Laser Absorption Spectrometry
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Laser Absorption Spectrometry
Laser absorption spectrometry (LAS) refers to techniques that use lasers to assess the concentration or amount of a species in gas phase by absorption spectrometry (AS). Optical spectroscopic techniques in general, and laser-based techniques in particular, have a great potential for detection and monitoring of constituents in gas phase. They combine a number of important properties, e.g. a high sensitivity and a high selectivity with non-intrusive and remote sensing capabilities. Laser absorption spectrometry has become the foremost used technique for quantitative assessments of atoms and molecules in gas phase. It is also a widely used technique for a variety of other applications, e.g. within the field of optical frequency metrology or in studies of light matter interactions. The most common technique is tunable diode laser absorption spectroscopy (TDLAS) which has become commercialized and is used for a variety of applications. Direct laser absorption spectrometry The most a ...
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Laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The first laser was built in 1960 by Theodore H. Maiman at Hughes Research Laboratories, based on theoretical work by Charles Hard Townes and Arthur Leonard Schawlow. A laser differs from other sources of light in that it emits light which is ''coherent''. Spatial coherence allows a laser to be focused to a tight spot, enabling applications such as laser cutting and lithography. Spatial coherence also allows a laser beam to stay narrow over great distances (collimation), enabling applications such as laser pointers and lidar (light detection and ranging). Lasers can also have high temporal coherence, which allows them to emit light with a very narrow spectrum. Alternatively, temporal coherence can be used to produce ultrashort pulses of ligh ...
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Process Control
An industrial process control in continuous production processes is a discipline that uses industrial control systems to achieve a production level of consistency, economy and safety which could not be achieved purely by human manual control. It is implemented widely in industries such as automotive, mining, dredging, oil refining, pulp and paper manufacturing, chemical processing and power generating plants. There is a wide range of size, type and complexity, but it enables a small number of operators to manage complex processes to a high degree of consistency. The development of large industrial process control systems was instrumental in enabling the design of large high volume and complex processes, which could not be otherwise economically or safely operated. The applications can range from controlling the temperature and level of a single process vessel, to a complete chemical processing plant with several thousand control loops. History Early process control breakthrou ...
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Hertz
The hertz (symbol: Hz) is the unit of frequency in the International System of Units (SI), equivalent to one event (or cycle) per second. The hertz is an SI derived unit whose expression in terms of SI base units is s−1, meaning that one hertz is the reciprocal of one second. It is named after Heinrich Rudolf Hertz (1857–1894), the first person to provide conclusive proof of the existence of electromagnetic waves. Hertz are commonly expressed in multiples: kilohertz (kHz), megahertz (MHz), gigahertz (GHz), terahertz (THz). Some of the unit's most common uses are in the description of periodic waveforms and musical tones, particularly those used in radio- and audio-related applications. It is also used to describe the clock speeds at which computers and other electronics are driven. The units are sometimes also used as a representation of the energy of a photon, via the Planck relation ''E'' = ''hν'', where ''E'' is the photon's energy, ''ν'' is its freq ...
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Longitudinal Mode
A longitudinal mode of a resonant cavity is a particular standing wave pattern formed by waves confined in the cavity. The longitudinal modes correspond to the wavelengths of the wave which are reinforced by constructive interference after many reflections from the cavity's reflecting surfaces. All other wavelengths are suppressed by destructive interference. A longitudinal mode pattern has its nodes located axially along the length of the cavity. Transverse modes, with nodes located perpendicular to the axis of the cavity, may also exist. Simple cavity A common example of longitudinal modes are the light wavelengths produced by a laser. In the simplest case, the laser's optical cavity is formed by two opposed plane (flat) mirrors surrounding the gain medium (a plane-parallel or Fabry–Pérot cavity). The allowed modes of the cavity are those where the mirror separation distance ''L'' is equal to an exact multiple of half the wavelength, ''λ'': : L = q \frac where ''q'' is ...
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White Cell (spectroscopy)
Multiple-pass or long path absorption cells are commonly used in spectroscopy to measure low-concentration components or to observe weak spectra in gases or liquids. Several important advances were made in this area beginning in the 1930s, and research into a wide range of applications continues to the present day. Functional Overview Generally the goal of this type of sample cell is to improve detection sensitivity by increasing the total optical path length that travels through a small, constant sample volume. In principle, a longer path length results in greater detection sensitivity. Focusing mirrors must be used to redirect the beam at each reflection point, resulting in the beam being restricted to a predefined space along a controlled path until it exits the optical cavity. The output of the cell is the input of an optical detector (a specialized type of transducer), which senses specific changes in the properties of the beam that occur during interaction with the test sam ...
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Herriott Cell
Multiple-pass or long path absorption cells are commonly used in spectroscopy to measure low-concentration components or to observe weak spectra in gases or liquids. Several important advances were made in this area beginning in the 1930s, and research into a wide range of applications continues to the present day. Functional Overview Generally the goal of this type of sample cell is to improve detection sensitivity by increasing the total optical path length that travels through a small, constant sample volume. In principle, a longer Optical path length, path length results in greater detection sensitivity. Focusing mirrors must be used to redirect the beam at each reflection point, resulting in the beam being restricted to a predefined space along a controlled path until it exits the optical cavity. The output of the cell is the input of an optical detector (a specialized type of transducer), which senses specific changes in the properties of the beam that occur during interactio ...
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