Lead–acid Battery
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Lead–acid Battery
The lead–acid battery is a type of rechargeable battery first invented in 1859 by French physicist Gaston Planté. It is the first type of rechargeable battery ever created. Compared to modern rechargeable batteries, lead–acid batteries have relatively low energy density. Despite this, their ability to supply high surge currents means that the cells have a relatively large power-to-weight ratio. These features, along with their low cost, make them attractive for use in motor vehicles to provide the high current required by starter motors. Lead-acid batteries suffer from relatively short cycle lifespan (usually less than 500 deep cycles) and overall lifespan (due to the "double sulfation" in the discharged state). As they are inexpensive compared to newer technologies, lead–acid batteries are widely used even when surge current is not important and other designs could provide higher energy densities. In 1999, lead–acid battery sales accounted for 40–50% of the value from ...
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Car Battery
An automotive battery or car battery is a rechargeable battery that is used to start a motor vehicle. Its main purpose is to provide an electric current to the electric-powered starting motor, which in turn starts the chemically-powered internal combustion engine that actually propels the vehicle. Once the engine is running, power for the car's electrical systems is still supplied by the battery, with the alternator charging the battery as demands increase or decrease. Battery in modern cars Gasoline and diesel engine Typically, starting uses less than three percent of the battery capacity. For this reason, automotive batteries are designed to deliver maximum current for a short period of time. They are sometimes referred to as "SLI batteries" for this reason, for starting, lighting and ignition. SLI batteries are not designed for deep discharging, and a full discharge can reduce the battery's lifespan. As well as starting the engine, an SLI battery supplies the extra power ne ...
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Lead Dioxide
Lead(IV) oxide is the inorganic compound with the formula PbO2. It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries. Properties Physical Lead dioxide has two major polymorphs, alpha and beta, which occur naturally as rare minerals scrutinyite and plattnerite, respectively. Whereas the beta form had been identified in 1845, α-PbO2 was first identified in 1946 and found as a naturally occurring mineral 1988. The alpha form has orthorhombic symmetry, space group Pbcn (No. 60), Pearson symbol ''oP''12, lattice constants ''a'' = 0.497 nm, ''b'' = 0.596 nm, ''c'' = 0.544 nm, ''Z'' = 4 (four formula units per unit cell). The lead atoms are six-coordinate. The symmetry of the beta form is tetragonal, space group P42/mnm (No. 136), Pearson symbol ''tP''6, la ...
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Ampere Hour
An ampere hour or amp hour (symbol: A⋅h or A h; often simplified as Ah) is a unit of electric charge, having dimensions of electric current multiplied by time, equal to the charge transferred by a steady current of one ampere flowing for one hour, or 3,600 coulombs. The commonly seen milliampere hour (symbol: mA⋅h, mA h, simplified as mAh) is one-thousandth of an ampere hour (3.6 coulombs). Use The ampere hour is frequently used in measurements of electrochemical systems such as electroplating and for battery capacity where the commonly known nominal voltage is dropped. A ''milliampere second'' (mA⋅s) is a unit of measurement used in X-ray imaging, diagnostic imaging, and radiation therapy. It is equivalent to a ''millicoulomb''. This quantity is proportional to the total X-ray energy produced by a given X-ray tube operated at a particular voltage. The same total dose can be delivered in different time periods depending on the X-ray tube current. To help e ...
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Coulomb
The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI). In the present version of the SI it is equal to the electric charge delivered by a 1 ampere constant current in 1 second and to elementary charges, , (about ). Name and history By 1878, the British Association for the Advancement of Science had defined the volt, ohm, and farad, but not the coulomb. In 1881, the International Electrical Congress, now the International Electrotechnical Commission (IEC), approved the volt as the unit for electromotive force, the ampere as the unit for electric current, and the coulomb as the unit of electric charge. At that time, the volt was defined as the potential difference .e., what is nowadays called the "voltage (difference)"across a conductor when a current of one ampere dissipates one watt of power. The coulomb (later "absolute coulomb" or "abcoulomb" for disambiguation) was part of the EMU system of units. The "international coulo ...
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Faraday (unit)
In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of SI base units, which took effect on 20 May 2019, the Faraday constant has the exactly defined value given by the product of the elementary charge ''e'' and Avogadro constant ''N''A: : : :. Derivation The Faraday constant can be thought of as the conversion factor between the mole (used in chemistry) and the coulomb (used in physics and in practical electrical measurements), and is therefore of particular use in electrochemistry. Because 1 mole contains exactly entities, and 1 coulomb contains exactly elementary charges, the Faraday constant is given by the quotient of these two quantities: :. One common use of the Faraday constant is in electrolysis calculations. One can divide the amount of charge (the current integrated over time) ...
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Mole (unit)
The mole, symbol mol, is the unit of amount of substance in the International System of Units (SI). The quantity amount of substance is a measure of how many elementary entities of a given substance are in an object or sample. The mole is defined as containing exactly elementary entities. Depending on what the substance is, an elementary entity may be an atom, a molecule, an ion, an ion pair, or a subatomic particle such as an electron. For example, 10 moles of water (a chemical compound) and 10 moles of mercury (a chemical element), contain equal amounts of substance and the mercury contains exactly one atom for each molecule of the water, despite the two having different volumes and different masses. The number of elementary entities in one mole is known as the Avogadro number, which is the approximate number of nucleons (protons or neutrons) in one gram of ordinary matter. The previous definition of a mole was simply the number of elementary entities equal to that of 12 gram ...
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Lead Dioxide
Lead(IV) oxide is the inorganic compound with the formula PbO2. It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries. Properties Physical Lead dioxide has two major polymorphs, alpha and beta, which occur naturally as rare minerals scrutinyite and plattnerite, respectively. Whereas the beta form had been identified in 1845, α-PbO2 was first identified in 1946 and found as a naturally occurring mineral 1988. The alpha form has orthorhombic symmetry, space group Pbcn (No. 60), Pearson symbol ''oP''12, lattice constants ''a'' = 0.497 nm, ''b'' = 0.596 nm, ''c'' = 0.544 nm, ''Z'' = 4 (four formula units per unit cell). The lead atoms are six-coordinate. The symmetry of the beta form is tetragonal, space group P42/mnm (No. 136), Pearson symbol ''tP''6, la ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released may boi ...
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Electrolyte
An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also function as electrolytes. El ...
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Lead(II) Sulfate
Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as ''fast white'', ''milk white'', ''sulfuric acid lead salt'' or ''anglesite''. It is often seen in the plates/electrodes of car batteries, as it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic lead and sulfuric acid on the negative terminal or lead dioxide and sulfuric acid on the positive terminal). Lead sulfate is poorly soluble in water. Manufacturing Lead(II) sulfate is prepared by treating lead oxide, hydroxide or carbonate with warm sulfuric acid or by treating a soluble lead salt with sulfuric acid. Alternatively, it can be made by the interaction of solutions of lead nitrate and sodium sulfate. Toxicology Lead sulfate is toxic by inhalation, ingestion and skin contact. It is a cumulative poison, and repeated exposure may lead to anemia, kidney damage, eyesight damage or damage to the cen ...
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Discharged
Discharge may refer to Expel or let go * Discharge, the act of firing a gun * Discharge, or termination of employment, the end of an employee's duration with an employer * Military discharge, the release of a member of the armed forces from service Flow * Discharge (hydrology), the amount of water flowing through the channel ** Effluent released into a river or sea ** Groundwater discharge, the volumetric flow rate of groundwater through an aquifer * Discharging method (discrete mathematics) is a proof technique in discrete mathematics * Electric discharge: ** Corona discharge, a type of electric current ** Direct-current discharge, a plasma ** Discharger, an electrical device that releases stored energy *** Battery discharging *** Static discharger, a device used on airplanes to maintain use of electrical equipment ** Electrostatic discharge, sudden and momentary electric current flows between two objects *** Dielectric barrier discharge, the electrical discharge between tw ...
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American Physical Society
The American Physical Society (APS) is a not-for-profit membership organization of professionals in physics and related disciplines, comprising nearly fifty divisions, sections, and other units. Its mission is the advancement and diffusion of knowledge of physics. The society publishes more than a dozen scientific journals, including the prestigious '' Physical Review'' and ''Physical Review Letters'', and organizes more than twenty science meetings each year. APS is a member society of the American Institute of Physics. Since January 2021 the organization has been led by chief executive officer Jonathan Bagger. History The American Physical Society was founded on May 20, 1899, when thirty-six physicists gathered at Columbia University for that purpose. They proclaimed the mission of the new Society to be "to advance and diffuse the knowledge of physics", and in one way or another the APS has been at that task ever since. In the early years, virtually the sole activity of the AP ...
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