Iron–nickel Clusters
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Iron–nickel Clusters
image:Polyhedra cluster chem.PNG, 350px, Figure 1: Closed triangulated polyhedra. (a) Tetrahedron (Td), (b) Trigonal bipyramid (D3h). (c) Octahedron (Oh). (d) Pentagonal bipyramid (D5d). (e) Capped octahedron (Cs). (f) Octadecahedron (C2r) Iron–nickel (Fe–Ni) clusters are metal cluster chemistry, clusters consisting of iron and nickel, i.e. Fe–Ni structures displaying polyhedral frameworks held together by two or more metal–metal bonds per metal atom, where the metal atoms are located at the vertices of closed, triangulated polyhedra. Individually, iron (Fe) and nickel (Ni) generally form metal clusters with π-acceptor ligands. Π acceptor ligands are ligands that remove some of the electron density from the metal. Figure 1 contains pictures of representative cluster shapes. Clusters take the form of closed, triangulated Polyhedron, polyhedral. Corresponding bulk systems of Fe and Ni atoms show a variety of composition-dependent abnormalities and unusual effects. Fe–Ni ...
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Polyhedra Cluster Chem
In geometry, a polyhedron (plural polyhedra or polyhedrons; ) is a Three-dimensional space, three-dimensional shape with flat polygonal Face (geometry), faces, straight Edge (geometry), edges and sharp corners or Vertex (geometry), vertices. A convex polyhedron is the convex hull of finitely many points, not all on the same plane. Cubes and Pyramid (geometry), pyramids are examples of convex polyhedra. A polyhedron is a 3-dimensional example of a polytope, a more general concept in any number of dimensions. Definition convex polyhedron, Convex polyhedra are well-defined, with several equivalent standard definitions. However, the formal mathematical definition of polyhedra that are not required to be convex has been problematic. Many definitions of "polyhedron" have been given within particular contexts,. some more rigorous than others, and there is not universal agreement over which of these to choose. Some of these definitions exclude shapes that have often been counted as ...
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