Grove Cell
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Grove Cell
The Grove cell was an early electric primary cell named after its inventor, Welsh physical scientist William Robert Grove, and consisted of a zinc anode in dilute sulfuric acid and a platinum cathode in concentrated nitric acid, the two separated by a porous ceramic pot. Cell details The Grove cell voltage is about 1.9 volts and arises from the following reaction: : Zn + H2SO4 + 2 HNO3 ZnSO4 + 2 H2O + 2 NO2↑ Use The Grove cell was the favored power source of the early American telegraph system in the period 1840 – 1860 because it offered a high current output and higher voltage than the earlier Daniell cell (at 1.9 volts and 1.1 volts, respectively). Disadvantages By the time of the American Civil War, as telegraph traffic increased, the Grove cell's tendency to discharge poisonous nitrogen dioxide (NO2) fumes proved increasingly hazardous to health, and as telegraphs became more complex, the need for constant voltage became critical. The Grove cell was limited in this respe ...
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Telegraph
Telegraphy is the long-distance transmission of messages where the sender uses symbolic codes, known to the recipient, rather than a physical exchange of an object bearing the message. Thus flag semaphore is a method of telegraphy, whereas pigeon post is not. Ancient signalling systems, although sometimes quite extensive and sophisticated as in China, were generally not capable of transmitting arbitrary text messages. Possible messages were fixed and predetermined and such systems are thus not true telegraphs. The earliest true telegraph put into widespread use was the optical telegraph of Claude Chappe, invented in the late 18th century. The system was used extensively in France, and European nations occupied by France, during the Napoleonic era. The electric telegraph started to replace the optical telegraph in the mid-19th century. It was first taken up in Britain in the form of the Cooke and Wheatstone telegraph, initially used mostly as an aid to railway signalling. Th ...
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History Of The Battery
Batteries provided the primary source of electricity before the development of electric generators and electrical grids around the end of the 19th century. Successive improvements in battery technology facilitated major electrical advances, from early scientific studies to the rise of telegraphs and telephones, eventually leading to portable computers, mobile phones, electric cars, and many other electrical devices. Students and engineers developed several commercially important types of battery. "Wet cells" were open containers that held liquid electrolyte and metallic electrodes. When the electrodes were completely consumed, the wet cell was renewed by replacing the electrodes and electrolyte. Open containers are unsuitable for mobile or portable use. Wet cells were used commercially in the telegraph and telephone systems. Early electric cars used semi-sealed wet cells. One important classification for batteries is by their life cycle. "Primary" batteries can produce cu ...
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List Of Battery Types
This list is a summary of notable electric battery types composed of one or more electrochemical cells. Three lists are provided in the table. The primary (non-rechargeable) and secondary (rechargeable) cell lists are lists of battery chemistry. The third list is a list of battery applications. Battery cell types See also * Baghdad Battery * Battery nomenclature * Carnot battery * Comparison of commercial battery types * History of the battery * List of battery sizes * List of energy densities * ''Search for the Super Battery'' (2017 PBS film) * Fuel cell References {{Battery sizes * Battery Battery most often refers to: * Electric battery, a device that provides electrical power * Battery (crime), a crime involving unlawful physical contact Battery may also refer to: Energy source *Automotive battery, a device to provide power t ...
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Nitrogen Dioxide
Nitrogen dioxide is a chemical compound with the formula . It is one of several nitrogen oxides. is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the production of fertilizers. At higher temperatures it is a reddish-brown gas. It can be fatal if inhaled in large quantities. Nitrogen dioxide is a paramagnetic, bent molecule with C2v point group symmetry. It is included in the NOx family of atmospheric pollutants. Properties Nitrogen dioxide is a reddish-brown gas with a pungent, acrid odor above , becomes a yellowish-brown liquid below , and converts to the colorless dinitrogen tetroxide () below . The bond length between the nitrogen atom and the oxygen atom is 119.7  pm. This bond length is consistent with a bond order between one and two. Unlike ozone, O3, the ground electronic state of nitrogen dioxide is a doublet state, since nitrogen has one unpaired electron, which decreases ...
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American Civil War
The American Civil War (April 12, 1861 – May 26, 1865; also known by other names) was a civil war in the United States. It was fought between the Union ("the North") and the Confederacy ("the South"), the latter formed by states that had seceded. The central cause of the war was the dispute over whether slavery would be permitted to expand into the western territories, leading to more slave states, or be prevented from doing so, which was widely believed would place slavery on a course of ultimate extinction. Decades of political controversy over slavery were brought to a head by the victory in the 1860 U.S. presidential election of Abraham Lincoln, who opposed slavery's expansion into the west. An initial seven southern slave states responded to Lincoln's victory by seceding from the United States and, in 1861, forming the Confederacy. The Confederacy seized U.S. forts and other federal assets within their borders. Led by Confederate President Jefferson Davis, ...
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Daniell Cell
The Daniell cell is a type of electrochemical cell invented in 1836 by John Frederic Daniell, a British chemist and meteorologist, and consists of a copper pot filled with a copper (II) sulfate solution, in which is immersed an unglazed earthenware container filled with sulfuric acid and a zinc electrode. He was searching for a way to eliminate the hydrogen bubble problem found in the voltaic pile, and his solution was to use a second electrolyte to consume the hydrogen produced by the first. Zinc sulfate may be substituted for the sulfuric acid. The Daniell cell was a great improvement over the existing technology used in the early days of battery development. A later variant of the Daniell cell called the gravity cell or crowfoot cell was invented in the 1860s by a Frenchman named Callaud and became a popular choice for electrical telegraphy. The Daniell cell is also the historical basis for the contemporary definition of the volt, which is the unit of electromotive force in t ...
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Voltage
Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to move a test charge between the two points. In the International System of Units, the derived unit for voltage is named ''volt''. The voltage between points can be caused by the build-up of electric charge (e.g., a capacitor), and from an electromotive force (e.g., electromagnetic induction in generator, inductors, and transformers). On a macroscopic scale, a potential difference can be caused by electrochemical processes (e.g., cells and batteries), the pressure-induced piezoelectric effect, and the thermoelectric effect. A voltmeter can be used to measure the voltage between two points in a system. Often a common reference potential such as the ground of the system is used as one of the points. A voltage can represent either a source ...
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Nitric Acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as pigments in inks and dyes. Nitric acid is also commonly used as a strong oxidizing agen ...
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Primary Cell
A primary battery or primary cell is a battery (a galvanic cell) that is designed to be used once and discarded, and not recharged with electricity and reused like a secondary cell (rechargeable battery). In general, the electrochemical reaction occurring in the cell is not reversible, rendering the cell unrechargeable. As a primary cell is used, chemical reactions in the battery use up the chemicals that generate the power; when they are gone, the battery stops producing electricity. In contrast, in a secondary cell, the reaction can be reversed by running a current into the cell with a battery charger to recharge it, regenerating the chemical reactants. Primary cells are made in a range of standard sizes to power small household appliances such as flashlights and portable radios. Primary batteries make up about 90% of the $50 billion battery market, but secondary batteries have been gaining market share. About 15 billion primary batteries are thrown away worldwide every year, vi ...
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Cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. Consequently, the mnemonic ''cathode current departs'' also means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside of the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity with respect to the anode can be positive ...
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Platinum
Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinum is a member of the platinum group of elements and group 10 of the periodic table of elements. It has six naturally occurring isotopes. It is one of the rarer elements in Earth's crust, with an average abundance of approximately 5  μg/kg. It occurs in some nickel and copper ores along with some native deposits, mostly in South Africa, which accounts for ~80% of the world production. Because of its scarcity in Earth's crust, only a few hundred tonnes are produced annually, and given its important uses, it is highly valuable and is a major precious metal commodity. Platinum is one of the least reactive metals. It has remarkable resistance to corrosion, even at high temperatures, and is therefore considered a noble metal. Consequent ...
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