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Ionization Energies
In physics and chemistry, ionization energy (IE) is the minimum energy required to remove the most loosely bound electron of an isolated gaseous atom, positive ion, or molecule. The first ionization energy is quantitatively expressed as :X(g) + energy ⟶ X+(g) + e− where X is any atom or molecule, X+ is the resultant ion when the original atom was stripped of a single electron, and e− is the removed electron. Ionization energy is positive for neutral atoms, meaning that the ionization is an endothermic process. Roughly speaking, the closer the outermost electrons are to the nucleus of the atom, the higher the atom's ionization energy. In physics, ionization energy (IE) is usually expressed in electronvolts (eV) or joules (J). In chemistry, it is expressed as the energy to ionize a mole of atoms or molecules, usually as kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Comparison of ionization energies of atoms in the periodic table reveals two periodi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molar Ionization Energies Of The Elements
These tables list values of molar ionization energies, measured in kJ⋅mol−1. This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions. The first molar ionization energy applies to the neutral atoms. The second, third, etc., molar ionization energy applies to the further removal of an electron from a singly, doubly, etc., charged ion. For ionization energies measured in the unit eV, see '' Ionization energies of the elements (data page)''. All data from rutherfordium Rutherfordium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Rf and atomic number 104. It is named after physicist Ernest Rutherford. As a synthetic element, it is not found in nature and can only be made in a p ... onwards is predicted. 1st–10th ionization energies 11th–20th ionisation energies 21st–30th ionisation energies References * Ionization energies of the elements (data page) * (for predictions) * * ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coulombic Attraction
Electrostatics is a branch of physics that studies slow-moving or stationary electric charges. Since classical antiquity, classical times, it has been known that some materials, such as amber, attract lightweight particles after triboelectric effect, rubbing. The Greek language, Greek word (), meaning 'amber', was thus the Root (linguistics), root of the word ''electricity''. Electrostatic phenomena arise from the forces that electric charges exert on each other. Such forces are described by Coulomb's law. There are many examples of electrostatic phenomena, from those as simple as the attraction of plastic wrap to one's hand after it is removed from a package, to the apparently spontaneous explosion of grain silos, the damage of electronic components during manufacturing, and photocopier and laser printing, laser printer operation. The electrostatic model accurately predicts electrical phenomena in "classical" cases where the velocities are low and the system is macroscopic so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Particle Accelerator
A particle accelerator is a machine that uses electromagnetic fields to propel electric charge, charged particles to very high speeds and energies to contain them in well-defined particle beam, beams. Small accelerators are used for fundamental research in particle physics. Accelerators are also used as synchrotron light sources for the study of condensed matter physics. Smaller particle accelerators are used in a wide variety of applications, including particle therapy for oncology, oncological purposes, Isotopes in medicine, radioisotope production for medical diagnostics, Ion implantation, ion implanters for the manufacturing of Semiconductor, semiconductors, and Accelerator mass spectrometry, accelerator mass spectrometers for measurements of rare isotopes such as radiocarbon. Large accelerators include the Relativistic Heavy Ion Collider at Brookhaven National Laboratory in New York, and the largest accelerator, the Large Hadron Collider near Geneva, Switzerland, operated b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Shell
In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus. The shells correspond to the principal quantum numbers (''n'' = 1, 2, 3, 4 ...) or are labeled alphabetically with the letters used in X-ray notation (K, L, M, ...). Each period on the conventional periodic table of elements represents an electron shell. Each shell can contain only a fixed number of electrons: the first shell can hold up to two electrons, the second shell can hold up to eight electrons, the third shell can hold up to 18, continuing as the general formula of the ''n''th shell being able to hold up to 2( ''n''2) electrons. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Pair
In chemistry, an electron pair or Lewis pair consists of two electrons that occupy the same molecular orbital but have opposite spins. Gilbert N. Lewis introduced the concepts of both the electron pair and the covalent bond in a landmark paper he published in 1916. Because electrons are fermions, the Pauli exclusion principle forbids these particles from having all the same quantum numbers. Therefore, for two electrons to occupy the same orbital, and thereby have the same orbital quantum number, they must have different spin quantum numbers. This also limits the number of electrons in the same orbital to two. The pairing of spins is often energetically favorable, and electron pairs therefore play a large role in chemistry. They can form a chemical bond A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds or through th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
D-block Contraction
The d-block contraction (sometimes called scandide contraction) is a term used in chemistry to describe the effect of having full d orbitals on the period 4 elements. The elements in question are gallium, germanium, arsenic, selenium, bromine, and krypton. Their electronic configurations include completely filled d orbitals (d10). The d-block contraction is best illustrated by comparing some properties of the group 13 elements to highlight the effect on gallium. Gallium can be seen to be anomalous. The most obvious effect is that the sum of the first three ionization potentials of gallium is higher than that of aluminium, whereas the trend in the group would be for it to be lower. The second table below shows the trend in the sum of the first three ionization potentials for the elements B, Al, Sc, Y, and La. Sc, Y, and La have three valence electrons above a noble gas electron core. In contrast to the group 13 elements, this sequence shows a smooth reduction. Ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lanthanide Contraction
The lanthanide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the lanthanide series, from left to right. It is caused by the poor shielding effect of nuclear charge by the 4f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right. About 10% of the lanthanide contraction has been attributed to relativistic effects. A decrease in atomic radii can be observed across the 4f elements from atomic number 57, lanthanum, to 70, ytterbium. This results in smaller than otherwise expected atomic radii and ionic radii for the subsequent d-block elements starting with 71, lutetium. Jolly, William L. ''Modern Inorganic Chemistry'', McGraw-Hill 1984, p. 22 This effect causes the radii of transition metals of group 5 and 6 to become unusually similar, as the expected increase in radius going down a period is nearly cancelled out by the f-block insertion, and has ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every atom of that element. The atomic number can be used to uniquely identify ordinary chemical elements. In an ordinary uncharged atom, the atomic number is also equal to the number of electrons. For an ordinary atom which contains protons, neutrons and electrons, the sum of the atomic number ''Z'' and the neutron number ''N'' gives the atom's atomic mass number ''A''. Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of the nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in daltons (making a quantity called the " relative isotopic mass"), is within 1% ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Relativistic Quantum Chemistry
Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to calculate elemental properties and structure, especially for the heavier elements of the periodic table. A prominent example is an explanation for the color of gold: due to relativistic effects, it is not silvery like most other metals. The term ''relativistic effects'' was developed in light of the history of quantum mechanics. Initially, quantum mechanics was developed without considering the theory of relativity. Relativistic effects are those discrepancies between values calculated by models that consider relativity and those that do not. Relativistic effects are important for heavier elements with high atomic numbers, such as lanthanides and actinides. Relativistic effects in chemistry can be considered to be perturbations, or small corrections, to the non-relativistic theory of chemistry, which is developed from the solutions of the Schrödinger equation. These corrections affect the el ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Configuration
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is , meaning that the 1s, 2s, and 2p subshells are occupied by two, two, and six electrons, respectively. Electronic configurations describe each electron as moving independently in an orbital, in an average field created by the nuclei and all the other electrons. Mathematically, configurations are described by Slater determinants or configuration state functions. According to the laws of quantum mechanics, a level of energy is associated with each electron configuration. In certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon. Knowledge of the electron configuration of different atoms is useful in understanding the structu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Shielding Effect
In chemistry, the shielding effect sometimes referred to as atomic shielding or electron shielding describes the attraction between an electron and the nucleus in any atom with more than one electron. The shielding effect can be defined as a reduction in the effective nuclear charge on the electron cloud, due to a difference in the attraction forces on the electrons in the atom. It is a special case of electric-field screening. This effect also has some significance in many projects in material sciences. Strength per electron shell or orbital The wider the electron shells are in space, the weaker is the electric interaction between the electrons and the nucleus due to screening. Further, because of differences in orbital penetration, we can order the screening strength, ''S'', that electrons in a given orbital (s, p, d, or f) provide to the rest of the electrons thus: S(\mathrm) > S(\mathrm) > S(\mathrm) > S(\mathrm) . Description In hydrogen, or any other atom in group 1 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Effective Nuclear Charge
In atomic physics, the effective nuclear charge of an electron in a multi-electron atom or ion is the number of elementary charges (e) an electron experiences by the nucleus. It is denoted by ''Z''eff. The term "effective" is used because the shielding effect of negatively charged electrons prevent higher energy electrons from experiencing the full nuclear charge of the nucleus due to the repelling effect of inner layer. The effective nuclear charge experienced by an electron is also called the core charge. It is possible to determine the strength of the nuclear charge by the oxidation number of the atom. Most of the physical and chemical properties of the elements can be explained on the basis of electronic configuration. Consider the behavior of ionization energies in the periodic table. It is known that the magnitude of ionization potential depends upon the following factors: # The size of an atom # The nuclear charge; oxidation number # The screening effect of the inner she ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
