|
Magic Angle Spinning
In solid-state NMR spectroscopy, magic-angle spinning (MAS) is a technique routinely used to produce better resolution NMR spectra. MAS NMR consists in spinning the sample (usually at a frequency of 1 to 130 kHz) at the magic angle θm (ca. 54.74°, where cos2θm=1/3) with respect to the direction of the magnetic field. Three main interactions responsible in solid state NMR ( dipolar, chemical shift anisotropy, quadrupolar) often lead to very broad and featureless NMR lines. However, these three interactions in solids are orientation-dependent and can be averaged to some extent by MAS: * The nuclear dipolar interaction has a 3\cos^2\theta - 1 dependence, where \theta is the angle between the internuclear axis and the main magnetic field. As a result, the dipolar interaction vanish at the magic angle θm and the interaction contributing to the line broadening is removed. Even though all internuclear vectors cannot be all set to the magic angle, rotating the sample around ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silicon Nitride
Silicon nitride is a chemical compound of the elements silicon and nitrogen. (''Trisilicon tetranitride'') is the most thermodynamically stable and commercially important of the silicon nitrides, and the term ″''Silicon nitride''″ commonly refers to this specific composition. It is a white, high-melting-point solid that is relatively chemically inert, being attacked by dilute HF and hot . It is very hard (8.5 on the mohs scale). It has a high thermal stability with strong optical nonlinearities for all-optical applications. Production Silicon nitride is prepared by heating powdered silicon between 1300 °C and 1400 °C in a nitrogen atmosphere: :3 Si + 2 → The silicon sample weight increases progressively due to the chemical combination of silicon and nitrogen. Without an iron catalyst, the reaction is complete after several hours (~7), when no further weight increase due to nitrogen absorption (per gram of silicon) is detected. In addition to , several other ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Edward Raymond Andrew
Edward Raymond Andrew (27 June 1921 – 27 May 2001) was a 20th-century British scientist who was a pioneer of nuclear magnetic resonance. He was a primary figure in the development and creation of the world's first MRI scanner. Life He was born in Boston, Lincolnshire, on 27 June 1921 the only child of English parents of Scots descent. He was educated at Wellingborough School where he was head boy. He then won a place at Christ's College, Cambridge on a Natural Science Tripos from 1939 to 1942 under C. P. Snow, Lawrence Bragg, Norman Feather, and David Shoenberg.Independent (newspaper) obituary 26 July 2001 From 1942 to 1945, during the Second World War, he was a Scientific Officer at the Air Defence Research and Development Establishment in Malvern studying the effects of gun flashes on radar. In 1945 he returned to Cambridge as a research student at Pembroke College and the Cavendish Laboratory. Here he worked with David Shoenberg on superconductors, gaining a doctor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron Nitride
Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula B N. It exists in various crystalline forms that are isoelectronic to a similarly structured carbon lattice. The hexagonal form corresponding to graphite is the most stable and soft among BN polymorphs, and is therefore used as a lubricant and an additive to cosmetic products. The cubic ( zincblende aka sphalerite structure) variety analogous to diamond is called c-BN; it is softer than diamond, but its thermal and chemical stability is superior. The rare wurtzite BN modification is similar to lonsdaleite but slightly softer than the cubic form. Because of excellent thermal and chemical stability, boron nitride ceramics are used in high-temperature equipment and metal casting. Boron nitride has potential use in nanotechnology. History Boron nitride was discovered by chemistry teacher of the Liverpool Institute in 1842 via reduction of boric acid with ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconium Dioxide
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zirconium silicate or zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vespel
Vespel is the trademark of a range of durable high-performance polyimide-based plastics made by DuPont. Characteristics and applications Vespel is mostly used in aerospace, semiconductor, and transportation technology. It combines heat resistance, lubricity, dimensional stability, chemical resistance, and creep resistance, and can be used in hostile and extreme environmental conditions. Unlike most plastics, it does not produce significant outgassing even at high temperatures, which makes it useful for lightweight heat shields and crucible support. It also performs well in vacuum applications, down to extremely low cryogenic temperatures. However, Vespel tends to absorb a small amount of water, resulting in longer pump time while placed in a vacuum. Although there are polymers surpassing polyimide in each of these properties, the combination of them is the main advantage of Vespel. Thermophysical properties Vespel is commonly used as a thermal conductivity reference mat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polychlorotrifluoroethylene
Polychlorotrifluoroethylene (PCTFE or PTFCE) is a thermoplastic chlorofluoropolymer with the molecular formula , where ''n'' is the number of monomer units in the polymer molecule. It is similar to polytetrafluoroethene (PTFE), except that it is a homopolymer of the monomer chlorotrifluoroethylene (CTFE) instead of tetrafluoroethene. It has the lowest water vapor transmission rate of any plastic. History It was discovered in 1934 by Fritz Schloffer and Otto Scherer who worked at IG Farben Company, Germany. Trade names After World War II, PCTFE was commercialized under the trade name of Kel-F 81 by M. W. Kellogg Company in early 1950s. The name "Kel-F" was derived from "Kellogg" and "fluoropolymer", which also represents other fluoropolymers like the copolymer poly(chlorotrifluoroethylene-co-vinylidene fluoride) (Kel-F 800). These were acquired by 3M Company in 1957. 3M discontinued manufacturing of Kel-F by 1996. PCTFE resin is now manufactured under different trade na ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyoxymethylene
Polyoxymethylene (POM), also known as acetal, polyacetal, and polyformaldehyde, is an engineering thermoplastic used in precision parts requiring high stiffness, low friction, and excellent dimensional stability. Short-chained POM (chain length between 8 and 100 repeating units) is also better known as paraformaldehyde (PFA). As with many other synthetic polymers, polyoxymethylenes are produced by different chemical firms with slightly different formulas and sold as Delrin, Kocetal, Ultraform, Celcon, Ramtal, Duracon, Kepital, Polypenco, Tenac and Hostaform. POM is characterized by its high strength, hardness and rigidity to −40 °C. POM is intrinsically opaque white because of its high crystalline composition but can be produced in a variety of colors. POM has a density of 1.410–1.420g/cm3. Typical applications for injection-molded POM include high-performance engineering components such as small gear wheels, eyeglass frames, ball bearings, ski bindings, fasteners ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Poly(methyl Methacrylate)
Poly(methyl methacrylate) (PMMA) is a synthetic polymer derived from methyl methacrylate. It is a transparent thermoplastic, used as an engineering plastic. PMMA is also known as acrylic, acrylic glass, as well as by the trade names and brands Crylux, Walcast, Hesalite, Plexiglas, Acrylite, Lucite, PerClax, and Perspex, among several others ( see below). This plastic is often used in sheet form as a lightweight or shatter-resistant alternative to glass. It can also be used as a casting resin, in inks and coatings, and for many other purposes. It is often technically classified as a type of glass, in that it is a non-crystalline vitreous substance—hence its occasional historic designation as ''acrylic glass''. History The first acrylic acid was created in 1843. Methacrylic acid, derived from acrylic acid, was formulated in 1865. The reaction between methacrylic acid and methanol results in the ester methyl methacrylate. It was developed in 1928 in several different la ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Air Bearing
Air bearings (also known as aerostatic or aerodynamic bearings) are bearings that use a thin film of pressurized gas to provide a low friction load-bearing interface between surfaces. The two surfaces do not touch, thus avoiding the problems of friction, wear, particulates, and lubricant handling associated with conventional bearings, and air bearings offer distinct advantages in precision positioning, such as lacking backlash and static friction, as well as in high-speed applications. Spacecraft simulators now most often use air bearings, and 3D printing, 3-D printers are now used to make air-bearing–based attitude simulators for CubeSat satellites.Nemanja Jovanovic, et al. Design and Testing of a Low-Cost, Open Source, 3-D Printed Air-Bearing-Based Attitude Simulator for CubeSat Satellites. ''Journal of Small Satellites'' Vol. 8, No. 2, pp. 859–880 (2019). https://jossonline.com/letters/design-and-testing-of-a-low-cost-open-source-3-d-printed-air-bearing-based-attitude-simul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid-state NMR
Solid-state nuclear magnetic resonance (ssNMR) is a spectroscopy technique used to characterize atomic-level structure and dynamics in solid materials. ssNMR spectra are broader due to nuclear spin interactions which can be categorized as dipolar coupling, chemical shielding, Quadrupole, quadrupolar interactions, and j-coupling. These interactions directly affect the lines shapes of experimental ssNMR spectra which can be seen in powder and dipolar patterns. There are many essential solid-state techniques alongside advanced ssNMR techniques that may be applied to elucidate the fundamental aspects of solid materials. ssNMR is often combined with magic angle spinning (MAS) to remove Anisotropy, anisotropic interactions and improve the sensitivity of the technique. The applications of ssNMR further extend to biology and medicine. Nuclear spin interactions The resonance frequency of a nuclear spin depends on the strength of the magnetic field at the Atomic nucleus, nucleus, which c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Turbine
A turbine ( or ) (from the Greek , ''tyrbē'', or Latin ''turbo'', meaning vortex) is a rotary mechanical device that extracts energy from a fluid flow and converts it into useful work. The work produced can be used for generating electrical power when combined with a generator.Munson, Bruce Roy, T. H. Okiishi, and Wade W. Huebsch. "Turbomachines." Fundamentals of Fluid Mechanics. 6th ed. Hoboken, NJ: J. Wiley & Sons, 2009. Print. A turbine is a turbomachine with at least one moving part called a rotor assembly, which is a shaft or drum with blades attached. Moving fluid acts on the blades so that they move and impart rotational energy to the rotor. Gas, steam, and water turbines have a casing around the blades that contains and controls the working fluid. Modern steam turbines frequently employ both reaction and impulse in the same unit, typically varying the degree of reaction and impulse from the blade root to its periphery. History Hero of Alexandria demonstrat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
