molecular mechanics can be used to study molecule systems ranging in size and complexity from small to large biological systems or material assemblies with many thousands to millions of atoms. All-atomistic molecular mechanics methods have the following properties: * Each atom is simulated as one particle * Each particle is assigned a radius (typically the van der Waals radius), polarizability, and a constant net charge (generally derived from quantum calculations and/or experiment) * Bonded interactions are treated as ''springs'' with an equilibrium distance equal to the experimental or calculated bond length Variants on this theme are possible. For example, many simulations have historically used a ''united-atom'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
N2ground
N, or n, is the fourteenth letter of the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages, and others worldwide. Its name in English is ''en'' (pronounced ), plural ''ens''. History One of the most common hieroglyphs, snake, was used in Egyptian writing to stand for a sound like the English , because the Egyptian word for "snake" was ''djet''. It is speculated by some, such as archeologist Douglas Petrovich, that Semitic speakers working in Egypt adapted hieroglyphs to create the first alphabet. Some hold that they used the same snake symbol to represent N, with a great proponent of this theory being Alan Gardiner, because their word for "snake" may have begun with n (an example of a possible word being ''nahash''). However, this theory has become disputed. The name for the letter in the Phoenician, Hebrew, Aramaic, and Arabic alphabets is ''nun'', which means "fish" in some of these languages. This possibly conn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Angular Frequency
In physics, angular frequency (symbol ''ω''), also called angular speed and angular rate, is a scalar measure of the angle rate (the angle per unit time) or the temporal rate of change of the phase argument of a sinusoidal waveform or sine function (for example, in oscillations and waves). Angular frequency (or angular speed) is the magnitude of the pseudovector quantity '' angular velocity''. (UP1) Angular frequency can be obtained multiplying '' rotational frequency'', ''ν'' (or ordinary ''frequency'', ''f'') by a full turn (2 radians): . It can also be formulated as , the instantaneous rate of change of the angular displacement, ''θ'', with respect to time, ''t''. (11 pages) Unit In SI[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wavenumber
In the physical sciences, the wavenumber (or wave number), also known as repetency, is the spatial frequency of a wave. Ordinary wavenumber is defined as the number of wave cycles divided by length; it is a physical quantity with dimension of reciprocal length, expressed in SI units of cycles per metre or reciprocal metre (m−1). Angular wavenumber, defined as the wave phase divided by time, is a quantity with dimension of angle per length and SI units of radians per metre. They are analogous to temporal frequency, respectively the '' ordinary frequency'', defined as the number of wave cycles divided by time (in cycles per second or reciprocal seconds), and the ''angular frequency'', defined as the phase angle divided by time (in radians per second). In multidimensional systems, the wavenumber is the magnitude of the '' wave vector''. The space of wave vectors is called ''reciprocal space''. Wave numbers and wave vectors play an essential role in optics and the physics ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Second
The second (symbol: s) is a unit of time derived from the division of the day first into 24 hours, then to 60 minutes, and finally to 60 seconds each (24 × 60 × 60 = 86400). The current and formal definition in the International System of Units (SI) is more precise: The second ..is defined by taking the fixed numerical value of the caesium frequency, Δ''ν''Cs, the unperturbed ground-state hyperfine transition frequency of the caesium 133 atom, to be when expressed in the unit Hz, which is equal to s−1. This current definition was adopted in 1967 when it became feasible to define the second based on fundamental properties of nature with caesium clocks. As the speed of Earth's rotation varies and is slowing ever so slightly, a leap second is added at irregular intervals to civil time to keep clocks in sync with Earth's rotation. The definition that is based on of a rotation of the earth is still used by the Universal Time 1 (UT1) system. Etymology "Minute" ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Joule (unit)
The joule ( , or ; symbol: J) is the unit of energy in the International System of Units (SI). In terms of SI base units, one joule corresponds to one kilogram- metre squared per second squared One joule is equal to the amount of work done when a force of one newton displaces a body through a distance of one metre in the direction of that force. It is also the energy dissipated as heat when an electric current of one ampere passes through a resistance of one ohm for one second. It is named after the English physicist James Prescott Joule (1818–1889). Definition According to the International Bureau of Weights and Measures the joule is defined as "the work done when the point of application of 1 MKS unit of force ewtonmoves a distance of 1 metre in the direction of the force." In terms of SI base units and in terms of SI derived units with special names, the joule is defined as One joule is also equivalent to any of the following: * The work required to move an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Matrix (mathematics)
In mathematics, a matrix (: matrices) is a rectangle, rectangular array or table of numbers, symbol (formal), symbols, or expression (mathematics), expressions, with elements or entries arranged in rows and columns, which is used to represent a mathematical object or property of such an object. For example, \begin1 & 9 & -13 \\20 & 5 & -6 \end is a matrix with two rows and three columns. This is often referred to as a "two-by-three matrix", a " matrix", or a matrix of dimension . Matrices are commonly used in linear algebra, where they represent linear maps. In geometry, matrices are widely used for specifying and representing geometric transformations (for example rotation (mathematics), rotations) and coordinate changes. In numerical analysis, many computational problems are solved by reducing them to a matrix computation, and this often involves computing with matrices of huge dimensions. Matrices are used in most areas of mathematics and scientific fields, either directly ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laguerre Polynomial
In mathematics, the Laguerre polynomials, named after Edmond Laguerre (1834–1886), are nontrivial solutions of Laguerre's differential equation: xy'' + (1 - x)y' + ny = 0,\ y = y(x) which is a second-order linear differential equation. This equation has nonsingular solutions only if is a non-negative integer. Sometimes the name Laguerre polynomials is used for solutions of xy'' + (\alpha + 1 - x)y' + ny = 0~. where is still a non-negative integer. Then they are also named generalized Laguerre polynomials, as will be done here (alternatively associated Laguerre polynomials or, rarely, Sonine polynomials, after their inventor Nikolay Yakovlevich Sonin). More generally, a Laguerre function is a solution when is not necessarily a non-negative integer. The Laguerre polynomials are also used for Gauss–Laguerre quadrature to numerically compute integrals of the form \int_0^\infty f(x) e^ \, dx. These polynomials, usually denoted , , ..., are a polynomial sequ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eigenstate
In quantum physics, a quantum state is a mathematical entity that embodies the knowledge of a quantum system. Quantum mechanics specifies the construction, evolution, and measurement of a quantum state. The result is a prediction for the system represented by the state. Knowledge of the quantum state, and the rules for the system's evolution in time, exhausts all that can be known about a quantum system. Quantum states may be defined differently for different kinds of systems or problems. Two broad categories are * wave functions describing quantum systems using position or momentum variables and * the more abstract vector quantum states. Historical, educational, and application-focused problems typically feature wave functions; modern professional physics uses the abstract vector states. In both categories, quantum states divide into pure versus mixed states, or into coherent states and incoherent states. Categories with special properties include stationary states for time ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
