|
Maxwell's Thermodynamic Surface
Maxwell’s thermodynamic surface is an 1874 sculpture made by Scottish physicist James Clerk Maxwell (1831–1879). This model provides a three-dimensional space of the various states of a fictitious substance with water-like properties. This plot has coordinates volume (x), entropy (y), and energy (z). It was based on the American scientist Josiah Willard Gibbs’ graphical thermodynamics papers of 1873. In Maxwell's words, the model allowed "the principal features of known substances obe represented on a convenient scale." Construction of the model Gibbs' papers defined what Gibbs called the "thermodynamic surface," which expressed the relationship between the volume, entropy, and energy of a substance at different temperatures and pressures. However, Gibbs did not include any diagrams of this surface. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thomas Andrews (scientist)
Thomas Andrews FRS FRSE (19 December 181326 November 1885) was an Irish chemist and physicist who did important work on phase transitions between gases and liquids. He was a longtime professor of chemistry at Queen's University of Belfast. Life Andrews was born in Belfast, Ireland, where his father was a linen merchant. He attended the Belfast Academy and the Royal Belfast Academical Institution, where at the latter of which he studied mathematics under James Thomson. In 1828 he went to the University of Glasgow to study chemistry under Professor Thomas Thomson, then studied at Trinity College, Dublin, where he gained distinction in classics as well as in science. Finally, at University of Edinburgh in 1835, he was awarded a doctorate in medicine. Andrews began a successful medical practice in his native Belfast in 1835, also giving instruction in chemistry at the Academical Institution. In 1845 he was appointed vice-president of the newly established Queen's University ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Muriel Rukeyser
Muriel Rukeyser (December 15, 1913 – February 12, 1980) was an American poet, essayist, biographer, novelist, screenwriter and political activist. She wrote across genres and forms, addressing issues related to racial, gender and class justice, war and war crimes, Jewish culture and diaspora, American history, politics, and culture. Kenneth Rexroth said that she was the greatest poet of her "exact generation," Anne Sexton famously described her as "mother of us all", while Adrienne Rich wrote that she was “our twentieth-century Coleridge; our Neruda." One of her most powerful pieces was the long poem titled ''The Book of the Dead (poem), The Book of the Dead'' (1938), documenting the details of the Hawks Nest Tunnel disaster, an industrial disaster in which hundreds of miners died of silicosis. Her poem "To be a Jew in the Twentieth Century" (1944), on the theme of Judaism as a gift, was adopted by the American Reform Judaism, Reform and Reconstructionist Judaism, Reconstruc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making up a substance. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), with the third being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and even by industry. Further, both spellings are often used ''within'' a particular industry or country. Industries in British English-speaking countries typically use the "gauge" spelling. is the pressure relative to the ambient pressure. Various #Units, units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the International System of Units, SI unit of pressure, the Pascal (unit), pascal (Pa), for example, is one newton (unit), newton per square metre (N/m2); similarly, the Pound (force), pound-force per square inch (Pound per square inch, psi, symbol lbf/in2) is the traditional unit of pressure in the imperial units, imperial and United States customary units, US customary systems. Pressure ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
John Strutt, 3rd Baron Rayleigh
John William Strutt, 3rd Baron Rayleigh ( ; 12 November 1842 – 30 June 1919), was an English physicist who received the Nobel Prize in Physics in 1904 "for his investigations of the densities of the most important gases and for his discovery of argon in connection with these studies". He served as president of the Royal Society from 1905 to 1908 and as chancellor of the University of Cambridge from 1908 to 1919. Rayleigh provided the first theoretical treatment of the elastic scattering of light by particles much smaller than the light's wavelength, a phenomenon now known as "Rayleigh scattering", which notably explains why the sky is blue. He studied and described transverse surface waves in solids, now known as "Rayleigh waves". He contributed extensively to fluid dynamics, with concepts such as the Rayleigh number (a dimensionless number associated with natural convection), Rayleigh flow, the Rayleigh–Taylor instability, and Rayleigh's criterion for the stability of Tay ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Critical Point (thermodynamics)
In thermodynamics, a critical point (or critical state) is the end point of a phase Equilibrium (thermodynamics), equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas comes into a supercritical fluid, supercritical phase, and so cannot be liquefied by pressure alone. At the critical point, defined by a ''critical temperature'' ''T''c and a ''critical pressure'' ''p''c, phase (matter), phase boundaries vanish. Other examples include the Upper critical solution temperature, liquid–liquid critical points in mixtures, and the ferromagnet–paramagnet transition (Curie temperature) in the absence of an external magnetic field. Liquid–vapor critical point Overview For simplicity and clarity, the generic notion of ''critical point'' is best introduced by discussing a specific example, the vapor–liquid cr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spinodal
In thermodynamics, the limit of local stability against phase separation with respect to small fluctuations is clearly defined by the condition that the second derivative of Gibbs free energy is zero. : 0 The locus of these points (the inflection point within a G-x or G-c curve, Gibbs free energy as a function of composition) is known as the spinodal curve.G. Astarita: ''Thermodynamics: An Advanced Textbook for Chemical Engineers'' (Springer 1990), chaps 4, 8, 9, 12.Sandler S. I., ''Chemical and Engineering Thermodynamics''. 1999 John Wiley & Sons, Inc., p 571.Koningsveld K., Stockmayer W. H., Nies, E., ''Polymer Phase Diagrams: A Textbook''. 2001 Oxford, p 12. For compositions within this curve, infinitesimally small fluctuations in composition and density will lead to phase separation via spinodal decomposition. Outside of the curve, the solution will be at least metastable with respect to fluctuations. In other words, outside the spinodal curve some careful process may obtain ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Supercooling
Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid below its freezing point without it becoming a solid. Per the established international definition, supercooling means ''‘cooling a substance below the normal freezing point without solidification’.'' IIR International Dictionary of Refrigeration, http://dictionary.iifiir.org/search.php ASHRAE Terminology, https://www.ashrae.org/technical-resources/free-resources/ashrae-terminology While it can be achieved by different physical means, the postponed solidification is most often due to the absence of nucleation, seed crystals or nuclei around which a crystal structure can form. The supercooling of water can be achieved without any special techniques other than chemical demineralization, down to . Supercooled water can occur naturally, for example in the atmosphere, animals or plants. This phenomenon was first identified in 1724 by Daniel Gabriel Fahrenheit, while developing Fahren ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superheating
In thermodynamics, superheating (sometimes referred to as boiling retardation, or boiling delay) is the phenomenon in which a liquid is heated to a temperature higher than its boiling point, without boiling. This is a so-called ''metastable state'' or '' metastate'', where boiling might occur at any time, induced by external or internal effects.Debenedetti, P.G.Metastable Liquids: Concepts and Principles; Princeton University Press: Princeton, NJ, USA, 1996.Maris, H., Balibar, S. (2000"Negative Pressures and Cavitation in Liquid Helium"Physics Today 53, 29 Superheating is achieved by heating a homogeneous substance in a clean container, free of nucleation sites, while taking care not to disturb the liquid. This may occur by microwaving water in a very smooth container. Disturbing the water may cause an unsafe eruption of hot water and result in burns. Cause Water is said to "boil" when bubbles of water vapor grow without bound, bursting at the surface. For a vapor bubble ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triple Point
In thermodynamics, the triple point of a substance is the temperature and pressure at which the three Phase (matter), phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium.. It is that temperature and pressure at which the sublimation (phase transition), sublimation, Melting, fusion, and vaporisation curves meet. For example, the triple point of Mercury (element), mercury occurs at a temperature of and a pressure of 0.165 Milli, mPascal (unit), Pa. In addition to the triple point for solid, liquid, and gas phases, a triple point may involve more than one solid phase, for substances with multiple polymorphism (materials science), polymorphs. Helium-4 is unusual in that it has no sublimation/deposition curve and therefore no triple points where its solid phase meets its gas phase. Instead, it has a vapor-liquid-superfluid point, a solid-liquid-superfluid point, a solid-solid-liquid point, and a solid-solid-superfluid point. None of these should be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tangent Plane
In geometry, the tangent line (or simply tangent) to a plane curve at a given point is, intuitively, the straight line that "just touches" the curve at that point. Leibniz defined it as the line through a pair of infinitely close points on the curve. More precisely, a straight line is tangent to the curve at a point if the line passes through the point on the curve and has slope , where ''f'' is the derivative of ''f''. A similar definition applies to space curves and curves in ''n''-dimensional Euclidean space. The point where the tangent line and the curve meet or intersect is called the ''point of tangency''. The tangent line is said to be "going in the same direction" as the curve, and is thus the best straight-line approximation to the curve at that point. The tangent line to a point on a differentiable curve can also be thought of as a '' tangent line approximation'', the graph of the affine function that best approximates the original function at the given poi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
