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Inner Sphere Complex
Inner sphere complex is a type of surface complex that refers to the surface chemistry changing a water-surface interface to one without water molecules bridging a ligand to the metal ion. Formation of inner sphere complexes occurs when ions bind directly to the surface with no intervening water molecules. These types of surface complexes are restricted to ions that have a high affinity for surface sites and include specifically adsorbed ions that can bind to the surface through covalent bonding. Inner sphere complexes describe active surface sites that are involved in nucleation, crystal growth, redox processes, soil chemistry, alongside other reactions taking place between a cation and surface. This affinity to surface sites can be attributed to covalent bonding. When compared to outer sphere complexes that have water molecules separating ions from ligands, inner sphere complexes have surface hydroxyl groups that function as \sigma -donor ligands, increasing the coordinated ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ligand
In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs, often through Lewis acids and bases, Lewis bases. The nature of metal–ligand bonding can range from covalent bond, covalent to ionic bond, ionic. Furthermore, the metal–ligand bond order can range from one to three. Ligands are viewed as Lewis bases, although rare cases are known to involve Lewis acids and bases, Lewis acidic "ligands". Metals and metalloids are bound to ligands in almost all circumstances, although gaseous "naked" metal ions can be generated in a high vacuum. Ligands in a complex dictate the reactivity (chemistry), reactivity of the central atom, including ligand substitution rates, the reactivity of the ligands themselves, and redox. Ligand selection requires critical consideration in many practical are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxyanion
An oxyanion, or oxoanion, is an ion with the generic formula (where A represents a chemical element and O represents an oxygen atom). Oxyanions are formed by a large majority of the chemical elements. The formulae of simple oxyanions are determined by the octet rule. The corresponding oxyacid of an oxyanion is the compound . The structures of condensed oxyanions can be rationalized in terms of AO''n'' polyhedral units with sharing of corners or edges between polyhedra. The oxyanions (specifically, phosphate and polyphosphate esters) adenosine monophosphate ( AMP), adenosine diphosphate ( ADP) and adenosine triphosphate (ATP) are important in biology. Monomeric oxyanions The formula of monomeric oxyanions, , is dictated by the oxidation state of the element A and its position in the periodic table. Elements of the first row are limited to a maximum coordination number of 4. However, none of the first row elements has a monomeric oxyanion with that coordination number. Instead, c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Weathering
Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no movement), and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity. Weathering processes are either physical or chemical. The former involves the breakdown of rocks and soils through such mechanical effects as heat, water, ice and wind. The latter covers reactions to water, atmospheric gases and biologically produced chemicals with rocks and soils. Water is the principal agent behind both kinds, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Biological chemical weathering is also called biological weathering. The materials left after the rock breaks down combine with organic material to create so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trace Element
__NOTOC__ A trace element is a chemical element of a minute quantity, a trace amount, especially used in referring to a micronutrient, but is also used to refer to minor elements in the composition of a rock, or other chemical substance. In nutrition, trace elements are classified into two groups: essential trace elements, and non-essential trace elements. Essential trace elements are needed for many physiological and biochemical processes in both plants and animals. Not only do trace elements play a role in biological processes but they also serve as catalysts to engage in redox – oxidation and reduction mechanisms. Trace elements of some heavy metals have a biological role as essential micronutrients. Types The two types of trace element in biochemistry are classed as essential or non-essential. Essential trace elements An essential trace element is a dietary element, a mineral that is only needed in minute quantities for the proper growth, development, and physiology ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sorption
Sorption is a physical and chemical process by which one substance becomes attached to another. Specific cases of sorption are treated in the following articles: ; Absorption: "the incorporation of a substance in one state into another of a different state" (e.g., liquids being absorbed by a solid or gases being absorbed by a liquid); ; Adsorption: The physical adherence or bonding of ions and molecules onto the surface of another phase (e.g., reagents adsorbed to a solid catalyst surface); ; Ion exchange: An exchange of ions between two electrolytes or between an electrolyte solution and a complex. The reverse of sorption is desorption. Sorption rate The adsorption and absorption rate of a diluted solute in gas or liquid solution to a surface or interface can be calculated using Fick's laws of diffusion Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Activation Energy
In the Arrhenius model of reaction rates, activation energy is the minimum amount of energy that must be available to reactants for a chemical reaction to occur. The activation energy (''E''a) of a reaction is measured in kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as a magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that there exists an appreciable number of molecules with translational energy equal to or greater than the activation energy. The term "activation energy" was introduced in 1889 by the Swedish scientist Svante Arrhenius. Other uses Although less commonly used, activation energy also applies to nuclear reactions and various other physical phenomena. Temperature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adsorption
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). While adsorption does often precede absorption, which involves the transfer of the absorbate into the volume of the absorbent material, alternatively, adsorption is distinctly a surface phenomenon, wherein the adsorbate does not penetrate through the material surface and into the bulk of the adsorbent. The term '' sorption'' encompasses both adsorption and absorption, and ''desorption'' is the reverse of sorption. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lewis Acids And Bases
A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any species that has a filled orbital containing an electron pair which is not involved in bonding but may form a dative bond with a Lewis acid to form a Lewis adduct. For example, NH3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane CH3)3Bis a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. In the context of a specific chemical reaction between NH3 and Me3B, a lone pair from NH3 will form a dative bond with the empty orbital of Me3B to form an adduct NH3•BMe3. The terminology refers to the contributions of Gilbert N. Lewis. From p. 142: "We are inclined to think of substances as po ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metallic Oxides
Metallic may be a reference to: *Metal *Metalloid, metal-like substance *Metallic bonding, type of chemical bonding *Metallicity, in astronomy the proportion of elements other than helium and hydrogen in an object *Metallic color, a color that gives the appearance of metal *Metallic dragon, a classification of dragon found in the role playing game Dungeons & Dragons *Metallic paint, paint that provides the appearance of metal *Heavy metal music, a genre of rock music See also *Metallica (other) Metallica Metallica is an American heavy metal band. It was formed in Los Angeles in 1981 by vocalist and guitarist James Hetfield and drummer Lars Ulrich, and has been based in San Francisco for most of its career. The band's fast tempo ... * Metal (other) * {{disambiguation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dupré Equation
Dupré is a French name that literally means "from the meadow ( "pré" in French)", or "from Prez". Also existing variants are Duprée, DuPree, Deupree, DePrez, Dupres, Duprez, Düpre and Du Preez. Notable people * Anna Johnson Dupree (1891–1977), Texas businesswoman and philanthropist * Ashley Alexandra Dupré (born 1985), stage name of the former prostitute connected to the Eliot Spitzer prostitution scandal * Augustin Dupré (1748–1833), engraver * Billy Joe DuPree (born 1950), American football player * Bud Dupree (born 1993), American football player * Champion Jack Dupree, (c.1910–1992) US-American blues pianist * Charles Dupré (1827–1907), Dutch chess master * Cornell Dupree, (1942–2011) US-American jazz and R&B guitarist * Emile Duprée (1936–2023), wrestling promoter * Fourie du Preez (born 1982), former South African rugby union player * Frik du Preez (born 1925), former South African rugby union player * Garron DuPree (born 1989), musician and member ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
